Enzyme-free detection of hydrogen peroxide from cerium oxide nanoparticles immobilized on poly(4-vinylpyridine) self-assembled monolayers

2013 ◽  
Vol 1 (28) ◽  
pp. 3443 ◽  
Author(s):  
James D. Gaynor ◽  
Ajay S. Karakoti ◽  
Talgat Inerbaev ◽  
Shail Sanghavi ◽  
P. Nachimuthu ◽  
...  
Keyword(s):  
Hydrogen Peroxide ◽  
Cerium Oxide ◽  
Self Assembled Monolayers ◽  
Cerium Oxide Nanoparticles ◽  
Oxide Nanoparticles ◽  
Assembled Monolayers ◽  
Self Assembled

Polyacrylic Acid Modified Cerium Oxide Nanoparticles: Synthesis and Characterization as a Peroxidase Mimic for Non-Enzymatic H2O2 Sensor

2020 ◽  
Vol 16 (5) ◽  
pp. 816-828
Author(s):  
Gurdeep Rattu ◽  
Nishtha Khansili ◽  
Prayaga M. Krishna
Keyword(s):  
Hydrogen Peroxide ◽  
Cerium Oxide ◽  
Polyacrylic Acid ◽  
Spectroscopic Analysis ◽  
Cerium Oxide Nanoparticles ◽  
Oxide Nanoparticles ◽  
Peroxidase Mimic ◽  
Ft Ir ◽  
H2o2 Sensing ◽  
Fluorescence Spectrometer

Background: Cerium oxide nanoparticles (nanoceria) are efficient free-radical scavengers due to their dual valence state and thus exhibit optical and catalytic properties. Therefore, the main purpose of this work was to understand the peroxidase mimic activity of polymer-stabilized nanoceria for enzyme-less H2O2 sensing by fluorescence spectrometer. Objective: This research revealed the development of fluorescence hydrogen peroxide nanosensor based on the peroxidase-like activity of polyacrylic acid stabilized nanoceria (PAA-CeO2 Nps). Methods: PAA-CeO2 Nps were synthesized by simple cross-linking reaction at a low temperature and characterized by XRD, SEM, Zeta potential, TGA, FT-IR and UV-VIS spectroscopic analysis. H2O2 sensing was performed by a fluorescence spectrometer. Results:: The synthesized polymer nanocomposite was characterized by XRD, SEM, TGA, FT-IR and UV-VIS spectroscopic analysis. The XRD diffraction patterns confirmed the polycrystalline nature and SEM micrograph showed nanoparticles having hexagonal symmetry and crystallite size of 32 nm. The broad peak of Ce–O bond appeared at 508 cm-1. UV-VIS measurements revealed a welldefined absorbance peak around 315 nm and an optical band-gap of 3.17 eV. As synthesized PAACeO2 Nps effectively catalysed the decomposition of hydrogen peroxide (H2O2) into hydroxyl radicals. Then terephthalic acid was oxidized by hydroxyl radical to form a highly fluorescent product. Under optimized conditions, the linear range for determination of hydrogen peroxide was 0.01 - 0.2 mM with a limit of detection (LOD) of 1.2 μM. Conclusion: The proposed method is ideally suited for the sensing of H2O2 at a low cost and this detection system enabled the sensing of analytes (sugars), which can enzymatically generate hydrogen peroxide.

scholarly journals The enzyme-like catalytic activity of cerium oxide nanoparticles and its dependency on Ce3+ surface area concentration

Nanoscale ◽  
2018 ◽  
Vol 10 (15) ◽  
pp. 6971-6980 ◽  
Author(s):  
V. Baldim ◽  
F. Bedioui ◽  
N. Mignet ◽  
I. Margaill ◽  
J.-F. Berret
Keyword(s):  
Reactive Oxygen Species ◽  
Hydrogen Peroxide ◽  
Catalytic Activity ◽  
Surface Area ◽  
Cerium Oxide ◽  
Superoxide Radical ◽  
Cerium Oxide Nanoparticles ◽  
Oxide Nanoparticles ◽  
Oxygen Species ◽  
Surface Area Concentration

Cerium oxide nanoparticles are known to catalyze the decomposition of reactive oxygen species such as the superoxide radical and hydrogen peroxide.

Cerium oxide nanoparticles protect primary osteoblasts against hydrogen peroxide induced oxidative damage

2014 ◽  
Vol 9 (2) ◽  
pp. 91-96 ◽  
Author(s):  
Guoqiang Zhou ◽  
Yang Li ◽  
Baofeng Zheng ◽  
Wenying Wang ◽  
Jing Gao ◽  
...  
Keyword(s):  
Hydrogen Peroxide ◽  
Oxidative Damage ◽  
Cerium Oxide ◽  
Cerium Oxide Nanoparticles ◽  
Oxide Nanoparticles ◽  
Primary Osteoblasts

Immobilization of Quantum Dots via Conjugated Self-Assembled Monolayers and Their Application as a Light-Controlled Sensor for the Detection of Hydrogen Peroxide

ACS Nano ◽  
2011 ◽  
Vol 5 (12) ◽  
pp. 9870-9876 ◽  
Author(s):  
Waqas Khalid ◽  
Mira El Helou ◽  
Tobias Murböck ◽  
Zhao Yue ◽  
Jose-Maria Montenegro ◽  
...  
Keyword(s):  
Hydrogen Peroxide ◽  
Quantum Dots ◽  
Self Assembled Monolayers ◽  
Assembled Monolayers ◽  
Self Assembled

Low content cerium oxide nanoparticles on carbon for hydrogen peroxide electrosynthesis

2012 ◽  
Vol 411-412 ◽  
pp. 1-6 ◽  
Author(s):  
M.H.M.T. Assumpção ◽  
A. Moraes ◽  
R.F.B. De Souza ◽  
I. Gaubeur ◽  
R.T.S. Oliveira ◽  
...  
Keyword(s):  
Hydrogen Peroxide ◽  
Cerium Oxide ◽  
Cerium Oxide Nanoparticles ◽  
Oxide Nanoparticles ◽  
Hydrogen Peroxide Electrosynthesis

Dual role of hydrogen peroxide on the oxidase-like activity of nanoceria and its application for colorimetric hydrogen peroxide and glucose sensing

RSC Advances ◽  
2016 ◽  
Vol 6 (65) ◽  
pp. 59939-59945 ◽  
Author(s):  
Ruochen Guo ◽  
Yanru Wang ◽  
Shaoxuan Yu ◽  
Wenxin Zhu ◽  
Fangqing Zheng ◽  
...  
Keyword(s):  
Hydrogen Peroxide ◽  
Catalytic Activity ◽  
Cerium Oxide ◽  
Glucose Sensing ◽  
Dual Role ◽  
Cerium Oxide Nanoparticles ◽  
Oxide Nanoparticles ◽  
Chromogenic Substrate

Nanoceria (cerium oxide nanoparticles) exhibits excellent catalytic activity towards chromogenic substrate 3,3,5,5-tetramethylbenzidine (TMB) in the presence of hydrogen peroxide (H2O2), which has been reported.

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