High-purity iron pyrite (FeS2) nanowires as high-capacity nanostructured cathodes for lithium-ion batteries

Nanoscale ◽  
2014 ◽  
Vol 6 (4) ◽  
pp. 2112-2118 ◽  
Author(s):  
Linsen Li ◽  
Miguel Cabán-Acevedo ◽  
Steven N. Girard ◽  
Song Jin

A large-scale conversion synthesis of phase-pure pyrite nanowires has been developed for the first time. Nano-pyrite cathodes exhibit high Li-storage capacity and excellent capacity retention, which demonstrates the promise of pyrite nanomaterials as a cost-effective high-capacity cathode material for Li-ion batteries.

2017 ◽  
Vol 5 (41) ◽  
pp. 21994-22003 ◽  
Author(s):  
Yun Qi ◽  
Bingqiu Liu ◽  
Lingyu Zhang ◽  
Yuqiu Huo ◽  
Lu Li ◽  
...  

CFO-SNSs, CFO-HNSs and MS-CFO-HNSs are controllably fabricated for the first time by a straightforward and cost-effective method on a large scale as superior anode materials for lithium ion batteries.


2016 ◽  
Vol 4 (40) ◽  
pp. 15411-15419 ◽  
Author(s):  
Huawei Song ◽  
Lisha Shen ◽  
Jing Wang ◽  
Chengxin Wang

Impressive Li-ion storage, fast charge–discharge and ultra long life spans more than 1000 cycles with high capacity retention are simultaneously obtained in CoCOP nanowires.


Nanoscale ◽  
2021 ◽  
Author(s):  
Kun Wang ◽  
Yongyuan Hu ◽  
Jian Pei ◽  
Fengyang Jing ◽  
Zhongzheng Qin ◽  
...  

High capacity Co2VO4 becomes a potential anode material for lithium ion batteries (LIBs) benefiting from its lower output voltage during cycling than other cobalt vanadates. However, the application of this...


RSC Advances ◽  
2019 ◽  
Vol 9 (60) ◽  
pp. 35045-35049
Author(s):  
Xu Chen ◽  
Jian Zhou ◽  
Jiarui Li ◽  
Haiyan Luo ◽  
Lin Mei ◽  
...  

High-performance lithium ion batteries are ideal energy storage devices for both grid-scale and large-scale applications.


Carbon ◽  
2013 ◽  
Vol 64 ◽  
pp. 158-169 ◽  
Author(s):  
Shuangqiang Chen ◽  
Peite Bao ◽  
Linda Xiao ◽  
Guoxiu Wang

2008 ◽  
Vol 80 (11) ◽  
pp. 2537-2542 ◽  
Author(s):  
Zexun Tang ◽  
Deshu Gao ◽  
Ping Chen ◽  
Zhaohui Li ◽  
Qiang Wu

Ni1/3Co1/3Mn1/3(OH)2, a precursor of LiNi1/3Co1/3Mn1/3O2 in new-generation Li-ion batteries, was prepared by a hydroxide coprecipitation method. Scanning electronic microscopy (SEM) micrographs reveal that the precursor particles thus obtained, show regular shape with uniform size under optimized conditions. X-ray diffraction (XRD) indicates that well-ordered layer-structured LiNi1/3Co1/3Mn1/3O2 was prepared after calcination at high temperature. The final product exhibited a spherical morphology with uniform size distribution (10 μm in diameter). At the terminal charging voltage of 4.3 and 4.5 V (vs. Li/Li+), the testing cells of LiNi1/3Co1/3Mn1/3O2 delivered a specific capacity of 161.2 and 184.1 mAh g-1, respectively. The high capacity retention of 98.0 and 96.1 % after charging to 4.3 and 4.5 V for 50 cycles, respectively, indicates that this material displays excellent cycling stability even at high cut-off voltage.


2014 ◽  
Vol 2 (24) ◽  
pp. 9118-9125 ◽  
Author(s):  
Renzong Hu ◽  
Wei Sun ◽  
Yulong Chen ◽  
Meiqin Zeng ◽  
Min Zhu

Plasma-assisted milled Si/graphene nanocomposite anode delivers high capacity and good cycleability in half and full cells using a LiMn2O4 cathode.


Nanomaterials ◽  
2020 ◽  
Vol 11 (1) ◽  
pp. 18
Author(s):  
Tahar Azib ◽  
Claire Thaury ◽  
Fermin Cuevas ◽  
Eric Leroy ◽  
Christian Jordy ◽  
...  

Embedding silicon nanoparticles in an intermetallic matrix is a promising strategy to produce remarkable bulk anode materials for lithium-ion (Li-ion) batteries with low potential, high electrochemical capacity and good cycling stability. These composite materials can be synthetized at a large scale using mechanical milling. However, for Si-Ni3Sn4 composites, milling also induces a chemical reaction between the two components leading to the formation of free Sn and NiSi2, which is detrimental to the performance of the electrode. To prevent this reaction, a modification of the surface chemistry of the silicon has been undertaken. Si nanoparticles coated with a surface layer of either carbon or oxide were used instead of pure silicon. The influence of the coating on the composition, (micro)structure and electrochemical properties of Si-Ni3Sn4 composites is studied and compared with that of pure Si. Si coating strongly reduces the reaction between Si and Ni3Sn4 during milling. Moreover, contrary to pure silicon, Si-coated composites have a plate-like morphology in which the surface-modified silicon particles are surrounded by a nanostructured, Ni3Sn4-based matrix leading to smooth potential profiles during electrochemical cycling. The chemical homogeneity of the matrix is more uniform for carbon-coated than for oxygen-coated silicon. As a consequence, different electrochemical behaviors are obtained depending on the surface chemistry, with better lithiation properties for the carbon-covered silicon able to deliver over 500 mAh/g for at least 400 cycles.


Author(s):  
J R E Wright ◽  
G E Payne

The Mediterranean migrant crisis has resulted in the highest population displacement since the Second World War. In 2016 alone, over one million made the journey across the sea. Since 2013 over 15,000 have died as a result of this journey. Small vessels such as wooden fishing boats and RIBs are commonly used by smugglers as transport. These are often unseaworthy and filled with numbers of passengers far exceeding their intended capacity. When failure occurs, rescues are typically conducted by the nearest available vessel. These vessels are often ill-equipped for a large-scale Search and Rescue (SAR) operation making it highly dangerous for all involved.  The size and quantity of lifeboats available are often insufficient for the large numbers of people to be rescued; as a result, repeat journeys are required, making the rescue process slow, inefficient and hazardous. This paper outlines a novel solution to this problem. A concept design is presented for a rapidly expandable lifeboat capable of holding large numbers of passengers, whilst still fitting into the operational envelope of common davits. The unique inflatable design can be deployed quickly from a range of vessels and aeroplanes offering an immediate platform from which disembarkation onto a suitable vessel can be achieved. CONOPS are outlined along with the required capabilities of the design. Drop stitch technology is identified as a viable means of manufacturing the large inflatable platforms. Finally, the paper discusses an alternative solution, retrofitting existing enclosed lifeboats with the solution to offer a more cost-effective alternative.  


2020 ◽  
Vol 12 (21) ◽  
pp. 9158
Author(s):  
Xiaomiao Tan ◽  
Jiangyu Zhu ◽  
Minato Wakisaka

The development of efficient, environmentally friendly, low-cost approaches used to boost the growth of microalgae is urgently required to meet the increasing demands for food supplements, cosmetics, and biofuels. In this study, the growth promotion effects of protocatechuic acid (PCA) in the freshwater microalga Euglena gracilis were confirmed for the first time. PCA is a simple phenolic compound derived from natural plants and has a range of biological functions. The highest biomass yield, 3.1-fold higher than that of the control, used at 1.3 g·L−1, was obtained at 800 mg·L−1 of PCA. The yields of the metabolites chlorophyll a, carotenoids, and paramylon in the presence of PCA at 800 mg·L−1 were 3.1, 3.3, and 1.7 times higher than those of the control group, respectively. The highest paramylon yield was achieved at a lower dosage of PCA (100 mg·L−1), which is considered to be feasible for economic paramylon production. The growth and biosynthesis of metabolites stimulated by phytochemicals such as PCA could be an efficient and cost-effective strategy to enhance the productivity of microalgae in large-scale cultivations.


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