Preparation and characterization of luminescent silicone elastomer by thiol–ene “click” chemistry

2014 ◽  
Vol 2 (15) ◽  
pp. 2724-2734 ◽  
Author(s):  
Yujing Zuo ◽  
Haifeng Lu ◽  
Lei Xue ◽  
Xianming Wang ◽  
Liang Ning ◽  
...  

Novel transparent and luminescent silicone elastomers were prepared by thiol–ene chemistry. They show very intense photoluminescence under ultraviolet light and have very high coloric purity.

2019 ◽  
Vol 15 (S359) ◽  
pp. 413-414
Author(s):  
María P. Agüero ◽  
Rubén Díaz ◽  
Mischa Schirmer

AbstractThis work is focused on the characterization of the Seyfert-2 galaxies hosting very large, ultra-luminous narrow-line regions (NLRs) at redshifts z = 0.2−0.34. With a space density of 4.4 Gcp−3 at z ∼ 0.3, these “Low Redshift Lyman-α Blob” (LAB) host galaxies are amongst the rarest objects in the universe, and represent an exceptional and short-lived phenomenon in the life cycle of active galactic nuclei (AGNs). We present the study of GMOS spectra for 13 LAB galaxies covering the rest frame spectral range 3700–6700 Å. Predominantly, the [OIII]λ5007 emission line radial distribution is as widespread as that of the continuum one. The emission line profiles exhibit FWHM between 300–700 Km s−1. In 7 of 13 cases a broad kinematical component is detected with FWHM within the range 600–1100 Km s−1. The exceptionally high [OIII]λ5007 luminosity is responsible for very high equivalent width reaching 1500 Å at the nucleus.


Author(s):  
Mario Vincenzo Russo ◽  
Ivan Notardonato ◽  
Alberto Rosada ◽  
Giuseppe Ianiri ◽  
Pasquale Avino

This paper shows a characterization of the organic and inorganic fraction of river waters (Tiber and Marta) and ores/soil samples collected in the Northern Latium region of Italy for evaluating the anthropogenic/natural source contribution to the environmental pollution of this area. For organic compounds, organochloride volatile compounds in Tiber and Marta rivers were analyzed by two different clean-up methods (i.e., liquid–liquid extraction and static headspace) followed by gas chromatography–electron capture detector (GC-ECD) analysis. The results show very high concentrations of bromoform (up to 1.82 and 3.2 µg L−1 in Tiber and Marta rivers, respectively), due to the presence of greenhouse crops, and of chloroform and tetrachloroethene, due to the presence of handicrafts installations. For the qualitative and quantitative assessment of the inorganic fraction, it is highlighted the use of a nuclear analytical method, instrumental neutron activation analysis, which allows having more information as possible from the sample without performing any chemical-physical pretreatment. The results have evidenced high levels of mercury (mean value 88.6 µg g−1), antimony (77.7 µg g−1), strontium (12,039 µg g−1) and zinc (103 µg g−1), whereas rare earth elements show levels similar to the literature data. Particular consideration is drawn for arsenic (414 µg g−1): the levels found in this paper (ranging between 1 and 5100 µg g−1) explain the high content of such element (as arsenates) in the aquifer, a big issue in this area.


2007 ◽  
Vol 6 (12) ◽  
pp. 2214-2221 ◽  
Author(s):  
Lois M. Douglas ◽  
Li Li ◽  
Yang Yang ◽  
A. M. Dranginis

ABSTRACT The Flo11/Muc1 flocculin has diverse phenotypic effects. Saccharomyces cerevisiae cells of strain background Σ1278b require Flo11p to form pseudohyphae, invade agar, adhere to plastic, and develop biofilms, but they do not flocculate. We show that S. cerevisiae var. diastaticus strains, on the other hand, exhibit Flo11-dependent flocculation and biofilm formation but do not invade agar or form pseudohyphae. In order to study the nature of the Flo11p proteins produced by these two types of strains, we examined secreted Flo11p, encoded by a plasmid-borne gene, in which the glycosylphosphatidylinositol anchor sequences had been replaced by a histidine tag. A protein of approximately 196 kDa was secreted from both strains, which upon purification and concentration, aggregated into a form with a very high molecular mass. When secreted Flo11p was covalently attached to microscopic beads, it conferred the ability to specifically bind to S. cerevisiae var. diastaticus cells, which flocculate, but not to Σ1278b cells, which do not flocculate. This was true for the 196-kDa form as well as the high-molecular-weight form of Flo11p, regardless of the strain source. The coated beads bound to S. cerevisiae var. diastaticus cells expressing FLO11 and failed to bind to cells with a deletion of FLO11, demonstrating a homotypic adhesive mechanism. Flo11p was shown to be a mannoprotein. Bead-to-cell adhesion was inhibited by mannose, which also inhibits Flo11-dependent flocculation in vivo, further suggesting that this in vitro system is a useful model for the study of fungal adhesion.


2008 ◽  
Vol 34 (2-3) ◽  
pp. 229-239 ◽  
Author(s):  
Wen-Hai Zhan ◽  
Jian-Li Hua ◽  
Ying-Hua Jin ◽  
Xin Teng ◽  
He Tian

2003 ◽  
Vol 2 (1) ◽  
pp. 35-39 ◽  
Author(s):  
S. Franck ◽  
M. Cuntz ◽  
W. von Bloh ◽  
C. Bounama

In a previous paper, we showed that Earth-type habitable planets around 47 UMa are in principle possible if a distinct set of conditions is warranted. These conditions include that the Earth-type planets have successfully formed and are orbitally stable and, in addition, that the 47 UMa star–planet system is relatively young ([lsim ]6 Gyr). We now extend this study by considering Earth-like planets with different land/ocean coverages. This study is again based on the so-called integrated system approach, which describes the photosynthetic biomass production taking into account a variety of climatological, biogeochemical and geodynamical processes. This approach implies a special characterization of the habitable zone defined for a distinct type of planet. We show that the likelihood of finding a habitable Earth-like planet on a stable orbit around 47 UMa critically depends on the percentage of the planetary land/ocean coverage. The likelihood is significantly increased for planets with a very high percentage of ocean surface (‘water worlds’).


2010 ◽  
Vol 76 (764) ◽  
pp. 383-385 ◽  
Author(s):  
Taiju SHIBATA ◽  
Junya SUMITA ◽  
Taiyo MAKITA ◽  
Takashi TAKAGI ◽  
Eiji KUNIMOTO ◽  
...  

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