Hydride transfer from NADH analogues to a nonheme manganese(iv)–oxo complex via rate-determining electron transfer

Heejung Yoon; Yong-Min Lee; Wonwoo Nam; Shunichi Fukuzumi

doi:10.1039/c4cc05313c

Hydride transfer from NADH analogues to a nonheme manganese(iv)–oxo complex via rate-determining electron transfer

Chemical Communications ◽

10.1039/c4cc05313c ◽

2014 ◽

Vol 50 (85) ◽

pp. 12944-12946 ◽

Cited By ~ 10

Author(s):

Heejung Yoon ◽

Yong-Min Lee ◽

Wonwoo Nam ◽

Shunichi Fukuzumi

Keyword(s):

Electron Transfer ◽

Charge Transfer ◽

Isotope Effect ◽

Kinetic Isotope Effect ◽

Hydride Transfer ◽

Charge Transfer Complexes ◽

Kinetic Isotope ◽

Transfer Step

Hydride transfer from NADH analogues to a nonheme Mn(iv)–oxo complex, [(Bn-TPEN)MnIV(O)]2+, proceeds via a rate-determining electron transfer step with no deuterium kinetic isotope effect (KIE = 1.0 ± 0.1) and via charge-transfer complexes formed in the reactions of Mn(iv)–oxo and NADH analogues.

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ChemInform Abstract: Electron Transfer in Reactions of Ketones with Organolithium Reagents. A 14C Kinetic Isotope Effect Probe.

ChemInform ◽

10.1002/chin.198744090 ◽

1987 ◽

Vol 18 (44) ◽

Author(s):

H. YAMATAKA ◽

N. FUJIMURA ◽

Y. KAWAFUJI ◽

T. HANAFUSA

Keyword(s):

Electron Transfer ◽

Isotope Effect ◽

Kinetic Isotope Effect ◽

Kinetic Isotope ◽

Organolithium Reagents

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Intramolecular kinetic isotope effect in hydride transfer from dihydroacridine to a quinolinium ion. Rejection of a proposed two-step mechanism with a kinetically significant intermediate

Organic & Biomolecular Chemistry ◽

10.1039/b806869k ◽

2008 ◽

Vol 6 (18) ◽

pp. 3349 ◽

Cited By ~ 15

Author(s):

Charles L. Perrin ◽

Chen Zhao

Keyword(s):

Isotope Effect ◽

Kinetic Isotope Effect ◽

Hydride Transfer ◽

Kinetic Isotope ◽

Ion Rejection ◽

Step Mechanism

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Brønsted Acid-Promoted C–H Bond Cleavage via Electron Transfer from Toluene Derivatives to a Protonated Nonheme Iron(IV)-Oxo Complex with No Kinetic Isotope Effect

Journal of the American Chemical Society ◽

10.1021/ja311662w ◽

2013 ◽

Vol 135 (13) ◽

pp. 5052-5061 ◽

Cited By ~ 79

Author(s):

Jiyun Park ◽

Yong-Min Lee ◽

Wonwoo Nam ◽

Shunichi Fukuzumi

Keyword(s):

Electron Transfer ◽

Isotope Effect ◽

Kinetic Isotope Effect ◽

Bond Cleavage ◽

Nonheme Iron ◽

Bronsted Acid ◽

Brønsted Acid ◽

Kinetic Isotope ◽

Brönsted Acid

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Temperature dependence of the primary kinetic isotope effect for hydride transfer mediated by a NAD(P)H-model; discrimination between bent and linear transition states

Recueil des Travaux Chimiques des Pays-Bas ◽

10.1002/recl.19831020612 ◽

2010 ◽

Vol 102 (6) ◽

pp. 339-340 ◽

Cited By ~ 7

Author(s):

W. van Gerresheim ◽

J. W. Verhoeven

Keyword(s):

Temperature Dependence ◽

Isotope Effect ◽

Kinetic Isotope Effect ◽

Transition States ◽

Hydride Transfer ◽

Model Discrimination ◽

Kinetic Isotope

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Conversion and Origin of Normal and Abnormal Temperature Dependences of Kinetic Isotope Effect in Hydride Transfer Reactions

The Journal of Organic Chemistry ◽

10.1021/jo3005952 ◽

2012 ◽

Vol 77 (10) ◽

pp. 4774-4783 ◽

Cited By ~ 12

Author(s):

Xiao-Qing Zhu ◽

Xiu-Tao Li ◽

Su-Hui Han ◽

Lian-Rui Mei

Keyword(s):

Isotope Effect ◽

Kinetic Isotope Effect ◽

Hydride Transfer ◽

Transfer Reactions ◽

Kinetic Isotope ◽

Temperature Dependences ◽

Hydride Transfer Reactions ◽

Abnormal Temperature

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Proton-Coupled Electron Transfer from Sulfur: A S-H/S-D Kinetic Isotope Effect of ≥31.1

Angewandte Chemie ◽

10.1002/1521-3757(20001117)112:22<4267::aid-ange4267>3.0.co;2-5 ◽

2000 ◽

Vol 112 (22) ◽

pp. 4267-4270 ◽

Cited By ~ 6

Author(s):

My-Hang V. Huynh ◽

Peter S. White ◽

Thomas J. Meyer

Keyword(s):

Electron Transfer ◽

Isotope Effect ◽

Kinetic Isotope Effect ◽

Proton Coupled Electron Transfer ◽

Kinetic Isotope

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Is There a Deuterium Kinetic Isotope Effect in the One-Electron Transfer from 1-Benzyl-1,4-dihydronicotinamide to 9-Fluorenylidenemalononitrile?

The Journal of Organic Chemistry ◽

10.1021/jo000651d ◽

2000 ◽

Vol 65 (21) ◽

pp. 7213-7214 ◽

Cited By ~ 2

Author(s):

Agnès Anne ◽

Jacques Moiroux ◽

Jean-Michel Savéant

Keyword(s):

Electron Transfer ◽

Isotope Effect ◽

Kinetic Isotope Effect ◽

Kinetic Isotope ◽

The One

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Proton-Coupled Electron Transfer from Nitrogen. A N−H/N−D Kinetic Isotope Effect of 41.4

Journal of the American Chemical Society ◽

10.1021/ja984325f ◽

1999 ◽

Vol 121 (18) ◽

pp. 4530-4531 ◽

Cited By ~ 17

Author(s):

My Hang V. Huynh ◽

Thomas J. Meyer ◽

Peter S. White

Keyword(s):

Electron Transfer ◽

Isotope Effect ◽

Kinetic Isotope Effect ◽

Proton Coupled Electron Transfer ◽

Kinetic Isotope

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ChemInform Abstract: Hydride Transfer in the Oxidation of Alcohols by ((bpy)2(py)Ru(O))2+. A kH/kD Kinetic Isotope Effect of 50.

ChemInform ◽

10.1002/chin.198723086 ◽

1987 ◽

Vol 18 (23) ◽

Author(s):

L. ROECKER ◽

T. J. MEYER

Keyword(s):

Isotope Effect ◽

Kinetic Isotope Effect ◽

Hydride Transfer ◽

Kinetic Isotope ◽

Oxidation Of Alcohols

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Proton-Coupled Electron Transfer from Sulfur: A S-H/S-D Kinetic Isotope Effect of ≥31.1

Angewandte Chemie International Edition ◽

10.1002/1521-3773(20001117)39:22<4101::aid-anie4101>3.0.co;2-e ◽

2000 ◽

Vol 39 (22) ◽

pp. 4101-4104 ◽

Cited By ~ 20

Author(s):

My-Hang V. Huynh ◽

Peter S. White ◽

Thomas J. Meyer

Keyword(s):

Electron Transfer ◽

Isotope Effect ◽

Kinetic Isotope Effect ◽

Proton Coupled Electron Transfer ◽

Kinetic Isotope

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