Evaluation of structural transformation in 2D metal–organic frameworks based on a 4,4′-sulfonyldibenzoate linker: microwave-assisted solvothermal synthesis, characterization and applications

CrystEngComm ◽  
2014 ◽  
Vol 16 (39) ◽  
pp. 9308-9319 ◽  
Author(s):  
Cheng-You Wu ◽  
Duraisamy Senthil Raja ◽  
Chun-Chuen Yang ◽  
Chun-Ting Yeh ◽  
Yu-Ru Chen ◽  
...  
Keyword(s):  
Structural Transformation ◽  
Solvothermal Synthesis ◽  
Metal Organic Frameworks ◽  
Microwave Assisted ◽  
Metal Organic

Structural transformation has been observed in 2D MOFs.

Microwave assisted non-solvothermal synthesis of metal–organic frameworks

RSC Advances ◽  
2016 ◽  
Vol 6 (31) ◽  
pp. 25967-25974 ◽  
Author(s):  
Gabriela Blanita ◽  
Gheorghe Borodi ◽  
Mihaela D. Lazar ◽  
Alexandru-Radu Biris ◽  
Lucian Barbu-Tudoran ◽  
...  
Keyword(s):  
Solvothermal Synthesis ◽  
Metal Organic Frameworks ◽  
Microwave Assisted ◽  
Metal Organic

Microwave-assisted non-solvothermal synthesis of HKUST-1.

Microwave-Assisted Solvothermal Synthesis and Optical Properties of Tagged MIL-140A Metal–Organic Frameworks

2013 ◽  
Vol 52 (22) ◽  
pp. 12878-12880 ◽  
Author(s):  
Weibin Liang ◽  
Ravichandar Babarao ◽  
Deanna M. D’Alessandro
Keyword(s):  
Optical Properties ◽  
Solvothermal Synthesis ◽  
Metal Organic Frameworks ◽  
Microwave Assisted ◽  
Metal Organic

Lanthanide metal–organic frameworks based on the 4,4′-oxybisbenzoic acid ligand: synthesis, structures and physical properties

2015 ◽  
Vol 39 (12) ◽  
pp. 9872-9878 ◽  
Author(s):  
Yun Li ◽  
Ning Wang ◽  
Yan-Ju Xiong ◽  
Qian Cheng ◽  
Jie-Fang Fang ◽  
...  
Keyword(s):  
Physical Properties ◽  
Solvothermal Synthesis ◽  
Metal Organic Frameworks ◽  
Lanthanide Ions ◽  
Acid Ligand ◽  
Metal Organic ◽  
Lanthanide Metal ◽  
Ligand Synthesis

Using solvothermal synthesis, eight new 3D microporous lanthanide-ions-based MOFs constructed from 4,4′-oxybisbenzoic acid were obtained and displayed two types of architecture.

Metal–Organic Frameworks with Pyridyl-Based Isophthalic Acid and Their Catalytic Applications in Microwave Assisted Peroxidative Oxidation of Alcohols and Henry Reaction

2016 ◽  
Vol 16 (4) ◽  
pp. 1837-1849 ◽  
Author(s):  
Anirban Karmakar ◽  
Luísa M. D. R. S. Martins ◽  
Susanta Hazra ◽  
M. Fátima C. Guedes da Silva ◽  
Armando J. L. Pombeiro
Keyword(s):  
Metal Organic Frameworks ◽  
Isophthalic Acid ◽  
Henry Reaction ◽  
Microwave Assisted ◽  
Oxidation Of Alcohols ◽  
Metal Organic ◽  
Catalytic Applications

scholarly journals Two-dimensional metal-organic frameworks containing linear dicarboxylates

2006 ◽  
Vol 62 (5) ◽  
pp. 808-814 ◽  
Author(s):  
Samuel M. Hawxwell ◽  
Harry Adams ◽  
Lee Brammer
Keyword(s):  
Dicarboxylic Acid ◽  
Solvothermal Synthesis ◽  
Interplanar Spacing ◽  
Metal Organic Frameworks ◽  
Dicarboxylic Acids ◽  
Two Dimensional ◽  
Secondary Building Units ◽  
Metal Organic ◽  
Gas Molecules ◽  
Solvent Molecules

The solvothermal synthesis of four two-dimensional metal-organic frameworks containing linear dicarboxylic acids as ligands for ZnII centres is described. Zn(BDC)(DMF) [(1) where BDC = benzene-1,4-dicarboxylic acid; DMF = N,N-dimethylformamide] adopts a common paddlewheel motif leading to a 44 grid network, whereas Zn3(BDC)3(EtOH)2 (2), Zn3(BDC)3(H2O)2·4DMF (3) and Zn3(BPDC)3(DMF)2·4DMF (4) each form networks with the relatively uncommon 36 topology based upon Zn3(O2CR)6 secondary building units. All contain coordinated solvent molecules, namely DMF [(1) and (4)], ethanol (2) or H2O (3). Comparison of structures (2) and (3) illustrates a clay-like flexibility in interplanar spacing which sheds light on the ability of the Zn3(BDC)3 framework to undergo desolvation and uptake of small solvent and gas molecules.

Sign in / Sign up

Export Citation Format

Share Document