Luminescent solar concentrators: challenges for lanthanide-based organic–inorganic hybrid materials

2014 ◽  
Vol 2 (16) ◽  
pp. 5580-5596 ◽  
Author(s):  
Sandra F. H. Correia ◽  
Verónica de Zea Bermudez ◽  
Sidney J. L. Ribeiro ◽  
Paulo S. André ◽  
Rute A. S. Ferreira ◽  
...  

Organic–inorganic hybrids incarcerating Ln3+ ions are a very promising class of materials for addressing the required challenges in the LSC design to improve solar energy harvesting and, then, PV energy conversion.

2020 ◽  
Author(s):  
Victor Gray ◽  
Jesse Allardice ◽  
Simon Dowland ◽  
Zhilong Zhang ◽  
James Xiao ◽  
...  

Catalysts ◽  
2021 ◽  
Vol 11 (8) ◽  
pp. 911
Author(s):  
Zeli Wang ◽  
Zhen Chen ◽  
Jiadong Dan ◽  
Weiqiang Chen ◽  
Chenghang Zhou ◽  
...  

In solar energy harvesting using solar cells and photocatalysts, the photoexcitation of electrons and holes in semiconductors is the first major step in the solar energy conversion. The lifetime of carriers, a key factor determining the energy conversion and photocatalysis efficiency, is shortened mainly by the recombination of photoexcited carriers. We prepared and tested a series of ZnO/TiO2-based heterostructures in search of designs which can extend the carrier lifetime. Time-resolved photoluminescence tests revealed that, in ZnO/TiO2 core–shell structure the carrier lifetime is extended by over 20 times comparing with the pure ZnO nanorods. The performance improved further when Ag nanoparticles were integrated at the ZnO/TiO2 interface to construct a Z-scheme structure. We utilized these samples as photoanodes in a photoelectrochemical (PEC) cell and analyzed their solar water splitting performances. Our data showed that these modifications significantly enhanced the PEC performance. Especially, under visible light, the Z-scheme structure generated a photocurrent density 100 times higher than from the original ZnO samples. These results reveal the potential of ZnO-Ag-TiO2 nanorod arrays as a long-carrier-lifetime structure for future solar energy harvesting applications.


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