High-yield photolytic generation of brominated single-walled carbon nanotubes and their application for gas sensing

2014 ◽  
Vol 50 (78) ◽  
pp. 11568-11571 ◽  
Author(s):  
D. Hines ◽  
M. H. Rümmeli ◽  
D. Adebimpe ◽  
D. L. Akins
Keyword(s):  
Carbon Nanotubes ◽  
Gas Sensing ◽  
Single Walled Carbon Nanotubes ◽  
High Yield ◽  
Single Walled Carbon ◽  
Walled Carbon Nanotubes

We present a facile and efficient photobromination technique for the covalent sidewall functionalization of SWNT using N-bromosuccinamide as the bromine source.

Unravelling the Mechanisms Behind Mixed Catalysts for the High Yield Production of Single-Walled Carbon Nanotubes

ACS Nano ◽  
2009 ◽  
Vol 3 (12) ◽  
pp. 3839-3844 ◽  
Author(s):  
Sailaja Tetali ◽  
Mujtaba Zaka ◽  
Ronny Schönfelder ◽  
Alicja Bachmatiuk ◽  
Felix Börrnert ◽  
...  
Keyword(s):  
Carbon Nanotubes ◽  
Single Walled Carbon Nanotubes ◽  
High Yield ◽  
Single Walled Carbon ◽  
Yield Production ◽  
Walled Carbon Nanotubes ◽  
High Yield Production

Effects of the Molecular Weight of PCz on Selective Extraction of Large-Diameter Semiconducting Single-Walled Carbon Nanotubes

2021 ◽  
Vol 69 ◽  
pp. 11-21
Author(s):  
Ping Zhang ◽  
Wen Hui Yi ◽  
Bai Lei ◽  
Jin Feng Zhou ◽  
Yi Long Tian ◽  
...  
Keyword(s):  
Carbon Nanotubes ◽  
Molecular Weight ◽  
Arc Discharge ◽  
Large Diameter ◽  
Single Walled Carbon Nanotubes ◽  
Selective Extraction ◽  
High Yield ◽  
Extraction Technology ◽  
Single Walled Carbon ◽  
Walled Carbon Nanotubes

Due to the difficulty in the selective synthesis of semiconductor (s-) and metal (m-) single-walled carbon nanotubes (SWCNTs), we still need to explore the selective extraction technology of s-SWCNTs. Using Poly[9-(1-octylonoyl)-9H-carbazole-2,7-diyl] (PCz) extraction of s-SWCNTs has attracted extensive attention in recent years, because it can selective extraction of large-diameter s-SWCNTs with high purity. However, influence of the molecular weight of this polymer on the s-SWCNTs selective extraction properties remains unclear. In this study, we used PCz with different average molecular weights to study the ability of selective extraction s-SWCNTs from pristine arc discharge carbon nanotubes. Spectra studies indicate that compared to the PCz with lower molecular weight, the PCz with higher molecular weight has better selective extraction ability, and can help to obtain s-SWCNTs with higher purity (>99%) and high yield. FETs devices have been prepared by s-SWCNTs obtained via PCz with higher molecular weight exhibit higher on/off ratio, lower off current and lower subthreshold swing. This work offers a reference of the design and synthesis of PCz polymer that performs sufficient selective ability in extracting s-SWCNTs with promising applications.

3D, covalent and noncovalent hybrid materials based on 3-phenylcoumarin derivatives and single walled carbon nanotubes as gas sensing layers

2020 ◽  
Vol 504 ◽  
pp. 144276 ◽  
Author(s):  
Maxim S. Polyakov ◽  
Victoria N. Ivanova ◽  
Tamara V. Basova ◽  
Andrey A. Saraev ◽  
Baybars Köksoy ◽  
...  
Keyword(s):  
Carbon Nanotubes ◽  
Hybrid Materials ◽  
Gas Sensing ◽  
Single Walled Carbon Nanotubes ◽  
Single Walled Carbon ◽  
Walled Carbon Nanotubes

Gas sensing properties of defect-induced single-walled carbon nanotubes

2016 ◽  
Vol 228 ◽  
pp. 688-692 ◽  
Author(s):  
Jaeseong Kim ◽  
Sun-Woo Choi ◽  
Je-Haeng Lee ◽  
Youngchul Chung ◽  
Young Tae Byun
Keyword(s):  
Carbon Nanotubes ◽  
Gas Sensing ◽  
Single Walled Carbon Nanotubes ◽  
Sensing Properties ◽  
Single Walled Carbon ◽  
Gas Sensing Properties ◽  
Walled Carbon Nanotubes

METHODS FOR DISPERSION AND ALIGNMENT OF SINGLE-WALLED CARBON NANOTUBES AND EFFECTS ON THEIR STRUCTURAL AND ELECTRONIC PROPERTIES

2006 ◽  
Vol 05 (04n05) ◽  
pp. 407-411
Author(s):  
JUN JIAO ◽  
LIFENG DONG ◽  
VACHARA CHIRAYOS ◽  
JOCELYN BUSH ◽  
JAMES HEDBERG
Keyword(s):  
Electron Microscopy ◽  
Carbon Nanotubes ◽  
Sodium Dodecyl ◽  
Single Walled Carbon Nanotubes ◽  
Dielectric Medium ◽  
High Yield ◽  
Single Walled Carbon ◽  
Transmission Electron ◽  
The Individual ◽  
Walled Carbon Nanotubes

Two effective methods for dispersion and alignment of single-walled carbon nanotubes (SWCNTs) were developed. One is the floating-potential dielectrophoresis (FPD) method, which can achieve the alignment of individual SWCNTs between two electrodes with high yield (more than 30%) and high repeatability. The second is the gas blow method. Using the shear forces associated with a rapidly moving fluid, SWCNTs were positioned in a direction corresponding to the flow vector of the fluid. This technique shows great potential for scaling up the displacement of SWCNTs with controlled orientations. Various dispersion agents including ethanol, dichlorobenzene, sodium dodecyl sulfate (SDS) and DNA were investigated with these two methods. It was found that SDS was the most effective dielectric medium used for FPD dispersion and alignment of SWCNTs. The result of electric measurement for the individual SWCNTs aligned between two electrodes suggests that, using the FPD method, both metallic and semiconducting SWCNTs could be aligned between the electrodes. The individual SWCNT resistances measured range from 20 KΩ to 5 MΩ suggesting a high contact resistance between an aligned SWCNT and metal electrodes. High resolution transmission electron microscopy (TEM) and scanning electron microscopy (SEM) characterization reveal DNA molecules wrapped around the SWNCTs after the dispersion process which may affect the intrinsic properties of SWCNTs.

High Yield Methods for Cutting Single-Walled Carbon Nanotubes

2008 ◽  
Author(s):  
Zhenning Gu ◽  
Kirk J. Ziegler ◽  
Howard K. Schmidt ◽  
Zheyi Chen ◽  
Urs Rauwald ◽  
...  
Keyword(s):  
Carbon Nanotubes ◽  
Single Walled Carbon Nanotubes ◽  
High Yield ◽  
Single Walled Carbon ◽  
Walled Carbon Nanotubes
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