Direct catalytic oxyamination of benzene to aniline over Cu(ii) nanoclusters supported on CuCr2O4 spinel nanoparticles via simultaneous activation of C–H and N–H bonds

2014 ◽  
Vol 50 (87) ◽  
pp. 13311-13314 ◽  
Author(s):  
Shankha S. Acharyya ◽  
Shilpi Ghosh ◽  
Rajaram Bal

We report the facile synthesis of a highly efficient, reusable catalyst comprising Cu(ii) nanoclusters supported on CuCr2O4 spinel nanoparticles for the oxyamination of benzene to aniline (H2O2 + NH3) under mild aqueous reaction conditions.

2021 ◽  
Author(s):  
Sudarshan S. Dipake ◽  
Sachin P. Gadekar ◽  
Premkumar B. Thombre ◽  
Machhindra K. Lande ◽  
Anjali S. Rajbhoj ◽  
...  

Synthesis ◽  
2020 ◽  
Author(s):  
Peter Ehlers ◽  
Peter Langer ◽  
Marian Blanco Ponce ◽  
Silvio Parpart ◽  
Alexander Villinger ◽  
...  

AbstractA concise and modular synthesis of pyrrolo[1,2-a][1,6]- and [1,8]naphthyridines by a one-pot two-step reaction consisting of electrophilic acylation followed by an alkyne-carbonyl-metathesis reaction as the final cyclization step is reported. This developed synthetic methodology allows the facile synthesis of these heterocyclic core structures in mainly high overall yields under metal-free conditions. Reaction conditions are carefully optimized and display a novel supplement to access these tricyclic heterocyclic compounds.


Author(s):  
Long Chen ◽  
Shi-Lu Zheng ◽  
Yun-Xiang Zou ◽  
Zhong Wen ◽  
Jiafu Lin ◽  
...  

Facile synthesis of 2-phosphorylated 2H-chromenes has been accomplished herein via a Y(OTf)3-catalyzed dehydrative coupling of 2H-chromene hemiacetals with P(O)-H compounds. This protocol features low catalyst loading, mild reaction conditions, broad...


2021 ◽  
Vol 6 (4) ◽  
pp. 852-857
Author(s):  
Ying Chen ◽  
Yanmei Xin ◽  
Congfei Yao ◽  
Yuqing Miao

2017 ◽  
Vol 19 (8) ◽  
pp. 1855-1860 ◽  
Author(s):  
Hao Tang ◽  
Ning Li ◽  
Fang Chen ◽  
Guangyi Li ◽  
Aiqin Wang ◽  
...  

A sulfated cyclopentanone-formaldehyde condensate was found to be an effective and reusable catalyst for the dehydration of fructose to 5-hydroxymethylfurfural (HMF).


RSC Advances ◽  
2015 ◽  
Vol 5 (61) ◽  
pp. 49295-49300 ◽  
Author(s):  
Handan Pamuk ◽  
Burak Aday ◽  
Fatih Şen ◽  
Muharrem Kaya

Pt NPs@GO has been used for the first time for synthesizing acridinedione from dimedone, aromatic aldehydes and various amines as a catalyst.


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