A stable Li-deficient oxide as high-performance cathode for advanced lithium-ion batteries

2015 ◽  
Vol 51 (15) ◽  
pp. 3231-3234 ◽  
Author(s):  
Peiyu Hou ◽  
Jie Wang ◽  
Jishun Song ◽  
Dawei Song ◽  
Xixi Shi ◽  
...  
Keyword(s):  
Lithium Ion Batteries ◽  
High Performance ◽  
Lithium Ion ◽  
Reversible Capacity ◽  
Cycle Life

A stable Li-deficient Li0.35Ni0.2Co0.1Mn0.7O2−x surprisingly delivers large reversible capacity (251.3 mA h g−1), outstanding cycle life and a low median-voltage of 2.7 V in the range of 2.0–4.9 V.

Synthesis and Electrochemical Performance of SnO2/Graphene Hybrid Anode for Lithium Ion Batteries

2013 ◽  
Vol 1540 ◽  
Author(s):  
Chia-Yi Lin ◽  
Chien-Te Hsieh ◽  
Ruey-Shin Juang
Keyword(s):  
Electrochemical Performance ◽  
Lithium Ion Batteries ◽  
Anode Material ◽  
High Performance ◽  
Coulombic Efficiency ◽  
Rate Capability ◽  
Lithium Ion ◽  
Reversible Capacity ◽  
Cycling Performance ◽  
Homogeneous Distribution

ABSTRACTAn efficient microwave-assisted polyol (MP) approach is report to prepare SnO2/graphene hybrid as an anode material for lithium ion batteries. The key factor to this MP method is to start with uniform graphene oxide (GO) suspension, in which a large amount of surface oxygenate groups ensures homogeneous distribution of the SnO2 nanoparticles onto the GO sheets under the microwave irradiation. The period for the microwave heating only takes 10 min. The obtained SnO2/graphene hybrid anode possesses a reversible capacity of 967 mAh g-1 at 0.1 C and a high Coulombic efficiency of 80.5% at the first cycle. The cycling performance and the rate capability of the hybrid anode are enhanced in comparison with that of the bare graphene anode. This improvement of electrochemical performance can be attributed to the formation of a 3-dimensional framework. Accordingly, this study provides an economical MP route for the fabrication of SnO2/graphene hybrid as an anode material for high-performance Li-ion batteries.

Preparation of a porous Sn@C nanocomposite as a high-performance anode material for lithium-ion batteries

Nanoscale ◽  
2015 ◽  
Vol 7 (28) ◽  
pp. 11940-11944 ◽  
Author(s):  
Yanjun Zhang ◽  
Li Jiang ◽  
Chunru Wang
Keyword(s):  
Lithium Ion Batteries ◽  
Anode Material ◽  
High Performance ◽  
Rate Capability ◽  
Lithium Ion ◽  
Reversible Capacity ◽  
Facile Hydrothermal Method ◽  
Calcination Process ◽  
Long Cycle Life ◽  
Good Rate Capability

A porous Sn@C nanocomposite was prepared via a facile hydrothermal method combined with a simple post-calcination process. It exhibited excellent electrochemical behavior with a high reversible capacity, long cycle life and good rate capability when used as an anode material for lithium ion batteries.

Hierarchical WO3@SnO2core–shell nanowire arrays on carbon cloth: a new class of anode for high-performance lithium-ion batteries

2014 ◽  
Vol 2 (20) ◽  
pp. 7367-7372 ◽  
Author(s):  
Lina Gao ◽  
Fengyu Qu ◽  
Xiang Wu
Keyword(s):  
Lithium Ion Batteries ◽  
High Performance ◽  
Nanowire Array ◽  
Lithium Ion ◽  
Reversible Capacity ◽  
Nanowire Arrays ◽  
Carbon Cloth ◽  
New Class ◽  
High Reversible Capacity

Hybrid WO3@SnO2nanowire array/carbon cloth electrodes exhibit a high reversible capacity of 1000 mA h g−1after 200 cycles.

scholarly journals Electrospun Core-Shell Nanofiber as Separator for Lithium-Ion Batteries with High Performance and Improved Safety

2019 ◽  
Author(s):  
Yun Zhao ◽  
Yanxi Li ◽  
Zheng Liang
Keyword(s):  
Lithium Ion Batteries ◽  
High Performance ◽  
Vinylidene Fluoride ◽  
Short Circuit ◽  
Lithium Ion ◽  
Reversible Capacity ◽  
Liquid Electrolyte ◽  
Core Shell ◽  
Fiber Network ◽  
Safety Issues

Though the energy density of lithium-ion batteries continues to increase, safety issues related with the internal short-circuit and the resulting combustion of highly flammable electrolyte impede the further development of lithium-ion batteries. It has been well-accepted that a thermal stable separator is important to postpone the entire battery short-circuit and thermal-runaway. Traditional methods to improve the thermal stability of separators includes surface modification and/or developing alternate material systems for separators which may always affect the battery performance negatively. Herein, a thermostable and shrink-free separator with little compromise in battery performance is prepared by coaxial electrospinning and tested. The separator consists of core-shell fiber networks where poly(vinylidene fluoride-hexafluoropropylene) (PVDF-HFP) layer serves as shell and polyacrylonitrile (PAN) as the core. This core-shell fiber network exhibits little or even no shrinking/melting at elevated temperature over 250 °C. Meanwhile, it shows excellent electrolyte wettability and can take large amount of liquid electrolyte three times more than that of conventional Celgard 2400 separator. In addition, the half-cell using LiNi1/3Co1/3Mn1/3O2 as cathode and the aforementioned electrospun core-shell fiber network as separator demonstrates superior electrochemical behavior, stably cycling for 200 cycles at 1 C with a reversible capacity of 130 mAh g-1 and little capacity decay.

High-Performance Anode Materials with Superior Structure of Fe3O4/FeS/rGO Composite for Lithium Ion Batteries

NANO ◽  
2020 ◽  
Vol 15 (10) ◽  
pp. 2050128 ◽  
Author(s):  
Ruirui Gao ◽  
Suqin Wang ◽  
Zhaoxiu Xu ◽  
Hongbo Li ◽  
Shuiliang Chen ◽  
...  
Keyword(s):  
Lithium Ion Batteries ◽  
Transition Metal Oxides ◽  
High Performance ◽  
Composite Electrode ◽  
Rate Capability ◽  
Lithium Ion ◽  
Reversible Capacity ◽  
Cycling Performance ◽  
Charging And Discharging Processes ◽  
New Perspective

In this work, we developed a simple one-step hydrothermal method to successfully prepare Fe3O4/FeS-reduced graphene oxide (Fe3O4/FeS/rGO) composite directly, which is a novel Lithium-ion batteries (LIBs) anode material. The characterization of Fe3O4/FeS/rGO composite demonstrates that octahedral Fe3O4/FeS particles are uniformly deposited on the rGO, leading to a strong synergy between them. The excellent structural design can make Fe3O4/FeS/rGO composite to have higher reversible capacity (744.7[Formula: see text]mAh/g at 0.1[Formula: see text]C after 50 cycles), excellent cycling performance and superior rate capability. This outstanding electrochemical behavior can be attributed to the conductivity network of rGO, which improves the composite electrode conductivity, facilitates the diffusion and transfer of ions and prevents the aggregation and pulverization of Fe3O4/FeS particles during the charging and discharging processes. Moreover, the Fe3O4/FeS/rGO electrode surface is covered with a thin solid-electrolyte interface (SEI) film and the octahedral structure of Fe3O4/FeS particles is still clearly visible, which indicates that composite electrode has excellent interface stability. We believe that the design of this composite structure will provide a new perspective for the further study of other transition metal oxides for LIBs.

Synthesis of Nitrogen and Phosphorus Dual-Doped Graphene Oxide as High-Performance Anode Material for Lithium-Ion Batteries

2020 ◽  
Vol 20 (12) ◽  
pp. 7673-7679
Author(s):  
Ke Wang ◽  
Zhi Li
Keyword(s):  
Graphene Oxide ◽  
Lithium Ion Batteries ◽  
Anode Material ◽  
High Performance ◽  
Lithium Ion ◽  
Reversible Capacity ◽  
Nitrogen And Phosphorus ◽  
Xrd Pattern ◽  
Ion Storage ◽  
Doped Graphene

Nitrogen and phosphorus dual-doped graphene oxide was prepared by directly calcining a mixture of pure graphene oxide, urea (nitrogen source), and 1,2-bis(diphenylphosphino)methane (phosphorous source). The morphology and composition of the obtained dual-doped graphene oxide were confirmed by SEM, TEM, XRD pattern, Raman spectrum, and XPS. The nitrogen and phosphorous dual-doped graphene oxide was tested as an anode material of lithium-ion batteries (LIBs). The cycle and rate performance of the dual-doped graphene oxide were also examined. The dualdoped graphene oxide exhibited a superior initial discharge capacity of 2796 mAh·g−1 and excellent reversible capacity of 1200 mAh·g−1 at a current density of 100 mA·g−1 after 200 charge/discharge cycles, suggesting that the dual-doping of nitrogen and phosphorous is an effective way to enhance lithium-ion storage for graphene oxide.

Heteroatom doped porous carbon derived from hair as an anode with high performance for lithium ion batteries

RSC Advances ◽  
2014 ◽  
Vol 4 (109) ◽  
pp. 63784-63791 ◽  
Author(s):  
Junke Ou ◽  
Yongzhi Zhang ◽  
Li Chen ◽  
Hongyan Yuan ◽  
Dan Xiao
Keyword(s):  
Lithium Ion Batteries ◽  
Anode Material ◽  
Porous Carbon ◽  
Human Hair ◽  
High Performance ◽  
Rate Capability ◽  
Lithium Ion ◽  
Reversible Capacity ◽  
Superior Performance ◽  
High Reversible Capacity

The HDPC derived from human hair shows superior performance as an anode material for LIBs with high reversible capacity (1331 mA h g−1 at 0.1 A g−1) and excellent rate capability (205 mA h g−1 at 10 A g−1).

Sign in / Sign up

Export Citation Format

Share Document