Experimental and theoretical evidence that electrostatics governs easy-axis orientation in DyIII-based molecular chains

2014 ◽  
Vol 50 (87) ◽  
pp. 13346-13348 ◽  
Author(s):  
Julie Jung ◽  
François Le Natur ◽  
Olivier Cador ◽  
Fabrice Pointillart ◽  
Guillaume Calvez ◽  
...  

Magnetic slow relaxation is observed in a DyIII-based molecular chain and the magnetic easy-axis is determined via single-crystal magnetometry and ab initio calculations.

2005 ◽  
Vol 97 (10) ◽  
pp. 10N115 ◽  
Author(s):  
A. Berger ◽  
E. Marinero ◽  
M. Doerner ◽  
X. Bian ◽  
K. Tang ◽  
...  

2021 ◽  
Vol 242 (1) ◽  
Author(s):  
K. Szymański ◽  
W. Olszewski ◽  
P. Butkiewicz ◽  
M. Biernacka ◽  
D. Satuła ◽  
...  

AbstractMössbauer measurements on single crystal absorbers at room and at low temperatures were performed. The results are fully consistent with previously published reports by other groups. Spectra of single crystals were simultaneously analyzed including magnetic dipole and electric quadrupole interactions. The analysis shows that there is a small component of magnetic moments perpendicular to the magnetic easy axis. Mössbauer data seem not agree with commonly accepted ferrimagnetic structure of GaFeO3.


2017 ◽  
Vol 72 (5) ◽  
pp. 449-455 ◽  
Author(s):  
Mehmet Bayirli ◽  
Oznur Karaagac ◽  
Hakan Kockar ◽  
Mursel Alper

AbstractThe magnetic textures for the produced magnetic materials are important concepts in accordance with technical applications. Therefore, the aim of this article is to determine 2D magnetic textures of electrodeposited Co–Cu films by the measurement of hysteresis loops at the incremented angles. For that, Co–Cu films were deposited with different Co2+ in the electrolyte. In addition, the easy-axis orientation in the films from the squareness values of the angles, Mp(β) obtained by the hysteresis loops have been numerically studied using the Fourier series analysis. The differences observed in the magnetic easy-axis distributions were attributed to changes of the incorporation of Co in the films with the change of Co2+ in the electrolyte. The coefficients of Fourier series (A0 and A2n ) were also computed for 2D films. It is seen that a systematic and small decrease in A0 and an obvious decrease in A2n (n=1) were observed with increasing incorporated Co in the films. Results imply that interactions cause slightly demagnetization effect accordance with higher incorporation of Co in the films. Furthermore, the crystal structure of the Co–Cu films analysed by X-ray diffraction revealed that the films have dominantly face-centred cubic structure. Film contents analysed by energy-dispersive X-ray spectroscopy and film morphologies observed by scanning electron microscope also support the magnetic texture analysis results found by numerical computation.


2012 ◽  
Vol 271-272 ◽  
pp. 343-346 ◽  
Author(s):  
Wen Feng Liu ◽  
Kai Zhang ◽  
Hai Jie Zhang

Mo/NdFeB/Mo thin flms were deposited by dc-magnetron sputtering onto Si substrates, then were annealed at 650 °C for 30 min. Nanostructured Mo/NdFeB/Mo films were successfully obtained with the magnetic easy axis of NdFeB perpendicular to the film plane. It was found that the c-axis orientation depends on the NdFeB sputter power. Good c-axis orientation was obtained at 40W NdFeB sputter power. Meanwhile, Mo layer can not only induce the c-axis orientation of NdFeB, but also improve the crystallization of NdFeB grains.


2014 ◽  
Vol 50 (77) ◽  
pp. 11418-11420 ◽  
Author(s):  
Shan-Shan Liu ◽  
Joseph W. Ziller ◽  
Yi-Quan Zhang ◽  
Bing-Wu Wang ◽  
William J. Evans ◽  
...  

The first example of a lanthanide(iii)/π-bonded arene SIM [(C6Me6)Dy(AlCl4)3] is reported and the π-bonded arene is dominant in determining the easy axis orientation shown by ab initio calculations.


2010 ◽  
Vol 65 (4) ◽  
pp. 342-346 ◽  
Author(s):  
Mehmet Bayirli ◽  
Hakan Kockar ◽  
Mursel Alper ◽  
Emrah Cokturen

The determination of texture effects in nickel-cobalt (Ni-Co) films with different thickness, which were obtained by electrodeposition, has been investigated by the measurement of hysteresis loops at different angles. Easy-axis distribution measurements were performed as a function of the squareness Mp(β ) and the correlations were established among the different thicknesses. The composition of Ni- Co films was determined by energy dispersive X-ray spectroscopy. The structural analysis made by X-ray diffraction revealed that all films have a polycrystalline face-centered cubic structure but their texture degrees vary depending on the film thickness. The determination of the easy-axis orientation in 2-D films from the Mp(β ) obtained by the hystersis loops was studied using Fourier series analyses. The coefficient A0 have a value of less then unity while A2 is inversely proportional to the width of the distribution function which may cause the change in the texture preferential orientations. Therefore, the differences observed in the magnetic easy-axis distributions were attributed to the changes in texture orientations caused by the compositional differences at different thicknesses of the polycrystalline films.


2007 ◽  
Vol 43 (6) ◽  
pp. 3022-3024 ◽  
Author(s):  
A. Dourlat ◽  
C. Gourdon ◽  
V. Jeudy ◽  
C. Testelin ◽  
K. Khazen ◽  
...  

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