Realization of both high hydrogen selectivity and capacity in a guest responsive metal–organic framework

2013 ◽  
Vol 1 (43) ◽  
pp. 13502 ◽  
Author(s):  
Trevor A. Makal ◽  
Wenjuan Zhuang ◽  
Hong-Cai Zhou
Keyword(s):  
Metal Organic Framework ◽  
High Hydrogen ◽  
Metal Organic ◽  
Hydrogen Selectivity ◽  
Selectivity And Capacity ◽  
Organic Framework

Molecular Sieve Membrane: Supported Metal-Organic Framework with High Hydrogen Selectivity

2009 ◽  
Vol 49 (3) ◽  
pp. 548-551 ◽  
Author(s):  
Yan-Shuo Li ◽  
Fang-Yi Liang ◽  
Helge Bux ◽  
Armin Feldhoff ◽  
Wei-Shen Yang ◽  
...  
Keyword(s):  
Molecular Sieve ◽  
Metal Organic Framework ◽  
High Hydrogen ◽  
Metal Organic ◽  
Hydrogen Selectivity ◽  
Organic Framework ◽  
Supported Metal

Mn(II)-Based Porous Metal–Organic Framework Showing Metamagnetic Properties and High Hydrogen Adsorption at Low Pressure

2011 ◽  
Vol 51 (1) ◽  
pp. 674-679 ◽  
Author(s):  
Zheng-Bo Han ◽  
Rui-Yun Lu ◽  
Yan-Fang Liang ◽  
Yan-Ling Zhou ◽  
Qing Chen ◽  
...  
Keyword(s):  
Hydrogen Adsorption ◽  
Metal Organic Framework ◽  
Porous Metal ◽  
Low Pressure ◽  
High Hydrogen ◽  
Metal Organic ◽  
Organic Framework

High Hydrogen Release Catalytic Activity by Quasi-MOF Prepared via Post-Synthetic Pore Engineering

2021 ◽  
Author(s):  
Minoo Bagheri ◽  
Mohammad Yaser Mohammad Yaser Masoomi ◽  
Esther Dominguez ◽  
Hermenegildo Garcia
Keyword(s):  
Catalytic Activity ◽  
Metal Organic Framework ◽  
Hydrogen Release ◽  
Structural Defects ◽  
High Hydrogen ◽  
Metal Organic ◽  
Organic Framework

The catalytic activity of metal-organic framewroks (MOFs) depends largely on the presence of structural defects. In the present stuyd, cobalt based metal-organic framework TMU-10, [Co6(oba)5(OH)2(H2O)2(DMF)4]n·2DMF has been submitted under controlled...

scholarly journals Record High Hydrogen Storage Capacity in the Metal–Organic Framework Ni2(m-dobdc) at Near-Ambient Temperatures

2018 ◽  
Vol 30 (22) ◽  
pp. 8179-8189 ◽  
Author(s):  
Matthew T. Kapelewski ◽  
Tomče Runčevski ◽  
Jacob D. Tarver ◽  
Henry Z. H. Jiang ◽  
Katherine E. Hurst ◽  
...  
Keyword(s):  
Hydrogen Storage ◽  
Storage Capacity ◽  
Metal Organic Framework ◽  
Hydrogen Storage Capacity ◽  
High Hydrogen ◽  
Ambient Temperatures ◽  
Metal Organic ◽  
Organic Framework

An rht-type metal–organic framework constructed from an unsymmetrical ligand exhibiting high hydrogen uptake capability

RSC Advances ◽  
2014 ◽  
Vol 4 (96) ◽  
pp. 53975-53980 ◽  
Author(s):  
Jian Li ◽  
Pei-Zhou Li ◽  
Qiu-Yan Li ◽  
Yang Cao ◽  
Han Lu ◽  
...  
Keyword(s):  
Metal Organic Framework ◽  
Hydrogen Uptake ◽  
High Hydrogen ◽  
Metal Organic ◽  
Organic Framework

Multifunctional metal–organic framework heterostructures for enhanced cancer therapy

2021 ◽  
Author(s):  
Jintong Liu ◽  
Jing Huang ◽  
Lei Zhang ◽  
Jianping Lei
Keyword(s):  
Cancer Therapy ◽  
General Principle ◽  
Biomedical Applications ◽  
Metal Organic Framework ◽  
Metal Organic ◽  
Functional Modulation ◽  
Organic Framework

We review the general principle of the design and functional modulation of nanoscaled MOF heterostructures, and biomedical applications in enhanced therapy.

Magnetic Ordering via Itinerant Ferromagnetism in a Metal-Organic Framework

2020 ◽  
Author(s):  
Jesse Park ◽  
Brianna Collins ◽  
Lucy Darago ◽  
Tomce Runcevski ◽  
Michael Aubrey ◽  
...  
Keyword(s):  
Charge Transport ◽  
Magnetic Order ◽  
Metal Organic Framework ◽  
Metal Organic Frameworks ◽  
Magnetic Ordering ◽  
Double Exchange ◽  
Itinerant Ferromagnetism ◽  
Organic Solids ◽  
Metal Organic ◽  
Organic Framework

<b>Materials that combine magnetic order with other desirable physical attributes offer to revolutionize our energy landscape. Indeed, such materials could find transformative applications in spintronics, quantum sensing, low-density magnets, and gas separations. As a result, efforts to design multifunctional magnetic materials have recently moved beyond traditional solid-state materials to metal–organic solids. Among these, metal–organic frameworks in particular bear structures that offer intrinsic porosity, vast chemical and structural programmability, and tunability of electronic properties. Nevertheless, magnetic order within metal–organic frameworks has generally been limited to low temperatures, owing largely to challenges in creating strong magnetic exchange in extended metal–organic solids. Here, we employ the phenomenon of itinerant ferromagnetism to realize magnetic ordering at <i>T</i><sub>C</sub> = 225 K in a mixed-valence chromium(II/III) triazolate compound, representing the highest ferromagnetic ordering temperature yet observed in a metal–organic framework. The itinerant ferromagnetism is shown to proceed via a double-exchange mechanism, the first such observation in any metal–organic material. Critically, this mechanism results in variable-temperature conductivity with barrierless charge transport below <i>T</i><sub>C</sub> and a large negative magnetoresistance of 23% at 5 K. These observations suggest applications for double-exchange-based coordination solids in the emergent fields of magnetoelectrics and spintronics. Taken together, the insights gleaned from these results are expected to provide a blueprint for the design and synthesis of porous materials with synergistic high-temperature magnetic and charge transport properties. </b>

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