Simple preparation of positively charged silver nanoparticles for detection of anions by surface-enhanced Raman spectroscopy

The Analyst ◽  
2015 ◽  
Vol 140 (9) ◽  
pp. 2988-2994 ◽  
Author(s):  
A. Stewart ◽  
S. Murray ◽  
S. E. J. Bell
Keyword(s):  
Raman Spectroscopy ◽  
Silver Nanoparticles ◽  
Zeta Potential ◽  
Surface Enhanced Raman Spectroscopy ◽  
Sers Substrates ◽  
Simple Preparation ◽  
Surface Enhanced ◽  
Surface Enhanced Raman ◽  
Positively Charged

Modification of Ag colloids with thiocholine bromide switches the zeta potential from ca. −50 mV to ca. +50 mV, giving SERS substrates which promote adsorption of anions.

scholarly journals Surface-enhanced Raman spectroscopy for the characterization of Vaccinium myrtillus L. bilberries of the Baltic–Nordic regions

2021 ◽  
Author(s):  
Lina Traksele ◽  
Valentinas Snitka
Keyword(s):  
Raman Spectroscopy ◽  
Silver Nanoparticles ◽  
Principal Component ◽  
Surface Enhanced Raman Spectroscopy ◽  
Vaccinium Myrtillus ◽  
Spectral Variation ◽  
Data Set ◽  
Sers Substrates ◽  
Surface Enhanced ◽  
Surface Enhanced Raman

AbstractIn this study, an investigation of the wild bilberries (Vaccinium myrtillus L.) of the different Baltic–Nordic regions using surface-enhanced Raman spectroscopy (SERS) combined with principal component analysis (PCA) is presented. The bilberries were collected in Lithuania, Latvia, Finland and Norway. The set of the SERS spectra of the berry extracts (pH ~ 4) were recorded on the silver nanoparticles based SERS substrates. The SERS spectra of the extracts were acquired using 532 nm laser as an excitation source. The morphology of the SERS substrates was evaluated by scanning electron microscopy (SEM) and the presence of the silver nanoparticles was confirmed by the energy-dispersive X-ray spectroscopy (EDX). The enhancement factor (EF) of the silver SERS substrates was found to be 105. It has been shown that a strong fluorescence background, associated with the phenolic compounds found in bilberries, can be subtracted due to the fluorescence-quenching properties of the silver nanoparticles. Therefore, an application of the SERS technique allowed to observe the characteristic peaks of the bilberries and the PCA tool enabled to evaluate the spectral variation across the entire SERS data set. The results presented in this paper show that the SERS technique coupled with PCA chemometric analysis might serve as a complementary method that allows to identify the country of origin of the bilberries based on the spectral differences.

The development of “fab-chips” as low-cost, sensitive surface-enhanced Raman spectroscopy (SERS) substrates for analytical applications

The Analyst ◽  
2015 ◽  
Vol 140 (3) ◽  
pp. 779-785 ◽  
Author(s):  
Ashley M. Robinson ◽  
Lili Zhao ◽  
Marwa Y. Shah Alam ◽  
Paridhi Bhandari ◽  
Scott G. Harroun ◽  
...  
Keyword(s):  
Raman Spectroscopy ◽  
Silver Nanoparticles ◽  
Chemical Sensing ◽  
Low Cost ◽  
Surface Enhanced Raman Spectroscopy ◽  
Sers Substrates ◽  
Sensing Applications ◽  
Wide Range ◽  
Surface Enhanced ◽  
Surface Enhanced Raman

Modification of metal-coated zari fabric chips with silver nanoparticles results in sensitive, affordable SERS substrates which are useful for a wide range of chemical sensing applications.

Diethyldithiocarbamate (DDTC) induced formation of positively charged silver nanoparticles for rapid in situ identification of inorganic explosives by surface enhanced Raman spectroscopy

RSC Advances ◽  
2016 ◽  
Vol 6 (57) ◽  
pp. 51823-51829 ◽  
Author(s):  
Juan Chen ◽  
Yu-e Shi ◽  
Min Zhang ◽  
Jinhua Zhan
Keyword(s):  
Raman Spectroscopy ◽  
Silver Nanoparticles ◽  
Surface Enhanced Raman Spectroscopy ◽  
Raman Spectrometer ◽  
Surface Enhanced ◽  
Surface Enhanced Raman ◽  
Positively Charged ◽  
Portable Raman

Diethyldithiocarbamate could induce the generation of positively charged silver nanoparticles for rapidin situdetection of the explosives with a portable Raman spectrometer.

Surface enhanced Raman spectroscopy substrates with advanced spectral sensitivity prepared from five years old silver nanoplatelets

2016 ◽  
Vol 09 (06) ◽  
pp. 1642003 ◽  
Author(s):  
Anna A. Semenova ◽  
Eugene A. Goodilin
Keyword(s):  
Raman Spectroscopy ◽  
Silver Nanoparticles ◽  
Spectral Sensitivity ◽  
Surface Enhanced Raman Spectroscopy ◽  
Sers Substrates ◽  
Wide Range ◽  
Surface Enhanced ◽  
Surface Enhanced Raman ◽  
Flexible Applications ◽  
First Time

A new simple approach is suggested to prepare surface enhanced Raman spectroscopy (SERS) substrates with high effectiveness for various laser excitation wavelengths and analytes with different light absorption features by impregnation of porous cellulose materials by a mixture of silver nanoplatelets with a wide range of sizes and anisotropy. The suggested route provides a much better spectral sensitivity and flexible applications since SERS as a phenomenon is essential on the nanometer scale only. The mixing provides always a proper fraction of silver nanoparticles deposited onto the substrate thus guaranteeing the enhancement of Raman signals under given excitation conditions for a wider set of given analytes. The substrates were successfully prepared for the first time from silver nanoplatelets aged for five years. This confirms high chemical and morphological stability of stabilized silver nanoparticles and the ability to use them as precursors for application - ready materials.

Silver oxide model surface improves computational simulation of surface-enhanced Raman spectroscopy on silver nanoparticles

2021 ◽  
Author(s):  
Scott G. Harroun ◽  
Yaoting Zhang ◽  
Tzu-Heng Chen ◽  
Huan-Tsung Chang ◽  
Alexis Vallée-Bélisle
Keyword(s):  
Raman Spectroscopy ◽  
Silver Nanoparticles ◽  
Silver Oxide ◽  
Accurate Result ◽  
Computational Simulation ◽  
Surface Enhanced Raman Spectroscopy ◽  
Model Surface ◽  
Surface Enhanced ◽  
Model Surfaces ◽  
Surface Enhanced Raman

For simulation of SERS on silver nanoparticles, Ag2O can provide a more accurate result than standard model surfaces such as Ag+, Ag, Ag4+ and Ag4.

SERS Tags Derived from Silver Nanoparticles and Aryl Diazonium Salts for Cell Raman Imaging

Nanoscale ◽  
2022 ◽  
Author(s):  
Da Li ◽  
Philippe Nizard ◽  
Delphine Onidas ◽  
Aazdine Lamouri ◽  
Jean Pinson ◽  
...  
Keyword(s):  
Raman Spectroscopy ◽  
Silver Nanoparticles ◽  
Surface Functionalization ◽  
Surface Enhanced Raman Spectroscopy ◽  
Raman Imaging ◽  
Diazonium Salts ◽  
Surface Enhanced ◽  
Surface Enhanced Raman ◽  
Silver Nps ◽  
Sers Tags

The surface functionalization of silver nanoparticles (NPs) by Raman reporters has stimulated a wide interest in recent years for the design of Surface-Enhanced Raman Spectroscopy (SERS) labels. However, silver NPs...

Graphene/silver nanoparticles‐based surface‐enhanced Raman spectroscopy detection platforms: Application in the study of DNA molecules at low pH

2019 ◽  
Vol 50 (12) ◽  
pp. 1849-1860
Author(s):  
Cristina M. Muntean ◽  
Nicoleta E. Dina ◽  
Maria Coroş ◽  
Nicoleta Toşa ◽  
Alexandru I. Turza ◽  
...  
Keyword(s):  
Raman Spectroscopy ◽  
Silver Nanoparticles ◽  
Surface Enhanced Raman Spectroscopy ◽  
Low Ph ◽  
Dna Molecules ◽  
Surface Enhanced ◽  
Surface Enhanced Raman
Sign in / Sign up

Export Citation Format

Share Document