Facile synthesis of spherical nanoparticles with a silica shell and multiple Au nanodots as the core

2013 ◽  
Vol 1 (17) ◽  
pp. 5408 ◽  
Author(s):  
Joonsung Pak ◽  
Hyojong Yoo
2018 ◽  
Vol 42 (11) ◽  
pp. 8773-8782 ◽  
Author(s):  
Haojie Song ◽  
Jian Huang ◽  
Xiaohua Jia ◽  
Weichen Sheng

The core–shell Ag@C nanospheres were obtained from glucose solution by coupling reduction AgNO3 and catalytic carbonation. The tribological performance of Ag@C nanospheres as a water-based additive can be improved.


2017 ◽  
Vol 06 (02) ◽  
pp. 11-21 ◽  
Author(s):  
Murad M. A. Abualrejal ◽  
Haifeng Zou ◽  
Jie Chen ◽  
Yanhua Song ◽  
Ye Sheng

Author(s):  
Lina Feng ◽  
Wenxian Li ◽  
Jinrong Bao ◽  
Yushang Zheng ◽  
Yilian Li ◽  
...  

Two novel core-shell composites SiO2@PMDA-Si-Tb, SiO2@PMDA-Si-Tb-phen with SiO2 as the core and terbium organic complex as the shell, were successfully synthesized. The terbium ion was coordinated with organic ligand forming terbium organic complex in the shell layer. The bi-functional organosilane ((HOOC)2C6H2(CONH(CH2)3Si(OCH2CH3)3)2 (abbreviated as PMDA-Si) was used as the first ligand and phen as the second ligand. Furthermore, the silica-modified SiO2@PMDA-Si-Tb@SiO2, SiO2@PMDA-Si-Tb-phen@SiO2 core-shell-shell composites were also synthesized by sol–gel chemical route. An amorphous silica shell was coated around the SiO2@PMDA-Si-Tb and SiO2@PMDA-Si-Tb-phen core-shell composites. The core-shell and core-shell-shell composites both exhibited excellent luminescence in solid state. The luminescence of core-shell-shell composites was stronger than that of core-shell composites. Meanwhile, an improved luminescence stability property for the core-shell-shell composites was found in the aqueous solution. The core-shell-shell composites exhibited bright luminescence, high stability, long lifetime, and good solubility, which may present potential applications in the field of bio-medical.


Nanomaterials ◽  
2021 ◽  
Vol 12 (1) ◽  
pp. 45
Author(s):  
Maxim K. Rabchinskii ◽  
Victor V. Sysoev ◽  
Sergei A. Ryzhkov ◽  
Ilya A. Eliseyev ◽  
Dina Yu. Stolyarova ◽  
...  

Graphene derivatization to either engineer its physical and chemical properties or overcome the problem of the facile synthesis of nanographenes is a subject of significant attention in the nanomaterials research community. In this paper, we propose a facile and scalable method for the synthesis of thiolated graphene via a two-step liquid-phase treatment of graphene oxide (GO). Employing the core-level methods, the introduction of up to 5.1 at.% of thiols is indicated with the simultaneous rise of the C/O ratio to 16.8. The crumpling of the graphene layer upon thiolation without its perforation is pointed out by microscopic and Raman studies. The conductance of thiolated graphene is revealed to be driven by the Mott hopping mechanism with the sheet resistance values of 2.15 kΩ/sq and dependable on the environment. The preliminary results on the chemiresistive effect of these films upon exposure to ethanol vapors in the mix with dry and humid air are shown. Finally, the work function value and valence band structure of thiolated graphene are analyzed. Taken together, the developed method and findings of the morphology and physics of the thiolated graphene guide the further application of this derivative in energy storage, sensing devices, and smart materials.


2017 ◽  
Vol 7 (4) ◽  
pp. 1700816 ◽  
Author(s):  
Qiang Yang ◽  
Huali Chen ◽  
Yan Bai ◽  
Yang Cao ◽  
Wenjing Hu ◽  
...  

RSC Advances ◽  
2021 ◽  
Vol 11 (7) ◽  
pp. 3981-3989
Author(s):  
Lu Zheng ◽  
Xinyi Huang ◽  
Jiuping Zhong ◽  
Zijun Wang ◽  
Xiaoning Cheng

A shell of SiO2 with tunable thickness was uniformly coated on NaGd(WO4)2:Yb3+/Er3+ core upconversion nanoparticles (UCNPs). The effects of the silica shell on UC luminescence and thermal sensing properties of the core–shell UCNPs were investigated.


2013 ◽  
Vol 372 ◽  
pp. 132-135 ◽  
Author(s):  
Takashi Harada ◽  
Takuji Misaka ◽  
Takao Sakata ◽  
Shigeru Ikeda ◽  
Michio Matsumura

A core-hollow shell composite composed of a nickel (Ni) nanoparticle core encapsulated in a hollow silica shell (Ni@SiO2) was prepared by using a nanocrystalline salt of nickel tris-hydrazine complex, which acted as not only a nickel source but also a solid template to produce the core-hollow shell structure. Structural characterizations using TEM and N2adsorption-desorption measurements of the thus-obtained Ni@SiO2powder revealed that it was composed of a Ni nanoparticle core of ca. 4.0 nm in diameter and a rectangular-shaped hollow silica shell with a micropore (ca. 0.5 nm in diameter) system.


ACS Catalysis ◽  
2012 ◽  
Vol 2 (10) ◽  
pp. 2119-2125 ◽  
Author(s):  
Zhonghong Zhu ◽  
Jinqiang Ma ◽  
Liang Xu ◽  
Lei Xu ◽  
Hexing Li ◽  
...  

2014 ◽  
Vol 472 ◽  
pp. 711-714 ◽  
Author(s):  
Bin Yue ◽  
Yuan Li ◽  
Kai Kong ◽  
Hai Bin Chu ◽  
Yong Liang Zhao

Five kinds of terbium complexes have been synthesized respectively with benzoic acid, 1,10-phenanthroline and 2,2'-bipyridine as ligands. The core-shell Ag@SiO2nanocomposites was prepared. The result of transmission electron microscopy (TEM) shows the diameter of the nanosilver is about 50 nm and the thickness of the silica shell is 10, 25 and 80 nm. Combine the nanoparticles composite with terbium complexes, we explore the changes of excitation wavelength and emission intensity. The results show that: by loading the terbium complexes above the different size of nanoparticles, the excitation wavelengths of complexes do not shift, and the emission intensity of the complexes are enhanced in the presence of Ag@SiO2nanoparticles because of metal-enhanced fluorescence (MEF), but at only a limited shell thickness particle region.


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