Highly selective Wacker oxidation of terminal olefins using magnetically recyclable Pd–Fe3O4 heterodimer nanocrystals

RSC Advances ◽  
2013 ◽  
Vol 3 (37) ◽  
pp. 16296 ◽  
Author(s):  
Sangmoon Byun ◽  
Jooyoung Chung ◽  
Youngjin Jang ◽  
Jungmin Kwon ◽  
Taeghwan Hyeon ◽  
...  
Keyword(s):  
Wacker Oxidation ◽  
Terminal Olefins

Wacker Oxidation of Terminal Olefins in a Mixture of [bmim][BF4] and Water.

ChemInform ◽  
2006 ◽  
Vol 37 (6) ◽  
Author(s):  
I. A. Ansari ◽  
Sipak Joyasawal ◽  
Manoj K. Gupta ◽  
J. S. Yadav ◽  
R. Gree
Keyword(s):  
Wacker Oxidation ◽  
Terminal Olefins

ChemInform Abstract: Tsuji-Wacker Oxidation of Terminal Olefins Using a Palladium-Carbon Nanotube Nanohybrid.

ChemInform ◽  
2015 ◽  
Vol 46 (49) ◽  
pp. no-no
Author(s):  
Simon Donck ◽  
Edmond Gravel ◽  
Nimesh Shah ◽  
Dhanaji V. Jawale ◽  
Eric Doris ◽  
...  
Keyword(s):  
Carbon Nanotube ◽  
Wacker Oxidation ◽  
Terminal Olefins

Optimal Regioselectivity Control in Electrocatalytic Oxidation of Terminal Olefins

2019 ◽  
Author(s):  
Sajjad Ghobadi ◽  
Thomas D. Roper ◽  
B. Frank Gupton ◽  
Carlos E. Castano
Keyword(s):  
Electrocatalytic Oxidation ◽  
Reduction Reaction ◽  
General Session ◽  
Pd Catalysts ◽  
Wacker Oxidation ◽  
Highly Active ◽  
The Poor ◽  
Catalyzed Reactions ◽  
Terminal Olefins ◽  
Supported Pd

Electrochemical Wacker oxidation of terminal olefins has been among the most interesting reactions from an industrial standpoint. However, the poor regioselectivity and contamination of products with palladium (Pd) catalysts have been the main drawbacks of its commercialization. Herein, rational preparation, as well as catalytic, structural, and electrochemical properties analysis of solid-supported Pd on graphene nanoplatelets (GNP) highly active catalysts for regioselective Wacker-type electrooxidation of terminal olefins is presented. The prepared catalysts improved by two orders of magnitude the electrocatalytic oxidation of 1-octene compared to the conventional homogeneously-catalyzed reactions. The control over oxidation regioselectivity via minimization of the cathodic reduction reaction was also confirmed.To be presented at: the 235th ECS Meeting, Dallas, TX. May 26-31, 2019. Symposium Selection:Physical and Analytical Electrochemistry, Electrocatalysis, and Photoelectrochemistry General Session 2Slot:Monday, 27 May 2019: 14:00-16:00Scheduled Time:15:20Final #:L01-1899

Pd(0)/C catalyzed efficient Wacker oxidation of functionalized terminal olefins

2009 ◽  
Vol 50 (24) ◽  
pp. 2893-2894 ◽  
Author(s):  
Mukund G. Kulkarni ◽  
Sharanappa M. Bagale ◽  
Mahadev P. Shinde ◽  
Dnyaneshwar D. Gaikwad ◽  
Ajit S. Borhade ◽  
...  
Keyword(s):  
Wacker Oxidation ◽  
Terminal Olefins

Wacker oxidation of terminal olefins in a mixture of [bmim][BF4] and water

2005 ◽  
Vol 46 (44) ◽  
pp. 7507-7510 ◽  
Author(s):  
I.A. Ansari ◽  
Sipak Joyasawal ◽  
Manoj K. Gupta ◽  
J.S. Yadav ◽  
R. Gree
Keyword(s):  
Wacker Oxidation ◽  
Terminal Olefins

MnO2 as a terminal oxidant in Wacker oxidation of homoallyl alcohols and terminal olefins

2020 ◽  
Vol 18 (31) ◽  
pp. 6115-6125 ◽  
Author(s):  
Rodney A. Fernandes ◽  
Gujjula V. Ramakrishna ◽  
Venkati Bethi
Keyword(s):  
Methyl Ketones ◽  
Reaction Conditions ◽  
Wacker Oxidation ◽  
Terminal Olefins

Efficient and mild reaction conditions for Wacker-type oxidation of terminal olefins of less explored homoallyl alcohols to β-hydroxy-methyl ketones have been developed by using a Pd(ii) catalyst and MnO2 as a co-oxidant.

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