Stereoselective synthesis of 4-substituted-cyclic sulfamidate-5-carboxylates by asymmetric transfer hydrogenation accompanied by dynamic kinetic resolution and applications to concise stereoselective syntheses of (−)-epi-cytoxazone and the taxotere side-chain

2014 ◽  
Vol 50 (89) ◽  
pp. 13706-13709 ◽  
Author(s):  
Jin-ah Kim ◽  
Yeon Ji Seo ◽  
Soyeong Kang ◽  
Juae Han ◽  
Hyeon-Kyu Lee
Keyword(s):  
Kinetic Resolution ◽  
Stereoselective Synthesis ◽  
Transfer Hydrogenation ◽  
Side Chain ◽  
Asymmetric Transfer Hydrogenation ◽  
Dynamic Kinetic Resolution ◽  
Stereoselective Syntheses

DKR driven, asymmetric transfer hydrogenations of cyclic sulfamidate imine-5-carboxylates were developed.

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