Stabilization of a highly porous metal–organic framework utilizing a carborane-based linker

2015 ◽  
Vol 51 (30) ◽  
pp. 6521-6523 ◽  
Author(s):  
Daniel J. Clingerman ◽  
William Morris ◽  
Joseph E. Mondloch ◽  
Robert D. Kennedy ◽  
Amy A. Sarjeant ◽  
...  
Keyword(s):  
Metal Organic Framework ◽  
Porous Metal ◽  
Metal Organic ◽  
Highly Porous ◽  
Organic Framework

The first tritopic carborane-based linker, H3BCA (C15B24O6H30), based on closo-1,10-C2B8H10, has been synthesized and incorporated into a metal–organic framework (MOF), NU-700 (Cu3(BCA)2).

Unusual pore structure and sorption behaviour in a hexanodal zinc–organic framework material

2014 ◽  
Vol 50 (14) ◽  
pp. 1678-1681 ◽  
Author(s):  
Jinjie Qian ◽  
Feilong Jiang ◽  
Linjie Zhang ◽  
Kongzhao Su ◽  
Jie Pan ◽  
...  
Keyword(s):  
Pore Structure ◽  
Metal Organic Framework ◽  
Porous Metal ◽  
Sorption Behaviour ◽  
Metal Organic ◽  
Highly Porous ◽  
Organic Framework

A highly porous metal–organic framework structurally consists of three topological kinds of 3-connected 1,3,5-benzenetricarboxylate ligands, Zn2(COO)4, Zn3O(COO)6 and Zn4O(COO)6 SBUs, featuring a new 3,3,3,4,4,6-c hexanodal topology.

Quantum Rotations and Chiral Polarization of Qubit Prototype Molecules in a Highly Porous Metal–Organic Framework: 1H NMR T1 Study

2011 ◽  
Vol 115 (42) ◽  
pp. 20460-20465 ◽  
Author(s):  
Svyatoslav P. Gabuda ◽  
Svetlana G. Kozlova ◽  
Denis G. Samsonenko ◽  
Danil N. Dybtsev ◽  
Vladimir P. Fedin
Keyword(s):  
1H Nmr ◽  
Metal Organic Framework ◽  
Porous Metal ◽  
Metal Organic ◽  
1H Nmr T1 ◽  
Highly Porous ◽  
Organic Framework

Highly porous metal–organic framework sustained with 12-connected nanoscopic octahedra

2013 ◽  
Vol 42 (5) ◽  
pp. 1708-1714 ◽  
Author(s):  
Weigang Lu ◽  
Daqiang Yuan ◽  
Trevor A. Makal ◽  
Zhangwen Wei ◽  
Jian-Rong Li ◽  
...  
Keyword(s):  
Metal Organic Framework ◽  
Porous Metal ◽  
Metal Organic ◽  
Highly Porous ◽  
Organic Framework

Self-assembled multifunctional core–shell highly porous metal–organic framework nanoparticles

2020 ◽  
Vol 581 ◽  
pp. 119281
Author(s):  
Jingwen Qiu ◽  
Xue Li ◽  
Karine Steenkeste ◽  
Nadine Barroca-Aubry ◽  
Caroline Aymes-Chodur ◽  
...  
Keyword(s):  
Metal Organic Framework ◽  
Porous Metal ◽  
Core Shell ◽  
Metal Organic ◽  
Self Assembled ◽  
Highly Porous ◽  
Organic Framework

Direct synthesis of N-sulfenylimines through oxidative coupling of amines with disulfides/thiols over copper based metal–organic frameworks

RSC Advances ◽  
2016 ◽  
Vol 6 (47) ◽  
pp. 40945-40952 ◽  
Author(s):  
Wei Long ◽  
Wenge Qiu ◽  
Chuanqiang Li ◽  
Liyun Song ◽  
Guangmei Bai ◽  
...  
Keyword(s):  
Oxidative Coupling ◽  
Metal Organic Framework ◽  
Direct Synthesis ◽  
Metal Organic Frameworks ◽  
Porous Metal ◽  
Building Blocks ◽  
Metal Organic ◽  
Highly Porous ◽  
Organic Framework

A highly porous metal–organic framework based on supramolecular building blocks with pcu-topology has been tested for the oxidative coupling of amines and disulfides to afford the N-sulfenylimines directly in good yields.

Highly Porous Metal-Organic Framework Containing a Novel Organosilicon Linker − A Promising Material for Hydrogen Storage

2009 ◽  
Vol 48 (14) ◽  
pp. 6559-6565 ◽  
Author(s):  
Stephanie E. Wenzel ◽  
Michael Fischer ◽  
Frank Hoffmann ◽  
Michael Fröba
Keyword(s):  
Hydrogen Storage ◽  
Metal Organic Framework ◽  
Porous Metal ◽  
Promising Material ◽  
Metal Organic ◽  
Highly Porous ◽  
Organic Framework

A nitro-decorated NbO-type metal–organic framework with a highly selective CO2 uptake and CH4 storage capacity

CrystEngComm ◽  
2014 ◽  
Vol 16 (28) ◽  
pp. 6287-6290 ◽  
Author(s):  
Mingxing Zhang ◽  
Qian Wang ◽  
Zhiyong Lu ◽  
Huiyan Liu ◽  
Wenlong Liu ◽  
...  
Keyword(s):  
Storage Capacity ◽  
Metal Organic Framework ◽  
Porous Metal ◽  
Co2 Uptake ◽  
Adsorption Selectivity ◽  
Total Uptake ◽  
Metal Organic ◽  
Highly Porous ◽  
Organic Framework ◽  
Ch4 Storage

A nitro-decorated and highly porous metal–organic framework with NbO topology was reported, exhibiting good adsorption selectivity of CO2/CH4 (8) and CO2/N2 (24) at 273 K and 1 bar, high methane total uptake of 184 cm3 cm−3 at 290 K and 35 bar.

Unique gas and hydrocarbon adsorption in a highly porous metal-organic framework made of extended aliphatic ligands

2008 ◽  
pp. 6123 ◽  
Author(s):  
Kunhao Li ◽  
JeongYong Lee ◽  
David H. Olson ◽  
Thomas J. Emge ◽  
Wenhua Bi ◽  
...  
Keyword(s):  
Metal Organic Framework ◽  
Porous Metal ◽  
Hydrocarbon Adsorption ◽  
Metal Organic ◽  
Highly Porous ◽  
Organic Framework
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