Self-assembly of PBzMA-b-PDMAEMA diblock copolymer films at the air–water interface and deposition on solid substrates via Langmuir–Blodgett transfer

Soft Matter ◽  
2013 ◽  
Vol 9 (45) ◽  
pp. 10899 ◽  
Author(s):  
P. Cecilia dos Santos Claro ◽  
Marcos E. Coustet ◽  
Carolina Diaz ◽  
Eliana Maza ◽  
M. Susana Cortizo ◽  
...  
Langmuir ◽  
1997 ◽  
Vol 13 (6) ◽  
pp. 1592-1601 ◽  
Author(s):  
J. V. Gandhi ◽  
J. V. Maher ◽  
K. A. Shaffer ◽  
T. M. Chapman

2014 ◽  
Vol 488-489 ◽  
pp. 260-264
Author(s):  
Qiu Ling Wang ◽  
Yong Na Li ◽  
Hui Ying Jia ◽  
Yong Ze Wei ◽  
Hui Fan Du ◽  
...  

A series of novel copolymers [p (AOBHA-co-NPMA)] containing 2-Allyloxy-N-benzylidene hexadecylamine (AOBHA) as film formation material and β-naphtayl methacrylate (NPMA) as photosensitive group were synthesized by free-radical polymerization. The copolymers could form stable condensed monolayer at air/water interface and be transformed onto solid substrates. Positive-tone patterns with the resolution of 0.75 μm of the copolymers Langmuir-Blodgett (LB) films with 35 layers were fabricated by deep UV irradiation, followed by developing with acetone. The etched gold patterns with resolution of 0.75 μm were also obtained, showing that the copolymer has enough resistance to wet etching suitable for fabricating photomask. The mechanism of photolysis was also investigated by UV and GPC, in which showed that the scission of main and side chain of p (AOBHA-co-NPMA) LB films occurred at the same time.


2011 ◽  
Vol 239-242 ◽  
pp. 1998-2001
Author(s):  
Tie Sheng Li ◽  
Wen Jian Xu ◽  
Hui Ying Jia ◽  
Yang Jie Wu ◽  
Tokuji Miyashita

A series of novel copolymers poly (AOBDA-co-DNMMA)s containing 2-Allyloxy-N-benzyl- idene dodecylamine (AOBDA) and 1.4-dioxaspiro[4.4] nonane-2-methyl methacrylate (DNMMA) were synthesized. The copolymers could form stable condensed monolayer at air/water interface and be transformed onto solid substrates successively. Positive-tone patterns with the resolution of 0.75 μm of the copolymers Langmuir-Blodgett (LB) films with 40 layers were obtained by deep UV irradiation, followed by developing in acetone. The etched gold patterns with resolution of 0.75 μm were also obtained, showing that the copolymer has enough resistance to wet etching suitable for fabricating photomask. The mechanism of photolysis was also investigated by UV, IR and GPC.


2020 ◽  
Author(s):  
Nobuo Kimizuka ◽  
Yuki Nagai ◽  
Keita Ishiba ◽  
Ryosuke Yamamoto ◽  
Teppei Yamada ◽  
...  

2000 ◽  
Vol 19 (2) ◽  
pp. 117-125 ◽  
Author(s):  
Wieslaw I Gruszecki ◽  
Bogumil Zelent ◽  
Heidar-Ali Tajmir-Riahi ◽  
Gongming Wang ◽  
Toufik Taleb ◽  
...  

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