A highly efficient mesoscopic solar cell based on CH3NH3PbI3−xClxfabricated via sequential solution deposition

2014 ◽  
Vol 50 (83) ◽  
pp. 12458-12461 ◽  
Author(s):  
Yingzhuang Ma ◽  
Lingling Zheng ◽  
Yao-Hsien Chung ◽  
Saisai Chu ◽  
Lixin Xiao ◽  
...  

A mixed halide perovskite of CH3NH3PbI3–xClxis synthesizedviasequential solution deposition by using a mixture of PbCl2and PbI2as the precursor with 11.7% power conversion efficiency for the mesoscopic cell.

2014 ◽  
Vol 2 (46) ◽  
pp. 19653-19659 ◽  
Author(s):  
Jianjun Tian ◽  
Lili Lv ◽  
Chengbin Fei ◽  
Yajie Wang ◽  
Xiaoguang Liu ◽  
...  

The power conversion efficiency of CdS/CdSe sensitized solar cells is increased to 6.33% by doping Mn2+ into the CdSe quantum dot.


Author(s):  
Mohd Quasim Khan ◽  
Khursheed Ahmad

In the last few decades, the energy demand has been increased dramatically. Different forms of energy have utilized to fulfill the energy requirements. Solar energy has been proven an effective and highly efficient energy source which has the potential to fulfill the energy requirements in the future. Previously, various kind of solar cells have been developed. In 2013, organic–inorganic metal halide perovskite materials have emerged as a rising star in the field of photovoltaics. The methyl ammonium lead halide perovskite structures were employed as visible light sensitizer for the development of highly efficient perovskite solar cells (PSCs). In 2018, the highest power conversion efficiency of 23.7% was achieved for methyl ammonium lead halide based PSCs. This obtained highest power conversion efficiency makes them superior over other solar cells. The PSCs can be employed for practical uses, if their long term stability improved by utilizing some novel strategies. In this chapter, we have discussed the optoelectronic properties of the perovskite materials, construction of PSCs and recent advances in the electron transport layers for the fabrication of PSCs.


2021 ◽  
Vol 01 (01) ◽  
pp. 56-57
Author(s):  
Galhenage A. Sewvandi ◽  
◽  
J.T.S.T. Jayawardane ◽  

Solar energy is a commonly used alternate source of energy and it can be utilized based on the principle of the photovoltaic effect. The photovoltaic effect converts sun energy into electrical energy using photovoltaic devices (solar cells). A solar cell device should have high efficiency and a long lifetime to be commercially beneficial. Presently, silicon and thin-film solar cells are widely employed. The crystalline solar cells are more efficient but they are also expensive. Thin-film solar cells are formed by placing one or more thin layers of photovoltaic materials on different substrates. Although these cells have a lower cost, they are also less efficient compared to Si-based solar cells. Organic-inorganic hybrid lead halide perovskite solar cells are one of the most promising low-cost power conversion efficiency technologies that could exceed the 26% threshold. However, the lack of environmental stability and of high lead toxicity are the main bottlenecks that impede the future industrialization and commercialization hybrid lead halide perovskite. Hence It is important to achieve high power conversion efficiency while also maintaining stability and non-toxicity in the development of new lead-free perovskite materials.


2020 ◽  
Vol 8 (34) ◽  
pp. 17756-17764
Author(s):  
Shuai You ◽  
Xiaoyan Xi ◽  
Xin Zhang ◽  
Hanying Wang ◽  
Pingqiang Gao ◽  
...  

Although the power conversion efficiency (PCE) of organometal halide perovskite solar cells (PSCs) has reached 25.2%, control of the crystallization process and its impact on film quality is still one of the main challenges.


Nanoscale ◽  
2019 ◽  
Vol 11 (45) ◽  
pp. 21824-21833 ◽  
Author(s):  
Jyoti V. Patil ◽  
Sawanta S. Mali ◽  
Chang Kook Hong

Controlling the grain size of the organic–inorganic perovskite thin films using thiourea additives now crossing 2 μm size with >20% power conversion efficiency.


2021 ◽  
Vol 11 (1) ◽  
Author(s):  
S. Wageh ◽  
Mahfoudh Raïssi ◽  
Thomas Berthelot ◽  
Matthieu Laurent ◽  
Didier Rousseau ◽  
...  

AbstractPoly(3,4-ethylenedioxythiophene) polystyrene sulfonate (PEDOT:PSS) mixed with single-wall nanotubes (SWNTs) (10:1) and doped with (0.1 M) perchloric acid (HClO4) in a solution-processed film, working as an excellent thin transparent conducting film (TCF) in organic solar cells, was investigated. This new electrode structure can be an outstanding substitute for conventional indium tin oxide (ITO) for applications in flexible solar cells due to the potential of attaining high transparency with enhanced conductivity, good flexibility, and good durability via a low-cost process over a large area. In addition, solution-processed vanadium oxide (VOx) doped with a small amount of PEDOT-PSS(PH1000) can be applied as a hole transport layer (HTL) for achieving high efficiency and stability. From these viewpoints, we investigate the benefit of using printed SWNTs-PEDOT-PSS doped with HClO4 as a transparent conducting electrode in a flexible organic solar cell. Additionally, we applied a VOx-PEDOT-PSS thin film as a hole transporting layer and a blend of PTB7 (polythieno[3,4-b] thiophene/benzodithiophene): PC71BM (phenyl-C71-butyric acid methyl ester) as an active layer in devices. Zinc oxide (ZnO) nanoparticles were applied as an electron transport layer and Ag was used as the top electrode. The proposed solar cell structure showed an enhancement in short-circuit current, power conversion efficiency, and stability relative to a conventional cell based on ITO. This result suggests a great carrier injection throughout the interfacial layer, high conductivity and transparency, as well as firm adherence for the new electrode.


2021 ◽  
Author(s):  
Stav Rahmany ◽  
Lioz Etgar

Much effort has been made to push the power conversion efficiency of perovskite solar cells (PSCs) towards the theoretical limit. Recent studies have shown that post deposition treatment of barrier...


2019 ◽  
Vol 7 (6) ◽  
pp. 2754-2763 ◽  
Author(s):  
Jieming Zhen ◽  
Weiran Zhou ◽  
Muqing Chen ◽  
Bairu Li ◽  
Lingbo Jia ◽  
...  

A novel pyridine-functionalized fullerene derivative (C60-PyP) as an additive in regular bulk heterojunction perovskite (CH3NH3Pbl3) solar cells (PSCs) enables a power conversion efficiency of 19.82% with markedly suppressed hysteresis.


2015 ◽  
Vol 19 (01-03) ◽  
pp. 175-191 ◽  
Author(s):  
Ganesh D. Sharma ◽  
Galateia E. Zervaki ◽  
Kalliopi Ladomenou ◽  
Emmanuel N. Koukaras ◽  
Panagiotis P. Angaridis ◽  
...  

Two porphyrin dyads with the donor-π-acceptor molecular architecture, namely ( ZnP )-[triazine-gly]-( H 2 PCOOH ) and ( ZnP )-[triazine-Npip]-( H 2 PCOOH ), which consist of a zinc-metalated porphyrin unit and a free-base porphyrin unit covalently linked at their peripheries to a central triazine group, substituted either by a glycine in the former or a N-piperidine group in the latter, have been synthesized via consecutive amination substitution reactions of cyanuric chloride. The UV-vis absorption spectra and cyclic-voltammetry measurements of the two dyads, as well as theoretical calculations based on Density Functional Theory, suggest that they have suitable frontier orbital energy levels for use as sensitizers in dye-sensitized solar cells. Dye-sensitized solar cells based on ( ZnP )-[triazine-gly]-( H 2 PCOOH ) and ( ZnP )-[triazine-Npip]-( H 2 PCOOH ) have been fabricated, and they were found to exhibit power conversion efficiency values of 5.44 and 4.15%, respectively. Photovoltaic measurements (J–V curves) and incident photon to current conversion efficiency spectra of the two solar cells suggest that the higher power conversion efficiency value of the former solar cell is a result of its enhanced short circuit current, open circuit voltage, and fill factor values, as well as higher dye loading. This is ascribed to the existence of two carboxylic acid anchoring groups in ( ZnP )-[triazine-gly]-( H 2 PCOOH ), compared to one carboxylic acid group in ( ZnP )-[triazine-Npip]-( H 2 PCOOH ), which leads to a more effective binding onto the TiO 2 photoanode. Electrochemical impedance spectra show evidence that the ( ZnP )-[triazine-gly]-( H 2 PCOOH ) based solar cell exhibits a longer electron lifetime and more effective suppression of charge recombination reactions between the injected electrons and electrolyte.


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