Controlling stereochemistry in polyketide synthesis: 1,3- vs. 1,2-asymmetric induction in methyl ketone aldol additions to β-super siloxy aldehydes

2013 ◽  
Vol 4 (8) ◽  
pp. 3223 ◽  
Author(s):  
Patrick B. Brady ◽  
Brian J. Albert ◽  
Matsujiro Akakura ◽  
Hisashi Yamamoto
Keyword(s):  
Methyl Ketone ◽  
Asymmetric Induction ◽  
Aldol Additions ◽  
Methyl Ketone Aldol

scholarly journals 1,5-Asymmetric Induction in Boron-Mediated β-Alkoxy Methyl Ketone Aldol Addition Reactions.

ChemInform ◽  
2004 ◽  
Vol 35 (2) ◽  
Author(s):  
David A. Evans ◽  
Bernard Cote ◽  
Paul J. Coleman ◽  
Brian T. Connell
Keyword(s):  
Methyl Ketone ◽  
Asymmetric Induction ◽  
Addition Reactions ◽  
Aldol Addition ◽  
Methyl Ketone Aldol

1,5-Asymmetric Induction in Methyl Ketone Aldol Addition Reactions

1997 ◽  
Vol 62 (4) ◽  
pp. 788-789 ◽  
Author(s):  
David A. Evans ◽  
Paul J. Coleman ◽  
Bernard Côté
Keyword(s):  
Methyl Ketone ◽  
Asymmetric Induction ◽  
Addition Reactions ◽  
Aldol Addition ◽  
Methyl Ketone Aldol

1,5-Asymmetric Induction in Boron-Mediated β-Alkoxy Methyl Ketone Aldol Addition Reactions

2003 ◽  
Vol 125 (36) ◽  
pp. 10893-10898 ◽  
Author(s):  
David A. Evans ◽  
Bernard Côté, ◽  
Paul J. Coleman ◽  
Brian T. Connell
Keyword(s):  
Methyl Ketone ◽  
Asymmetric Induction ◽  
Addition Reactions ◽  
Aldol Addition ◽  
Methyl Ketone Aldol

Lewis Base-Catalyzed, Asymmetric Aldol Additions of Methyl Ketone Enolates†

1998 ◽  
Vol 63 (4) ◽  
pp. 918-919 ◽  
Author(s):  
Scott E. Denmark ◽  
Robert A. Stavenger ◽  
Ken-Tsung Wong
Keyword(s):  
Methyl Ketone ◽  
Lewis Base ◽  
Asymmetric Aldol ◽  
Aldol Additions ◽  
Ketone Enolates
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