Air-stable inverted structure of hybrid solar cells using a cesium-doped ZnO electron transport layer prepared by a sol–gel process

2013 ◽  
Vol 1 (38) ◽  
pp. 11802 ◽  
Author(s):  
Seungchul Kwon ◽  
Kyung-Geun Lim ◽  
Myungsun Shim ◽  
Hong Chul Moon ◽  
Jicheol Park ◽  
...  
2020 ◽  
Vol 8 (10) ◽  
pp. 5308-5314 ◽  
Author(s):  
Xia Yang ◽  
Hanjun Yang ◽  
Xiaotian Hu ◽  
Wenting Li ◽  
Zhimin Fang ◽  
...  

High-efficiency flexible CsPbI2Br PSCs are designed by introducing Al-doped ZnO as an electron-transport layer and tert-butyl cyanoacetate as a hole passivation layer. The optimized PSC exhibits outstanding stability and a champion PCE of 15.08%.


Solar Energy ◽  
2016 ◽  
Vol 133 ◽  
pp. 103-110 ◽  
Author(s):  
Xiaoxiao Ma ◽  
Jian Zhong ◽  
Mingqiu Li ◽  
Jianpo Chen ◽  
Yingxia Zhang ◽  
...  

Nanomaterials ◽  
2021 ◽  
Vol 11 (11) ◽  
pp. 3090
Author(s):  
Jun Choi ◽  
Young Ki Park ◽  
Hee Dong Lee ◽  
Seok Il Hong ◽  
Woosung Lee ◽  
...  

A robust electron transport layer (ETL) is an essential component in planar-heterojunction perovskite solar cells (PSCs). Herein, a sol-gel-driven ZrSnO4 thin film is synthesized and its optoelectronic properties are systematically investigated. The optimized processing conditions for sol-gel synthesis produce a ZrSnO4 thin film that exhibits high optical transmittance in the UV-Vis-NIR range, a suitable conduction band maximum, and good electrical conductivity, revealing its potential for application in the ETL of planar-heterojunction PSCs. Consequently, the ZrSnO4 ETL-based devices deliver promising power conversion efficiency (PCE) up to 19.05% from CH3NH3PbI3-based planar-heterojunction devices. Furthermore, the optimal ZrSnO4 ETL also contributes to decent long-term stability of the non-encapsulated device for 360 h in an ambient atmosphere (T~25 °C, RH~55%,), suggesting great potential of the sol-gel-driven ZrSnO4 thin film for a robust solution-processed ETL material in high-performance PSCs.


2013 ◽  
Vol 2013 ◽  
pp. 1-4 ◽  
Author(s):  
Chandra Bhal Singh ◽  
Vandana Singh ◽  
S. Bhattacharya ◽  
P. Balaji Bhargav ◽  
Nafis Ahmed

Hybrid solar cells are based on the concept of using both organic and inorganic materials for fabrication of devices. Hybrid solar cells, based on a heterojunction between inorganic electron acceptor layer and organic donor layer, has been fabricated. Effect of electron transport layer on open circuit voltage (Voc) of hybrid solar cells was investigated. Hybrid solar cells were fabricated using amorphous silicon as main absorbing layer and as electron acceptor layer while using copper phthalocyanine (CuPc) as the donor materials. Al doped ZnO layer was used as buffer layer between ITO and a-Si:H to prevent ITO from reacting with silane gas during plasma enhanced chemical deposition (PECVD) process. ZnO:Al thin film also acts as electron transport layer. The open circuit voltage of hybrid solar cells studied with varying the thickness of ZnO:Al layer. Voc was increased from 0.30 volt to 0.52 volt with increasing the thickness of ZnO:Al layer from 15 nm to 45 nm. The poor interface between inorganic (a-Si:H) and organic layers may be a possible reason for low fill factor and low photocurrent in hybrid solar cells.


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