An organometallic complex revealing an unexpected, reversible, temperature induced SC–SC transformation

CrystEngComm ◽  
2014 ◽  
Vol 16 (21) ◽  
pp. 4641-4652 ◽  
Author(s):  
Rupert G. D. Taylor ◽  
Benjamin R. Yeo ◽  
Andrew J. Hallett ◽  
Benson M. Kariuki ◽  
Simon J. A. Pope
Keyword(s):  
Phase Transformation ◽  
Transition Metal ◽  
Single Crystal ◽  
Coordination Complex ◽  
Metal Coordination ◽  
Organometallic Complex

A reversible, temperature driven phase transformation that takes place at ca. 180 K, in a single-crystal to single-crystal manner, has been observed for a monometallic transition metal coordination complex based on a fac-Re(CO)3 core, with a chelated 2,2′-bipyridine unit and a halogenated N-(4-iodophenyl)nicotinamide axial co-ligand.

Transition metal coordination complexes of chrysazin

CrystEngComm ◽  
2016 ◽  
Vol 18 (27) ◽  
pp. 5121-5129 ◽  
Author(s):  
Patrick J. Beldon ◽  
Sebastian Henke ◽  
Bartomeu Monserrat ◽  
Satoshi Tominaka ◽  
Norbert Stock ◽  
...  
Keyword(s):  
Transition Metal ◽  
Transition Metals ◽  
Single Crystal ◽  
Coordination Compounds ◽  
Coordination Complexes ◽  
Metal Coordination ◽  
X Ray Diffraction ◽  
X Ray

Eleven novel coordination compounds, composed of chrysazin (1,8-dihydroxyanthraquinone) and different first-row transition metals (Fe, Co, Ni, Cu), were synthesised and the structures determined by single-crystal X-ray diffraction.

A novel polyoxometalate tri-supported mixed-valent transition metal coordination complex

2010 ◽  
Vol 13 (10) ◽  
pp. 1217-1220 ◽  
Author(s):  
Li-Na Xiao ◽  
Yan Wang ◽  
Yan Chen ◽  
Yu Peng ◽  
Guo-Dong Li ◽  
...  
Keyword(s):  
Transition Metal ◽  
Coordination Complex ◽  
Metal Coordination

scholarly journals Epitaxial Single‐Crystal Growth of Transition Metal Dichalcogenide Monolayers via the Atomic Sawtooth Au Surface

2021 ◽  
pp. 2006601
Author(s):  
Soo Ho Choi ◽  
Hyung‐Jin Kim ◽  
Bumsub Song ◽  
Yong In Kim ◽  
Gyeongtak Han ◽  
...  
Keyword(s):  
Crystal Growth ◽  
Transition Metal ◽  
Single Crystal ◽  
Single Crystal Growth ◽  
Transition Metal Dichalcogenide

scholarly journals Intermolecular interaction energies in transition metal coordination compounds

CrystEngComm ◽  
2015 ◽  
Vol 17 (48) ◽  
pp. 9300-9310 ◽  
Author(s):  
Andrew G. P. Maloney ◽  
Peter A. Wood ◽  
Simon Parsons
Keyword(s):  
Transition Metal ◽  
Transition Metals ◽  
Crystal Structures ◽  
Intermolecular Interaction ◽  
Coordination Compounds ◽  
Metal Coordination ◽  
Interaction Energies

The PIXEL method has been parameterised and validated for transition metals, extending its applicability from ~40% to ~85% of all published crystal structures.

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