An efficient triazole-pyridine-bistetrazolate platform for highly luminescent lanthanide complexes

2014 ◽  
Vol 50 (71) ◽  
pp. 10323-10326 ◽  
Author(s):  
S. Di Pietro ◽  
D. Imbert ◽  
M. Mazzanti
Keyword(s):  
Solid State ◽  
Quantum Yield ◽  
Lanthanide Complexes ◽  
Polymeric Matrix ◽  
Luminescence Quantum Yield

Two new triazole-pyridine-bistetrazolate ligands were synthesized via a versatile procedure that allows for further derivatization; their lanthanide complexes are highly luminescent in the solid state and in a PVA polymeric matrix with measured values for the luminescence quantum yield of 70(7) and 98(9)% for EuIII and TbIII, respectively.

scholarly journals Listening to Lanthanide Complexes: Determination of the Intrinsic Luminescence Quantum Yield by Nonradiative Relaxation

ChemPhysChem ◽  
2008 ◽  
Vol 9 (4) ◽  
pp. 600-606 ◽  
Author(s):  
Yuetao Yang ◽  
Junjia Li ◽  
Xiaojun Liu ◽  
Shuyi Zhang ◽  
Kris Driesen ◽  
...  
Keyword(s):  
Quantum Yield ◽  
Lanthanide Complexes ◽  
Luminescence Quantum Yield ◽  
Nonradiative Relaxation ◽  
Intrinsic Luminescence

A highly luminescent and highly oxygen-sensitive Tb(iii) complex with a tris-aryloxide functionalised 1,4,7-triazacyclononane ligand

2014 ◽  
Vol 50 (99) ◽  
pp. 15737-15739 ◽  
Author(s):  
Hidetaka Nakai ◽  
Takahiro Goto ◽  
Kazuhiro Kitagawa ◽  
Kyoshiro Nonaka ◽  
Takahiro Matsumoto ◽  
...  
Keyword(s):  
Quantum Yield ◽  
Lanthanide Complexes ◽  
Luminescence Quantum Yield ◽  
Oxygen Sensitive

This communication presents a new terbium(iii) complex that shows the highest luminescence quantum yield among the oxygen-sensitive lanthanide complexes.

scholarly journals Zn(II) Heteroleptic Halide Complexes with 2-Halopyridines: Features of Halogen Bonding in Solid State

Molecules ◽  
2021 ◽  
Vol 26 (11) ◽  
pp. 3393
Author(s):  
Mikhail A. Vershinin ◽  
Marianna I. Rakhmanova ◽  
Alexander S. Novikov ◽  
Maxim N. Sokolov ◽  
Sergey A. Adonin
Keyword(s):  
Solid State ◽  
Quantum Yield ◽  
Crystal Packing ◽  
Halogen Bonding ◽  
Molecular Complexes ◽  
Substituted Pyridines ◽  
Halide Complexes

Reactions between Zn(II) dihalides and 2-halogen-substituted pyridines 2-XPy result in a series of heteroleptic molecular complexes [(2-XPy)2ZnY2] (Y = Cl, X = Cl (1), Br (2), I (3); Y = Br, X = Cl (4), Br (5), I (6), Y = I, X = Cl (7), Br (8), and I (9)). Moreover, 1–7 are isostructural (triclinic), while 8 and 9 are monoclinic. In all cases, halogen bonding plays an important role in formation of crystal packing. Moreover, 1–9 demonstrate luminescence in asolid state; for the best emitting complexes, quantum yield (QY) exceeds 21%.

Erbium-activated modified silica glasses with high 4I13/2 luminescence quantum yield

2006 ◽  
Vol 28 (11) ◽  
pp. 1325-1328 ◽  
Author(s):  
S.N.B. Bhaktha ◽  
B. Boulard ◽  
S. Chaussedent ◽  
A. Chiappini ◽  
A. Chiasera ◽  
...  
Keyword(s):  
Quantum Yield ◽  
Luminescence Quantum Yield ◽  
Modified Silica ◽  
Silica Glasses

scholarly journals Diverse Coordination Numbers and Geometries in Pyridyl Adducts of Lanthanide(III) Complexes Based on β-Diketonate

Inorganics ◽  
2021 ◽  
Vol 9 (10) ◽  
pp. 74
Author(s):  
Franz A. Mautner ◽  
Florian Bierbaumer ◽  
Roland C. Fischer ◽  
Ana Torvisco ◽  
Ramon Vicente ◽  
...  
Keyword(s):  
Rare Earth ◽  
Solid State ◽  
Quantum Yield ◽  
Rare Earth Complexes ◽  
Luminescence Spectra ◽  
Excitation Wavelength ◽  
Coordination Numbers ◽  
State Luminescence

Ten mononuclear rare earth complexes of formula [La(btfa)3(H2O)2] (1), [La(btfa)3(4,4′-Mt2bipy)] (2), [La(btfa)3(4,4′-Me2bipy)2] (3), [La(btfa)3(5,5′-Me2bipy)2] (4), [La(btfa)3(terpy)] (5), [La(btfa)3(phen)(EtOH)] (6), [La(btfa)3(4,4′-Me2bipy)(EtOH)] (7), [La(btfa)3(2-benzpy)(MeOH)] (8), [Tb(btfa)3(4,4′-Me2bipy)] (9) and (Hpy)[Eu(btfa)4] (10), where btfa = 4,4,4-trifuoro-1-phenylbutane-1,3-dionato anion, 4,4′-Mt2bipy = 4,4′-dimethoxy-2,2′-bipyridine, 4,4′-Me2bipy = 4,4′-dimethyl-2,2′-bipyridine, 5,5′-Me2bipy = 5,5′-dimethyl-2,2′-bipyridine, terpy = 2,2′:6′,2′-terpyridine, phen = 1,10-phenathroline, 2-benzpy = 2-(2-pyridyl)benzimidazole, Hpy = pyridiniumH+ cation) have been synthesized and structurally characterized. The complexes display coordination numbers (CN) eight for 1, 2, 9, 10, nine for 5, 6, 7, 8 and ten for 3 and 4. The solid-state luminescence spectra of Tb-9 and Eu-10 complexes showed the same characteristic bands predicted from the Tb(III) and Eu(III) ions. The Overall Quantum Yield measured (ϕTOT) at the excitation wavelength of 371 nm for both compounds yielded 1.04% for 9 and up to 34.56% for 10.

Synthesis of CdS-Capped CdSe Nanocrystals without any Poisonous Materials

2014 ◽  
Vol 981 ◽  
pp. 806-809
Author(s):  
Wu Lei Zhou ◽  
Tuo Cai ◽  
Yun Chen ◽  
Xuan Lin Chen ◽  
Yu Qiu Qu ◽  
...  
Keyword(s):  
Aqueous Solution ◽  
Quantum Yield ◽  
Aqueous Medium ◽  
Laser Irradiation ◽  
Absorption Spectroscopy ◽  
Photoluminescence Spectroscopy ◽  
Luminescence Quantum Yield ◽  
Cdse Nanocrystals ◽  
Core Shell ◽  
Photo Stability

CdS-capped CdSe nanocrystals (NCs) which show high luminescence quantum yield are synthesized without any Poisonous Materials in aqueous solution. The synthesis in an aqueous medium without any poisonous materials is attached importance to. The absorption spectroscopy and photoluminescence spectroscopy are employed to analyze the NCs. It takes 78s that the intensity decreases to the half for bare CdSe NCs, but 442s for CdSe/CdS core/shell NCs. The photo stability of CdSe NCs under 325nm laser irradiation is enhanced greatly after CdS overcoating.

Gold Doping of Silver Nanoclusters: A 26-Fold Enhancement in the Luminescence Quantum Yield

2016 ◽  
Vol 128 (19) ◽  
pp. 5843-5847 ◽  
Author(s):  
Giada Soldan ◽  
Maha A. Aljuhani ◽  
Megalamane S. Bootharaju ◽  
Lina G. AbdulHalim ◽  
Manas R. Parida ◽  
...  
Keyword(s):  
Quantum Yield ◽  
Silver Nanoclusters ◽  
Luminescence Quantum Yield ◽  
Gold Doping

Synthesis, photoluminescence and Judd–Ofelt analysis of red LiGd5P2O13 : Eu3+ phosphors for white LEDs

RSC Advances ◽  
2015 ◽  
Vol 5 (67) ◽  
pp. 54622-54628 ◽  
Author(s):  
Xinguo Zhang ◽  
Liya Zhou ◽  
Qi Pang ◽  
Menglian Gong
Keyword(s):  
Thermal Stability ◽  
Solid State ◽  
Quantum Yield ◽  
Solid State Reaction ◽  
Red Light ◽  
Solid State Reaction Method ◽  
Reaction Method ◽  
White Leds ◽  
Good Thermal Stability ◽  
Red Phosphors

LiGd5P2O13 : Eu3+ red phosphors were prepared by solid-state reaction method. Phosphors could be efficiently excited by NUV/blue light and emit pure-red light. LiGd5P2O13 : Eu3+ shows good thermal stability with quantum yield of 46.5%.

Facile preparation of solid-state fluorescent carbon dots with high fluorescence quantum yield and application in rapid latent fingerprints detection

2021 ◽  
Author(s):  
Hai-Jiao Wang ◽  
Wan-Yi Hou ◽  
Jing Kang ◽  
Xin-Yu Zhai ◽  
Hongli Chen ◽  
...  
Keyword(s):  
Solid State ◽  
Quantum Yield ◽  
Fluorescence Quantum Yield ◽  
Latent Fingerprints ◽  
Energy Resonance ◽  
Facile Preparation ◽  
High Fluorescence ◽  
Fluorescent Carbon Dots ◽  
High Fluorescence Quantum Yield ◽  
Resonance Transfer

Due to the direct π - π interaction and excessive energy resonance transfer, it is very challenging to prepare CDs with high fluorescence quantum yield (QY) in solid state. In...

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