scholarly journals Increased short circuit current in an azafullerene-based organic solar cell

2015 ◽  
Vol 51 (6) ◽  
pp. 1128-1130 ◽  
Author(s):  
Werther Cambarau ◽  
Urs F. Fritze ◽  
Aurélien Viterisi ◽  
Emilio Palomares ◽  
Max von Delius
Keyword(s):  
Solar Cells ◽  
Solar Cell ◽  
Organic Solar Cells ◽  
Organic Solar Cell ◽  
Short Circuit ◽  
Short Circuit Current

We report azafullerene monoadduct DPC59N, which in organic solar cells outperforms benchmark acceptor PC60BM in respect to JSC and EQE.

An Improved Triple-Tandem Organic Solar Cell

2009 ◽  
Vol 1212 ◽  
Author(s):  
Dewei Zhao ◽  
Xiao Wei Sun ◽  
Lin Ke ◽  
Swee Tiam Tan
Keyword(s):  
Solar Cell ◽  
Small Molecule ◽  
Organic Solar Cells ◽  
Organic Solar Cell ◽  
Copper Phthalocyanine ◽  
Short Circuit ◽  
Short Circuit Current ◽  
Open Circuit ◽  
Solar Irradiation ◽  
The Third

AbstractWe present an efficient polymer-small molecule triple-tandem organic solar cell (OSC), consisting of poly(3-hexylthiophene) (P3HT) and 1-(3-methoxycarbonyl)-propyl-1-phenyl-(6,6)C61 (PCBM) bulk heterojunction as the first and second cells, and small molecules copper phthalocyanine (CuPc) and fullerene (C60) as the third cell on top. These sub-cells are connected by an intermediate layer of Al(1 nm)/MoO3(15 nm), which appears to be highly transparent, structurally smooth, and electrically functional. Compared to our previous all polymer triple-tandem organic solar cells (2.03%), this polymer-small molecule triple-tandem organic solar cell achieves an improved power conversion efficiency of 2.18% with a short-circuit current density (Jsc) = 3.02 mA/cm2, open-circuit voltage (Voc) = 1.51 V, and fill factor (FF) = 47.7% under simulated solar irradiation of 100 mW/cm2 (AM1.5G), which can be attributed to the increased photocurrent generation in the third cell since the third cell has the complementary absorption with two bottom cells despite a slightly reduced Voc.

Production and characterization of organic solar cells

2018 ◽  
Vol 15 (4) ◽  
pp. 540-548 ◽  
Author(s):  
Kindness A.M. Uyanga ◽  
Modestus Okechukwu Okwu ◽  
A.O. Adeoye ◽  
S.E. Ogbeide
Keyword(s):  
Solar Cells ◽  
Solar Cell ◽  
Active Layer ◽  
Organic Solar Cells ◽  
Organic Solar Cell ◽  
Short Circuit ◽  
Active Material ◽  
Soda Lime Glass ◽  
Content Type ◽  
Different Temperatures

Purpose The study aims to carry out the production of a bulk heterojunction organic solar cell in a laboratory scale using a blend of poly (3-hexylthiopene) (P3HT) and [6, 6]-phenyl (C61) butyric acid methyl ether (PCBM). Design/methodology/approach Four inverted geometry organic solar cells were prepared based on 1:1 ratio of P3HT to PCBM and subjected to post annealing at different temperatures of 32, 120, 130 and 140°C. Solar cells were fabricated with structure glass/ITO/P3HT:PCBM/PEDOT:PSS/Au and characterized using Keithley 2400 series sourcemeter and a multimeter interfaced to a computer system with a LabVIEW software, which showed both dark and illumination current–voltage characteristic curves. Four reference cells were also fabricated with structure soda lime glass/P3HT:PCBM and annealed at different temperatures of 32, 120, 130 and 140°C. Findings The third organic solar cell prepared, Sample CITO, had the best performance with power conversion efficiency (PCE) of 2.0281 per cent, fill factor (FF) of 0.392, short circuit current of −0.0133 A and open circuit voltage of 0.389 V. Annealing of active layer was found to improve cell morphology, FF and PCE. Annealing of the active layer at 140°C resulted in a decrease of the PCE to 2.01 per cent. Research limitations/implications These findings are in good agreement with previous investigation in literature which reported that best annealing temperature for a 1:1 ratio blend of active material is 130°C. Ultraviolet–visible spectra on reference cells showed that sample CITO had wider absorption spectra with peak absorbance at a wavelength of 508 nm. Originality/value This research is purely original.

scholarly journals PREPARATION AND CHARACTERIZATION OF P3HT-PCBM ORGANIC SOLAR CELLS

2013 ◽  
pp. 23-25
Author(s):  
ANUBHAV GUPTA ◽  
PRAVEEN S ◽  
ABHISHEK KUMAR ◽  
PRIYANKA SHREE ◽  
SUCHANA MISHRA
Keyword(s):  
Solar Cells ◽  
Solar Cell ◽  
Active Layer ◽  
Organic Solar Cells ◽  
Silicon Solar Cell ◽  
Short Circuit ◽  
Short Circuit Current ◽  
Open Circuit ◽  
Glass Substrates

Organic solar cells using P3HT: PCBM as an active layer on ITO coated glass substrates were fabricated and characterized. Different air annealing procedures and cathode materials were tried and the characteristics were compared with that of a standard thin film polycrystalline silicon solar cell. It was found that the sample prepared with post-deposition air annealing at 130 oC improves the open circuit voltage (Voc) considerably. Besides, short circuit current (Isc) and the efficiency (η) were highest for the sample with a non annealed active layer. Series resistance (Rs) for this sample was lowest, but 103 times higher than that of the silicon solar cell, which in turn may have reduced the efficiency value for the organic cell compared to silicon.

Study of Al/Organic/ITO Polymer Solar Cell on Glass Substrate

2013 ◽  
Vol 448-453 ◽  
pp. 1446-1451
Author(s):  
Yi Tsung Chang ◽  
Jen Hong Su ◽  
Yi Ting Shih ◽  
Yen Lin Shih
Keyword(s):  
Solar Cells ◽  
Solar Cell ◽  
Active Layer ◽  
Organic Solar Cells ◽  
Glass Substrate ◽  
Polymer Solar Cells ◽  
Short Circuit ◽  
Single Layer ◽  
Short Circuit Current ◽  
Open Circuit

A single layer of organic solar cells with the Al/P3HT/PEDOT: PSS/ITO structure on glass substrate was investigated in this paper, and examined the performance of the polymer solar cells by changing 60, 70 and 80 nm thickness of the P3HT active layer. These devices had better absorption in the active layer and poor charges collect in the electrode with increase thickness of active layer were observed. It is found that the best properties that the single layer organic solar cell with open-circuit voltage 0.457 V, short-circuit current 1.05E-4 mA and power conversion efficiency of 3.3E-5% was achieved under illumination 100 mW/cm2 when the thickness of P3HT active layer is about 80 nm.

On the short circuit resilience of organic solar cells: prediction and validation

2015 ◽  
Vol 17 (33) ◽  
pp. 21501-21506 ◽  
Author(s):  
A. Jolt Oostra ◽  
Edsger C. P. Smits ◽  
Dago M. de Leeuw ◽  
Paul W. M. Blom ◽  
Jasper J. Michels
Keyword(s):  
Solar Cells ◽  
Solar Cell ◽  
Fault Tolerance ◽  
Organic Solar Cells ◽  
Organic Solar Cell ◽  
Short Circuit ◽  
Cell Performance ◽  
Solar Cell Performance ◽  
Short Circuits

As flexible organic solar cell performance suffers from processing-related short-circuits, quantitative insight in the effect of flaws is eminent. This work provides such insight and explains how an intrinsic healing mechanism significantly enhances fault-tolerance.

Boron-Nitrogen Doped Dihydroindeno[1,2-b]fluorene Derivatives as Acceptors in Organic Solar Cells

2019 ◽  
Author(s):  
Matthew Morgan ◽  
Maryam Nazari ◽  
Thomas Pickl ◽  
J. Mikko Rautiainen ◽  
Heikki M. Tuononen ◽  
...  
Keyword(s):  
Solar Cells ◽  
Solar Cell ◽  
Organic Solar Cells ◽  
Organic Solar Cell ◽  
Broad Absorption ◽  
Nitrogen Doped ◽  
Large Depth ◽  
End Products ◽  
Boron Nitrogen ◽  
The Way

The electrophilic borylation of 2,5-diarylpyrazines results in the formation of boron-nitrogen doped dihydroindeno[1,2-<i>b</i>]fluorene which can be synthesized via mildly air-sensitive techniques and the end products handled readily under atmosphereic conditions. Through transmetallation via diarylzinc reagents a series of derivatives were sythesized which show broad absorption profiles that highlight the versatility of this backbone to be used in organic solar cell devices. These compounds can be synthesized in large yields, in alow number of steps and functionalized at many stages along the way providing a large depth of possibilities. Exploratory device paramaters were studied and show PCE of 2%.

Optical Absorption Enhancement in Polymer BHJ thin Film Using Ag Nanostructures: A Simulation Study

2020 ◽  
Vol 16 (4) ◽  
pp. 556-567
Author(s):  
Asma Khalil ◽  
Zubair Ahmad ◽  
Farid Touati ◽  
Mohamed Masmoudi
Keyword(s):  
Absorption Spectrum ◽  
Solar Cell ◽  
Methyl Ester ◽  
Butyric Acid ◽  
Organic Solar Cell ◽  
Short Circuit ◽  
Acid Methyl Ester ◽  
Short Circuit Current ◽  
Acid Methyl ◽  
Butyric Acid Methyl Ester

Background: The photo-absorption and light trapping through the different layers of the organic solar cell structures are a growing concern now-a-days as it affects dramatically the overall efficiency of the cells. In fact, selecting the right material combination is a key factor in increasing the efficiency in the layers. In addition to good absorption properties, insertion of nanostructures has been proved in recent researches to affect significantly the light trapping inside the organic solar cell. All these factors are determined to expand the absorption spectrum and tailor it to a wider spectrum. Objective: The purpose of this investigation is to explore the consequence of the incorporation of the Ag nanostructures, with different sizes and structures, on the photo absorption of the organic BHJ thin films. Methods: Through a three-dimensional Maxwell solver software, Lumerical FDTD, a simulation and comparison of the optical absorption of the three famous organic materials blends poly(3- hexylthiophene): phenyl C71 butyric acid methyl ester (P3HT:PCBM), poly[N-9″-heptadecanyl-2,7- carbazole-alt-5,5-(4′,7′-di-2-thienyl-2′,1′,3′-benzothiadiazole)]: phenyl C71 butyric acid methyl ester (PCDTBT:PCBM) and poly[2,6-(4,4-bis-(2-ethylhexyl)-4H-cyclopenta[2,1-b;3,4-b′]dithiophene)-alt- 4,7-(2,1,3-benzothiadiazole)]: phenyl C71 butyric acid methyl ester (PCDPDTBT:PCBM) has been conducted. Furthermore, FDTD simulation study of the incorporation of nanoparticles structures with different sizes, in different locations and concentrations through a bulk heterojunction organic solar cell structure has also been performed. Results: It has been demonstrated that embedding nanostructures in different locations of the cell, specifically in the active layer and the hole transporting layer had a considerable effect of widening the absorption spectrum and increasing the short circuit current. The effect of incorporation the nanostructures in the active layer has been proved to be greater than in the HTL. Furthermore, the comparison results showed that, PCDTBT:PCBM is no more advantageous over P3HT:PCBM and PCPDTBT:PCBM, and P3HT:PCBM took the lead and showed better performance in terms of absorption spectrum and short circuit current value. Conclusion: This work revealed the significant effect of size, location and concentration of the Ag nanostructures while incorporated in the organic solar cell. In fact, embedding nanostructures in the solar cell widen the absorption spectrum and increases the short circuit current, this result has been proven to be significant only when the nanostructures are inserted in the active layer following specific dimensions and structures.

Determining the exciton diffusion length of copper phthalocyanine in operating planar-heterojunction organic solar cells

2020 ◽  
Vol 89 (3) ◽  
pp. 30201 ◽  
Author(s):  
Xi Guan ◽  
Shiyu Wang ◽  
Wenxing Liu ◽  
Dashan Qin ◽  
Dayan Ban
Keyword(s):  
Solar Cells ◽  
Organic Solar Cells ◽  
Diffusion Length ◽  
Copper Phthalocyanine ◽  
Short Circuit ◽  
Thick Layer ◽  
Short Circuit Current ◽  
Short Circuit Current Density ◽  
Exciton Diffusion ◽  
Exciton Diffusion Length

Organic solar cells based on planar copper phthalocyanine (CuPc)/C60 heterojunction have been characterized, in which a 2 nm-thick layer of bathocuproine (BCP) is inserted into the CuPc layer. The thin layer of BCP allows hole current to tunnel it through but blocks the exciton diffusion, thereby altering the steady-state exciton profile in the CuPc zone (zone 1) sandwiched between BCP and C60. The short-circuit current density (JSC) of device is limited by the hole-exciton scattering effect at the BCP/CuPc (zone 1) interface. Based on the variation of JSC with the width of zone 1, the exciton diffusion length of CuPc is deduced to be 12.5–15 nm. The current research provides an easy and helpful method to determine the exciton diffusion lengths of organic electron donors.

Additive-induced Miscibility Regulation and Hierarchical Morphology Enables 17.5% Binary Organic Solar Cells

2021 ◽  
Author(s):  
Jie Lv ◽  
Hua Tang ◽  
Jiaming Huang ◽  
Cenqi Yan ◽  
Kuan Liu ◽  
...  
Keyword(s):  
Solar Cells ◽  
Solar Cell ◽  
Organic Solar Cells ◽  
Organic Solar Cell ◽  
Power Conversion ◽  
Charge Trapping ◽  
Free Charge ◽  
Charge Generation ◽  
Low Charge ◽  
Hierarchical Morphology

Due to the barrierless free charge generation, low charge trapping, and high charge mobilities, the PM6:Y6 organic solar cell (OSC) achieves excellent power conversion efficiency (PCE) of 15.7%. However, the...

scholarly journals CdTe-Based Thin Film Solar Cells: Past, Present and Future

Energies ◽  
2021 ◽  
Vol 14 (6) ◽  
pp. 1684
Author(s):  
Alessandro Romeo ◽  
Elisa Artegiani
Keyword(s):  
Thin Film ◽  
Solar Cells ◽  
Solar Cell ◽  
Short Circuit ◽  
Short Circuit Current ◽  
Short Circuit Current Density ◽  
Open Circuit ◽  
Early Years ◽  
Solar Cell Efficiency ◽  
Cell Efficiency

CdTe is a very robust and chemically stable material and for this reason its related solar cell thin film photovoltaic technology is now the only thin film technology in the first 10 top producers in the world. CdTe has an optimum band gap for the Schockley-Queisser limit and could deliver very high efficiencies as single junction device of more than 32%, with an open circuit voltage of 1 V and a short circuit current density exceeding 30 mA/cm2. CdTe solar cells were introduced at the beginning of the 70s and they have been studied and implemented particularly in the last 30 years. The strong improvement in efficiency in the last 5 years was obtained by a new redesign of the CdTe solar cell device reaching a single solar cell efficiency of 22.1% and a module efficiency of 19%. In this paper we describe the fabrication process following the history of the solar cell as it was developed in the early years up to the latest development and changes. Moreover the paper also presents future possible alternative absorbers and discusses the only apparently controversial environmental impacts of this fantastic technology.

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