A high capacity silicon–graphite composite as anode for lithium-ion batteries using low content amorphous silicon and compatible binders

2013 ◽  
Vol 1 (28) ◽  
pp. 8234 ◽  
Author(s):  
Chae-Ho Yim ◽  
Fabrice M. Courtel ◽  
Yaser Abu-Lebdeh
2018 ◽  
Author(s):  
Mikel Arrese-Igor ◽  
Norbert Radacsi

Current lithium-ion batteries are close to reaching their physicochemical energy density limit. Moreover, they present high operation risks regarding their liquid electrolyte. Solid-state batteries are a promising alternative to overcome these problems. They offer safe operation, and potentially improved energy and power density. The option of operating at higher voltages has led to the possibility of employing high capacity electrodes. In this study, the synthesis of a nanostructured anode through electrospinning was carried out. This electrode is based on polymer nanofibres with intercalated graphite particles. The effect of molecular weight, voltage, temperature and humidity has been studied for the formation of smooth and uniform nanofibres. At the optimized conditions, Polyethylene oxide (PEO)-Polyethylene glycol (PEG) nanofibres with diameters around 600 nm were successfully electrospun. The effect of graphite loading on the electrospinning of this solution was also studied. A 30% graphite particle loading in the final fibres was reached with a reproducible methodology. It was found that the electrospun graphite particles received a polymer coating during electrospinning. EDX analysis confirmed that most of the graphite particles are covered by a polymer layer, confirming this hypothesis. Even if it is unclear how this affects the behaviour of the graphite for energy storage, high graphite content was electrospun together with PEO nanofibres with a new methodology.


Author(s):  
Shaohua Lu ◽  
Weidong Hu ◽  
Xiaojun Hu

Due to their low cost and improved safety compared to lithium-ion batteries, sodium-ion batteries have attracted worldwide attention in recent decades.


2019 ◽  
Vol 7 (29) ◽  
pp. 17357-17365 ◽  
Author(s):  
Bozhao Wu ◽  
Xiangzheng Jia ◽  
Yanlei Wang ◽  
Jinxi Hu ◽  
Enlai Gao ◽  
...  

A new graphyne with high stability, excellent flexibility and carrier mobility is theoretically predicted as a promising anode material for lithium-ion batteries with high capacity.


2021 ◽  
Vol 376 ◽  
pp. 138035
Author(s):  
Wengang Yan ◽  
Kaili Liang ◽  
Zongtao Chi ◽  
Tao Liu ◽  
Minghui Cao ◽  
...  

2021 ◽  
Vol 10 (1) ◽  
pp. 210-220
Author(s):  
Fangfang Wang ◽  
Ruoyu Hong ◽  
Xuesong Lu ◽  
Huiyong Liu ◽  
Yuan Zhu ◽  
...  

Abstract The high-nickel cathode material of LiNi0.8Co0.15Al0.05O2 (LNCA) has a prospective application for lithium-ion batteries due to the high capacity and low cost. However, the side reaction between the electrolyte and the electrode seriously affects the cycling stability of lithium-ion batteries. In this work, Ni2+ preoxidation and the optimization of calcination temperature were carried out to reduce the cation mixing of LNCA, and solid-phase Al-doping improved the uniformity of element distribution and the orderliness of the layered structure. In addition, the surface of LNCA was homogeneously modified with ZnO coating by a facile wet-chemical route. Compared to the pristine LNCA, the optimized ZnO-coated LNCA showed excellent electrochemical performance with the first discharge-specific capacity of 187.5 mA h g−1, and the capacity retention of 91.3% at 0.2C after 100 cycles. The experiment demonstrated that the improved electrochemical performance of ZnO-coated LNCA is assigned to the surface coating of ZnO which protects LNCA from being corroded by the electrolyte during cycling.


Nanoscale ◽  
2021 ◽  
Author(s):  
Kun Wang ◽  
Yongyuan Hu ◽  
Jian Pei ◽  
Fengyang Jing ◽  
Zhongzheng Qin ◽  
...  

High capacity Co2VO4 becomes a potential anode material for lithium ion batteries (LIBs) benefiting from its lower output voltage during cycling than other cobalt vanadates. However, the application of this...


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