Convergent synthesis of a hexasaccharide corresponding to the cell wall O-antigen of Escherichia coli O41

RSC Advances ◽  
2014 ◽  
Vol 4 (1) ◽  
pp. 54-60 ◽  
Author(s):  
Tamashree Ghosh ◽  
Abhishek Santra ◽  
Anup Kumar Misra
RSC Advances ◽  
2017 ◽  
Vol 7 (79) ◽  
pp. 49903-49909 ◽  
Author(s):  
Anshupriya Si ◽  
Anup Kumar Misra

The pentasaccharide repeating unit of the cell wall O-antigen ofEscherichia coliO156 containing 4,6-O-(R)-pyruvate acetal was synthesized using stereoselective [2 + 3] block glycosylation in satisfactory yield.


2012 ◽  
Vol 8 ◽  
pp. 2053-2059 ◽  
Author(s):  
Abhijit Sau ◽  
Anup Kumar Misra

A tetrasaccharide repeating unit corresponding to the cell-wall lipopolysaccharide of E. coli O40 was synthesized by using a convergent block glycosylation strategy. A disaccharide donor was coupled to a disaccharide acceptor by a stereoselective glycosylation. A 2-aminoethyl linker was chosen as the anomeric protecting group at the reducing end of the tetrasaccharide. All glycosylation steps are significantly high yielding and stereoselective.


2014 ◽  
Vol 391 ◽  
pp. 9-15 ◽  
Author(s):  
Abhishek Santra ◽  
Anshupriya Si ◽  
Rajiv Kumar Kar ◽  
Anirban Bhunia ◽  
Anup Kumar Misra

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