scholarly journals Synthesis and formation mechanism of CuInS2 nanocrystals with a tunable phase

CrystEngComm ◽  
2014 ◽  
Vol 16 (41) ◽  
pp. 9596-9602 ◽  
Author(s):  
Chao Yu ◽  
Linlin Zhang ◽  
Long Tian ◽  
Dan Liu ◽  
Fanglin Chen ◽  
...  

Monodisperse chalcopyrite and wurtzite CuInS2 nanocrystals are produced and their crystal phases are controlled by varying the In precursors.

RSC Advances ◽  
2014 ◽  
Vol 4 (69) ◽  
pp. 36875-36881 ◽  
Author(s):  
Fengcong Gong ◽  
Shouqin Tian ◽  
Baoshun Liu ◽  
Dehua Xiong ◽  
Xiujian Zhao

CuInS2 nanocrystals with different phase structures were synthesized by a facile heat-up method through simply adjusting the OA dosage. This is because a high OA dosage could facilitate the formation and crystallization of the CuIn(SR)x intermediate, giving a metastable wurtzite CuInS2 structure, while low OA dosage would lead to low crystallinity of the intermediate, producing a stable zinc-blende phase.


2014 ◽  
Vol 38 (4) ◽  
pp. 1731-1737 ◽  
Author(s):  
Keigo Aso ◽  
Akitoshi Hayashi ◽  
Masahiro Tatsumisago

The formation mechanism of nickel sulfide was investigated by changing reaction conditions, examining intermediates, and verifying the effects of capping ability of a coordinating solvent on crystal phases of nickel sulfide.


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