Metal–organic frameworks as stationary phases for mixed-mode separation applications

2014 ◽  
Vol 50 (28) ◽  
pp. 3735 ◽  
Author(s):  
Chris S. Hawes ◽  
Yada Nolvachai ◽  
Chadin Kulsing ◽  
Gregory P. Knowles ◽  
Alan L. Chaffee ◽  
...  
Keyword(s):  
Mixed Mode ◽  
Stationary Phases ◽  
Metal Organic Frameworks ◽  
Mode Separation ◽  
Metal Organic

Metal-organic frameworks as stationary phases for chromatography and solid phase extraction: A review

2022 ◽  
Vol 455 ◽  
pp. 214364
Author(s):  
Anna A. Kotova ◽  
Didier Thiebaut ◽  
Jérôme Vial ◽  
Antoine Tissot ◽  
Christian Serre
Keyword(s):  
Solid Phase Extraction ◽  
Solid Phase ◽  
Stationary Phases ◽  
Metal Organic Frameworks ◽  
Phase Extraction ◽  
Metal Organic

scholarly journals Metal-Organic Frameworks in Green Analytical Chemistry

Separations ◽  
2019 ◽  
Vol 6 (3) ◽  
pp. 33 ◽  
Author(s):  
Rocío-Bautista ◽  
Taima-Mancera ◽  
Pasán ◽  
Pino
Keyword(s):  
Analytical Chemistry ◽  
Thermal Stability ◽  
Hybrid Materials ◽  
Stationary Phases ◽  
Metal Organic Frameworks ◽  
Green Analytical Chemistry ◽  
Surface Areas ◽  
Form Part ◽  
Metal Organic ◽  
Sorbent Materials

Metal-organic frameworks (MOFs) are porous hybrid materials composed of metal ions and organic linkers, characterized by their crystallinity and by the highest known surface areas. MOFs structures present accessible cages, tunnels and modifiable pores, together with adequate mechanical and thermal stability. Their outstanding properties have led to their recognition as revolutionary materials in recent years. Analytical chemistry has also benefited from the potential of MOF applications. MOFs succeed as sorbent materials in extraction and microextraction procedures, as sensors, and as stationary or pseudo-stationary phases in chromatographic systems. To date, around 100 different MOFs form part of those analytical applications. This review intends to give an overview on the use of MOFs in analytical chemistry in recent years (2017–2019) within the framework of green analytical chemistry requirements, with a particular emphasis on possible toxicity issues of neat MOFs and trends to ensure green approaches in their preparation.

Applications of metal-organic frameworks as stationary phases in chromatography

2013 ◽  
Vol 50 ◽  
pp. 33-41 ◽  
Author(s):  
Yuebo Yu ◽  
Yuqian Ren ◽  
Wei Shen ◽  
Huimin Deng ◽  
Zhiqiang Gao
Keyword(s):  
Stationary Phases ◽  
Metal Organic Frameworks ◽  
Metal Organic

Regulating metal–organic frameworks as stationary phases and absorbents for analytical separations

2021 ◽  
Vol 13 (11) ◽  
pp. 1318-1331
Author(s):  
Sha-Sha Meng ◽  
Ming Xu ◽  
Ting Han ◽  
Yu-Hao Gu ◽  
Zhi-Yuan Gu
Keyword(s):  
Stationary Phases ◽  
Metal Organic Frameworks ◽  
Metal Centers ◽  
Analytical Separations ◽  
Metal Organic ◽  
Coordination Bonds

Metal–organic frameworks (MOFs) are highly ordered framework systems composed of metal centers and organic linkers formed through coordination bonds.

scholarly journals UiO-66@SiO2 core–shell microparticles as stationary phases for the separation of small organic molecules

The Analyst ◽  
2017 ◽  
Vol 142 (3) ◽  
pp. 517-524 ◽  
Author(s):  
R. D. Arrua ◽  
A. Peristyy ◽  
P. N. Nesterenko ◽  
A. Das ◽  
D. M. D'Alessandro ◽  
...  
Keyword(s):  
Small Molecules ◽  
Organic Molecules ◽  
Stationary Phases ◽  
Metal Organic Frameworks ◽  
Core Shell ◽  
Small Organic Molecules ◽  
Separation Selectivity ◽  
Metal Organic

Microparticles decorated with metal–organic frameworks exhibited a unique flow-dependent separation selectivity (FDSS) effect for the isocratic separation of small molecules.

Metal-Organic Frameworks

2021 ◽  
Author(s):  
Lars Öhrström ◽  
Francoise M. Amombo Noa
Keyword(s):  
Metal Organic Frameworks ◽  
Metal Organic

Substrate templated synthesis of single-phase and uniform Zr-porphyrin-based metal–organic frameworks

2020 ◽  
Vol 7 (1) ◽  
pp. 221-231
Author(s):  
Seong Won Hong ◽  
Ju Won Paik ◽  
Dongju Seo ◽  
Jae-Min Oh ◽  
Young Kyu Jeong ◽  
...  
Keyword(s):  
Chemical Bath Deposition ◽  
Single Phase ◽  
Metal Organic Frameworks ◽  
Templated Synthesis ◽  
Pore Structures ◽  
Phase Pure ◽  
Metal Organic ◽  
Cbd Method

We successfully demonstrate that the chemical bath deposition (CBD) method is a versatile method for synthesizing phase-pure and uniform MOFs by controlling their nucleation stages and pore structures.

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