Oxidation rate of Fe and electrochemical performance of Fe–air solid oxide rechargeable battery using LaGaO3 based oxide ion conductor

RSC Advances ◽  
2013 ◽  
Vol 3 (23) ◽  
pp. 8820 ◽  
Author(s):  
Atsushi Inoishi ◽  
Yohei Okamoto ◽  
Young-Wan Ju ◽  
Shintaro Ida ◽  
Tatsumi Ishihara
Keyword(s):  
Electrochemical Performance ◽  
Oxidation Rate ◽  
Solid Oxide ◽  
Rechargeable Battery ◽  
Ion Conductor ◽  
Oxide Ion Conductor ◽  
Oxide Ion

Low temperature operation of a solid-oxide Fe–air rechargeable battery using a La0.9Sr0.1Ga0.8Mg0.2O3 oxide ion conductor

2015 ◽  
Vol 3 (16) ◽  
pp. 8260-8264 ◽  
Author(s):  
A. Inoishi ◽  
J. Hyodo ◽  
H. Kim ◽  
T. Sakai ◽  
S. Ida ◽  
...  
Keyword(s):  
Fuel Cells ◽  
Low Temperature ◽  
Solid Oxide Fuel Cells ◽  
Solid Oxide ◽  
Rechargeable Battery ◽  
Oxide Fuel ◽  
Ion Conductor ◽  
Oxide Ion Conductor ◽  
Temperature Operating ◽  
Oxide Ion

We investigated a catalyst for oxidation of Fe powder using steam and it was applied to a Fe–air rechargeable battery based on the low temperature operating Solid Oxide Fuel Cells technology.

scholarly journals Hexagonal perovskite related oxide ion conductor Ba3NbMoO8.5: phase transition, temperature evolution of the local structure and properties

2019 ◽  
Vol 7 (44) ◽  
pp. 25503-25510 ◽  
Author(s):  
Matthew S. Chambers ◽  
Kirstie S. McCombie ◽  
Josie E. Auckett ◽  
Abbie C. McLaughlin ◽  
John T. S. Irvine ◽  
...  
Keyword(s):  
Solid Oxide Fuel Cells ◽  
Local Structure ◽  
Solid Oxide ◽  
Oxide Fuel ◽  
Structure And Properties ◽  
Ion Conductor ◽  
Oxide Ion Conductor ◽  
Oxide Ion Conductivity ◽  
Reducing Conditions ◽  
Oxide Ion

Ba3NbMoO8.5 has recently been demonstrated to exhibit competitive oxide ion conductivity and to be stable under reducing conditions, making it an excellent potential electrolyte for solid oxide fuel cells.

Reversible Solid State Fe-Air Rechargeable Battery Using LaGaO3 Based Oxide Ion Conducting Electrolyte

2014 ◽  
Vol 783-786 ◽  
pp. 1680-1685
Author(s):  
Tatsumi Ishihara ◽  
Atsushi Inoishi ◽  
Sintaro Ida
Keyword(s):  
Energy Density ◽  
High Energy ◽  
Solid Oxide ◽  
High Energy Density ◽  
Storage Device ◽  
Cycle Stability ◽  
Ion Conductor ◽  
Oxide Ion Conductor ◽  
Ion Conducting ◽  
Oxide Ion

The combination of solid oxide fuel cell technology with Fe-air battery concept was proposed by using H2/H2O as a redox mediator and LaGaO3based oxide for electrolyte. Since large internal resistance and large degradation during charge and discharge cycles are observed on anode, improvement in discharge potential and cycle stability are strongly required by improving stability of anode. In this study, cermet anode consisting of Ni-Fe alloy combined with oxide ion conductor was investigated. It was found that by using cermet anode of Ni-Fe combined with Ce0.6Mn0.3Fe0.1O2(CMF), the observed energy density of the cell is improved to be 1109 Wh/Kg-Fe at 10 mA/cm2, 873 K, which is about 92% of the theoretical energy density assuming the formation of Fe3O4(1290 Wh/Kg-Fe). Cycle stability was also much improved on the cell using Ni-Fe-CMF anode comparing with that of Ni-Fe metal because of suppressed aggregation of Ni by mixing with CMF. Electrochemical charge-discharge measurement at 773 K showed excellent cycle stability over 30 cycles with high energy density (Round trip efficiency is higher than 80 %). The excellent performance and stability with operating at lower temperature promise this Fe-air solid oxide battery as the next generation energy storage device for averaging electricity and electric vehicle.

Sr3−3xNa3xSi3O9−1.5x (x = 0.45) as a superior solid oxide-ion electrolyte for intermediate temperature-solid oxide fuel cells

2014 ◽  
Vol 7 (5) ◽  
pp. 1680-1684 ◽  
Author(s):  
Tao Wei ◽  
Preetam Singh ◽  
Yunhui Gong ◽  
John B. Goodenough ◽  
Yunhui Huang ◽  
...  
Keyword(s):  
Activation Energy ◽  
Fuel Cells ◽  
Solid Oxide Fuel Cells ◽  
Solid Oxide ◽  
Oxide Fuel ◽  
Ion Conductor ◽  
Oxide Ion Conductor ◽  
Oxide Ion Conductivity ◽  
Oxide Ion Conductors ◽  
Oxide Ion

A new solid oxide-ion conductor Sr3−3xNa3xSi3O9−1.5x (x = 0.45) exhibits the highest oxide-ion conductivity with the lowest activation energy among all the known chemically stable oxide-ion conductors.

Intermediate Temperature Solid Oxide Fuel Cells Using a New LaGaO3 Based Oxide Ion Conductor: I. Doped as a New Cathode Material

1998 ◽  
Vol 145 (9) ◽  
pp. 3177-3183 ◽  
Author(s):  
Tatsumi Ishihara ◽  
Miho Honda ◽  
Takaaki Shibayama ◽  
Hiroaki Minami ◽  
Hiroyasu Nishiguchi ◽  
...  
Keyword(s):  
Fuel Cells ◽  
Solid Oxide Fuel Cells ◽  
Cathode Material ◽  
Solid Oxide ◽  
Intermediate Temperature ◽  
Oxide Fuel ◽  
Ion Conductor ◽  
Oxide Ion Conductor ◽  
Oxide Ion

scholarly journals Improved cycle stability of Fe–air solid state oxide rechargeable battery using LaGaO3-based oxide ion conductor

2014 ◽  
Vol 262 ◽  
pp. 310-315 ◽  
Author(s):  
Atsushi Inoishi ◽  
Takaaki Sakai ◽  
Young Wan Ju ◽  
Shintaro Ida ◽  
Tatsumi Ishihara
Keyword(s):  
Solid State ◽  
Rechargeable Battery ◽  
Cycle Stability ◽  
Ion Conductor ◽  
Oxide Ion Conductor ◽  
Oxide Ion
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