A ternary nanocomposite electrode of polyoxometalate/carbon nanotubes/gold nanoparticles for electrochemical detection of hydrogen peroxide

The Analyst ◽  
2015 ◽  
Vol 140 (3) ◽  
pp. 820-826 ◽  
Author(s):  
Shuyue Guo ◽  
Lin Xu ◽  
Bingbing Xu ◽  
Zhixia Sun ◽  
Lihao Wang

In this work, a nanocomposite film electrode containing polyoxometalate (POM) clusters K6P2W18O62 (P2W18), carbon nanotubes (CNTs) and Au nanoparticles (AuNPs) was fabricated by a layer-by-layer self-assembly technique.

RSC Advances ◽  
2015 ◽  
Vol 5 (70) ◽  
pp. 56583-56589 ◽  
Author(s):  
Yulan Wang ◽  
Dan Wu ◽  
Yong Zhang ◽  
Xiang Ren ◽  
Yaoguang Wang ◽  
...  

In this work, a novel and ultrasensitive label-free electrochemical immunosensor was developed for the quantitative detection of alpha fetoprotein (AFP).


Nanoscale ◽  
2015 ◽  
Vol 7 (45) ◽  
pp. 19118-19128 ◽  
Author(s):  
Yuan Wang ◽  
Hua-Bin Fang ◽  
Yan-Zhen Zheng ◽  
Rongqin Ye ◽  
Xia Tao ◽  
...  

An excellent visible-light-driven photocatalyst composed of well-defined monodisperse Au nanoparticles on ZnO microspheres via a layer-by-layer self-assembly technique is demonstrated.


2013 ◽  
Vol 704 ◽  
pp. 258-263
Author(s):  
Zhao Hao Wang ◽  
Han Cui ◽  
Qi Jin Wan ◽  
Nian Jun Yang

A robust and effective nanocomposite film modified gold electrode based on 2, 3-dimercaptosuccinic acid (DMSA) and Au nanoparticles (AuNPs) was prepared by a method combining self-assembly with underpotential deposition. Direct electron transfer can easily take place between a gold electrode and catalase molecules anchored on AuNPs films. Besides, the CAT/AuNPs/DMSA multilayer film had a relatively rapid and satisfactory response toward H2O2 with a wide linear range from 3.0×106 to 5.86×103 M and a low detection limit of 3.0 μM (S/N = 3). The Michaelis-Menten constant of the immobilized CAT was calculated to be 2.2 mM. The simple CAT/AuNPs/DMSA/Au system can be developed into a H2O2 biosensor.


2016 ◽  
Vol 4 (7) ◽  
pp. 1310-1317 ◽  
Author(s):  
Jialin Zhang ◽  
Zhimin Chen ◽  
Hao Wu ◽  
Feng Wu ◽  
Chunying He ◽  
...  

Binder-free multilayer films composed of phthalocyanine and carbon nanotubes were constructed by the layer-by-layer electrostatic assembly and applied for the electrochemical detection of NO2− and H2O2.


2008 ◽  
Vol 1 ◽  
pp. 1-9 ◽  
Author(s):  
Wei Xue ◽  
Tianhong Cui

We demonstrate a carbon nanotube based high-resolution biosensor for acetylcholine sensing. Carbon nanotubes are deposited on a silicon wafer in a repeated fashion with layer-by-layer nano self-assembly technique. With nano-assembled acetylcholinesterase molecules on the surface, the carbon nanotube biosensor is capable of detecting acetylcholine at an ultra-low concentration of 100 pM. The sensitivity of the acetylcholine sensor is measured as 7.2 µA/decade. The real-time measurement shows the response time of the biosensor is approximately 6 sec. Both the carbon nanotube film and the acetylcholinesterase film are crucial in the sensing process. Due to its high resolution, fast response, small size, and low cost, the carbon nanotube biosensor has tremendous potential for applications in medical research and clinical diagnosis.


RSC Advances ◽  
2014 ◽  
Vol 4 (46) ◽  
pp. 24369-24376 ◽  
Author(s):  
Jiemin Zhao ◽  
Xiaoping Wang ◽  
Yanshen Kuang ◽  
Yufeng Zhang ◽  
Xiaowen Shi ◽  
...  

Alginate (ALG)–lysozyme (LZ) beads were fabricated by a cross-linking process. Negatively charged ALG and positively charged LZ were alternately deposited on the positively charged ALG–LZ beads via a layer-by-layer (LBL) self-assembly technique.


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