Water soluble and fluorescent copolymers as highly sensitive and selective fluorescent chemosensors for the detection of cyanide anions in biological media

RSC Advances ◽  
2013 ◽  
Vol 3 (44) ◽  
pp. 22168 ◽  
Author(s):  
Jalal Isaad ◽  
Fouad Malek ◽  
Ahmida El Achari
Keyword(s):  
Water Soluble ◽  
Fluorescent Chemosensors ◽  
Biological Media ◽  
Highly Sensitive

scholarly journals Application of chromato-mass-spectrometric methods of determination of exposure markers in biomonitoring researches in workers of productions of polyvinyl chloride and aluminum

2020 ◽  
Vol 99 (10) ◽  
pp. 1159-1164
Author(s):  
Salim F. Shayakhmetov ◽  
Olga M. Zhurba ◽  
Anton N. Alekseenko ◽  
Alexey V. Merinov
Keyword(s):  
Polyvinyl Chloride ◽  
Mass Spectrometric ◽  
Aluminum Production ◽  
Control Groups ◽  
Biological Media ◽  
Mass Selective Detector ◽  
Selective Detector ◽  
Highly Sensitive ◽  
Polycyclic Aromatic

Introduction. The presence of highly toxic polycyclic aromatic hydrocarbons (PAHs) in the production of aluminum and organochlorine compounds (OCC) in the production of polyvinyl chloride (PVC) poses a serious threat to the health of workers, necessitates biological monitoring of toxicants and their metabolites in biological media to assess health risks on basis of modern methods chemical analysis. Material and methods. Biomonitoring studies of the content of marker metabolite OCC - thiodiacetic acid (TDAA) in urine were performed in 65 workers of PVC production and PAHs metabolite - 1-hydroxypyrene (1-OHPyr) in 144 workers of the aluminum smelter using developed own methods of gas-chromato-mass-spectrometric (GC-MS) analysis. Sample analysis was performed on an Agilent 7890A gas chromatograph with an Agilent 5979 mass selective detector. Results. Methodological methods and parameters of GC-MS measurement of TDAA and 1-OHPyr in urine, which provided high selectivity and sensitivity of the analysis of samples, were examined and considered. Reliable differences in the levels of marker metabolites among the groups of main and auxiliary occupations and persons in the control groups, their dependence on the degree of exposure to PAHs, and OCC were established. The highest concentrations of TDAA in urine were observed in unit operators of PVC workshop and 1-OHPyr - in anode workers of aluminum production. Discussion. The revealed reliable intergroup and interindividual differences in the contents of TDAA and 1-OHPyr in the urine of workers indicate the reliability and informativeness of the results of the analysis of biological media. The results are consistent with data from foreign studies, confirm the occupational - production nature of the exposure of toxicants among workers in the main professions of enterprises. Conclusion. The results of approbation of highly sensitive and selective methods for the determination of TDAA and 1-OHPyr in urine samples developed on the base of GC-MS method demonstrate the possibility of their use in biomonitoring studies of workers of productions and the population to adequately assess the exposure of highly toxic PAHs and OCC.

Self-Assembled Porous Nanoparticles Based on Silicone Polymer with Aggregation-induced Emission for Highly Sensitive Detection of Nitroaromatics

2021 ◽  
Author(s):  
Xiangzhong Zhao ◽  
Yan Liang ◽  
Ting Wang ◽  
Fangfang Li ◽  
Hua Wang
Keyword(s):  
Polymeric Materials ◽  
Sensitive Detection ◽  
Ideal Class ◽  
Fluorescent Chemosensors ◽  
Aggregation Induced Emission ◽  
Highly Sensitive ◽  
Fluorescent Materials ◽  
Porous Nanoparticles ◽  
Highly Sensitive Detection ◽  
Silicone Polymer

Aggregation-induced emission (AIE) -active polymeric materials have been regarded as an ideal class of fluorescent materials to be widely used as fluorescent chemosensors. Herein, we demonstrate a simple and effective...

Forming a water-soluble supramolecular polymer and an AIEE hydrogel: two novel approaches for highly sensitive detection and efficient adsorption of aldehydes

2019 ◽  
Vol 10 (47) ◽  
pp. 6489-6494 ◽  
Author(s):  
Yan-Qing Fan ◽  
Qing Huang ◽  
You-Ming Zhang ◽  
Jiao Wang ◽  
Xiao-Wen Guan ◽  
...  
Keyword(s):  
Water Soluble ◽  
Sensitive Detection ◽  
Supramolecular Polymer ◽  
Highly Sensitive ◽  
Novel Approaches ◽  
Highly Sensitive Detection

Two novel approaches for highly sensitive detection and efficient adsorption of aldehydes by forming a water-soluble supramolecular polymer and an AIEE hydrogel.

Water-soluble poly(p-phenylene) incorporating methoxyphenol units: Highly sensitive and selective chemodosimeters for hypochlorite

Polymer ◽  
2012 ◽  
Vol 53 (12) ◽  
pp. 2356-2360 ◽  
Author(s):  
Wenjun Zhang ◽  
Chen'ge Li ◽  
Jingui Qin ◽  
Chuluo Yang
Keyword(s):  
Water Soluble ◽  
Highly Sensitive ◽  
Soluble Poly
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