The effects of halogen bonding and molecular design on the self-assembly of coordination polymers of Mn(iii)-tetraarylporphyrin with axial bridging ligands

CrystEngComm ◽  
2014 ◽  
Vol 16 (36) ◽  
pp. 8327-8333 ◽  
Author(s):  
Goutam Nandi ◽  
Israel Goldberg
Keyword(s):  
Coordination Polymers ◽  
Self Assembly ◽  
Molecular Design ◽  
Halogen Bonding ◽  
Graphite Surface ◽  
The Self ◽  
Bridging Ligands

Two new coordination polymers of Mn(iii)-tetra(iodophenyl)porphyrin with isonicotinate and pyrimidine-5-carboxylate linkers have been synthesized. The effect of halogen-bonding interactions on their self-assembly in the crystalline bulk and on a graphite surface has been discussed.

Self-assembly of chiral oligo(methylene-p-phenylene-ethynylene)s into vesicle-like particles independent of hydrophobicity/hydrophilicity of side chains and solvents

Soft Matter ◽  
2021 ◽  
Author(s):  
Zhiqiang Zhao ◽  
Zheng Bian ◽  
Yu Chen ◽  
Chuanqing Kang ◽  
Lianxun Gao ◽  
...  
Keyword(s):  
Self Assembly ◽  
Molecular Design ◽  
The Self ◽  
Side Chains ◽  
Phenylene Ethynylene

Chiral oligo(methylene-p-phenyleneethynylene)s can form vesicular assemblies no matter whether side chains and solvents are hydrophilic or hydrophobic. The self-assembly processes are highly independent of molecular design and chemical environments.

A series of helical coordination polymers based on two racemic bis(pyridylmethylene) propane-1,2-diamine ligands: relationship of conformations, structures and properties

CrystEngComm ◽  
2019 ◽  
Vol 21 (47) ◽  
pp. 7249-7259 ◽  
Author(s):  
Li-Na Zhu ◽  
Zhao-Peng Deng ◽  
Li-Hua Huo ◽  
Shan Gao
Keyword(s):  
Coordination Polymers ◽  
Self Assembly ◽  
The Self ◽  
Metal Salts ◽  
Structures And Properties ◽  
Relationship Of ◽  
Diamine Ligands

The self-assembly of d10 metal salts and two racemic bis(pyridyl) diamine ligands generates ten complexes, showing diverse helical and wavelike chains, (4,4) layers, as well as 3D sqc and uog nets.

Effects of the position and number of bromine substituents on the concentration-mediated 2D self-assembly of phenanthrene derivatives

2016 ◽  
Vol 18 (10) ◽  
pp. 7208-7215 ◽  
Author(s):  
Xingyu Hu ◽  
Bao Zha ◽  
Yican Wu ◽  
Xinrui Miao ◽  
Wenli Deng
Keyword(s):  
Self Assembly ◽  
Driving Force ◽  
Halogen Bonding ◽  
The Self

Br⋯Br halogen bonding exists in the self-assembly of 2,7-DBHP, whereas the driving force for the assembly of 3,6-DBHP is Br⋯Br vdWs type interactions.

Hydrogen-bonded azaphenacene: a strategy for the organization of π-conjugated materials

2018 ◽  
Vol 6 (15) ◽  
pp. 3968-3975 ◽  
Author(s):  
Paula Gómez ◽  
Stamatis Georgakopoulos ◽  
José Pedro Cerón ◽  
Iván da Silva ◽  
Miriam Más-Montoya ◽  
...  
Keyword(s):  
Self Assembly ◽  
Molecular Design ◽  
The Self ◽  
Molecular Materials ◽  
Conjugated Materials ◽  
Hydrogen Bonded

Molecular design for the self-assembly of molecular materials.

Copper(i) halide cluster-based coordination polymers modulated by chiral ditopic dithiodianthranilide ligands: synthesis, crystal structure and photoluminescence

CrystEngComm ◽  
2021 ◽  
Author(s):  
Jarosław Chojnacki ◽  
Michał Mońka ◽  
Illia E. Serdiuk ◽  
Piotr Bojarski ◽  
Tadeusz Połoński ◽  
...  
Keyword(s):  
Crystal Structure ◽  
Coordination Polymers ◽  
Self Assembly ◽  
Spectroscopic Properties ◽  
The Self ◽  
Halide Cluster

The influence of ligand chirality on the self-assembly and spectroscopic properties of copper(i) halide coordination polymers was investigated.

Hydrothermal Syntheses, Crystal Structures, and Luminescent Properties of Two MnII Coordination Polymers: From Two-Fold Interpenetrated pcu Topological Net to Polycatenated 2D+2D→3D Framework

2015 ◽  
Vol 68 (2) ◽  
pp. 322 ◽  
Author(s):  
Wenlong Liu ◽  
Mengqiang Wu ◽  
Xueying Wang ◽  
Wei Wang ◽  
Dayu Liu ◽  
...  
Keyword(s):  
Dicarboxylic Acid ◽  
Coordination Polymers ◽  
Self Assembly ◽  
Room Temperature ◽  
Luminescent Properties ◽  
The Self ◽  
X Ray Diffraction ◽  
X Ray ◽  
3D Framework ◽  
Dimethyl Benzene

Using a hydrothermal synthesis, the self-assembly of MnII ions and 1,4-bis(1-imidazol-yl)-2,5-dimethyl benzene with two dicarboxylate ligands, 2-nitrobenzene-1,4-dicarboxylic acid (2-H2ata) and 5-methylbenzene-1,3-dicarboxylic acid (5-CH3-H2ip) constructed two interesting coordination polymers: [Mn(2-ata)(bimb)]n (1) and {[Mn(5-CH3-ip)(bimb)1.5]·2H2O}n (2), where bimb refers to 1,4-bis(1-imidazol-yl)-2,5-dimethyl benzene. Their structures were determined by single-crystal X-ray diffraction, elemental analysis, and infrared spectroscopy. Complex 1 exhibits a 2-fold interpenetrated pcu net. Complex 2 shows an unusual polycatenated 2D+2D→3D framework. In addition, the solid-state photoluminescent properties of 1 and 2 were investigated at room temperature.

scholarly journals Towards supramolecular nanostructured materials: control of the self-assembly of ionic bent-core amphiphiles

2020 ◽  
Vol 8 (6) ◽  
pp. 1998-2007 ◽  
Author(s):  
Martín Castillo-Vallés ◽  
Miguel Cano ◽  
Ana Bermejo-Sanz ◽  
Nélida Gimeno ◽  
M. Blanca Ros
Keyword(s):  
Nanostructured Materials ◽  
Self Assembly ◽  
Molecular Design ◽  
The Self ◽  
Bottom Up

Bottom-up self-assembly: the formation of mesophases and nanostructures in solution from ionic bent-core dendrimers has been systematically studied by molecular design.

Synthese und Koordinationschemie eines neuartigen Bistetrazols: Ein 1D-Metallopolymer durch Selbstorganisation koordinativ ungesättigter Zink(II)-M4onomere [1] / Synthesis and Coordination Chemistry of a New Bistetrazole: A 1D-Metallopolymer via Self-Assembly of Monomeric Zinc(II)-Buildingblocks

1995 ◽  
Vol 50 (4) ◽  
pp. 642-648 ◽  
Author(s):  
Rolf W. Saalfrank ◽  
Klaus Schobert ◽  
Stefan Trümmer ◽  
Alexander Wolski
Keyword(s):  
Coordination Chemistry ◽  
Self Assembly ◽  
Intermediate Formation ◽  
The Self ◽  
Polymeric Chain ◽  
X Ray Diffraction ◽  
Bridging Ligands ◽  
Subsequent Formation ◽  
X Ray ◽  
Polymeric Compounds

The new bistetrazole 13 has been obtained by subsequent formation of the two heterocyclic units. In methanolic solution 13 reacts with zinc(II) acetate to yield the pseudo-meso-1 D-coordination polymer [ZnL2(MeOH)]n (n = ∞) 14. The structure of 14 was established by single crystal X-ray diffraction. The generation of the polymeric chain 14 is understandable, if intermediate formation of coordinatively unsaturated zinc(II) buildingblocks (Δ)-15 and (Λ)-15 is assumed. Alternating linkage of the self-complementary chiral monomers 15, across one cyanofunction each, leads to 14 with zinc being essentially octahedrally coordinated. Compared with polymeric compounds of similar bridging ligands, the Zn ··· N≡C-distance in 14 (225,7 pm) is short.

Effect of Anions on the Self-Assembly of Cd(II)-Containing Coordination Polymers Based on a Novel Flexible Tetrakis(imidazole) Ligand

2010 ◽  
Vol 10 (2) ◽  
pp. 995-1016 ◽  
Author(s):  
Hong-Ye Bai ◽  
Jian-Fang Ma ◽  
Jin Yang ◽  
Ying-Ying Liu ◽  
Hua-Wu ◽  
...  
Keyword(s):  
Coordination Polymers ◽  
Self Assembly ◽  
The Self ◽  
Imidazole Ligand
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