Modeling and self-assembly behavior of PEG–PLA–PEG triblock copolymers in aqueous solution

Nanoscale ◽  
2013 ◽  
Vol 5 (19) ◽  
pp. 9010 ◽  
Author(s):  
Xiaohan Wu ◽  
Suming Li ◽  
Fanny Coumes ◽  
Vincent Darcos ◽  
Joséphine Lai Kee Him ◽  
...  
Keyword(s):  
Aqueous Solution ◽  
Self Assembly ◽  
Triblock Copolymers ◽  
Assembly Behavior

scholarly journals Complex Self-Assembly Behavior of Bis-hydrophilic PEO-b-PCL-b-PMOXA Triblock Copolymers in Aqueous Solution

2017 ◽  
Vol 50 (18) ◽  
pp. 7155-7168 ◽  
Author(s):  
Evgeniia V. Konishcheva ◽  
Ulmas E. Zhumaev ◽  
Maximilian Kratt ◽  
Valentin Oehri ◽  
Wolfgang Meier
Keyword(s):  
Aqueous Solution ◽  
Self Assembly ◽  
Triblock Copolymers ◽  
Assembly Behavior

Synthesis and self-assembly behavior of POSS-embedded hyperbranched polymers

2015 ◽  
Vol 51 (39) ◽  
pp. 8296-8299 ◽  
Author(s):  
Dawei Li ◽  
Yuguang Niu ◽  
Yanyu Yang ◽  
Xing Wang ◽  
Fei Yang ◽  
...  
Keyword(s):  
Aqueous Solution ◽  
Self Assembly ◽  
Hyperbranched Polymers ◽  
Simple Approach ◽  
Morphological Transition ◽  
Assembly Behavior

We demonstrate a simple approach to prepare POSS-embedded hyperbranched amphiphiles, presenting morphological transition from micelle to vesicle in aqueous solution.

scholarly journals On the Aqueous Solution Behavior of C-Substituted 3,1,2-Ruthenadicarbadodecaboranes

Inorganics ◽  
2019 ◽  
Vol 7 (7) ◽  
pp. 91 ◽  
Author(s):  
Marta Gozzi ◽  
Benedikt Schwarze ◽  
Peter Coburger ◽  
Evamarie Hey-Hawkins
Keyword(s):  
Aqueous Solution ◽  
Aqueous Solutions ◽  
Self Assembly ◽  
Self Assembling ◽  
Vis Spectroscopy ◽  
Assembly Behavior ◽  
Biological Performance ◽  
Type 3

3,1,2-Ruthenadicarbadodecaborane complexes bearing the [C2B9H11]2− (dicarbollide) ligand are robust scaffolds, with exceptional thermal and chemical stability. Our previous work has shown that these complexes possess promising anti-tumor activities in vitro, and tend to form aggregates (or self-assemblies) in aqueous solutions. Here, we report on the synthesis and characterization of four ruthenium(II) complexes of the type [3-(η6-arene)-1,2-R2-3,1,2-RuC2B9H9], bearing either non-polar (R = Me (2–4)) or polar (R = CO2Me (7)) substituents at the cluster carbon atoms. The behavior in aqueous solution of complexes 2, 7 and the parent unsubstituted [3-(η6-p-cymene)-3,1,2-RuC2B9H11] (8) was investigated via UV-Vis spectroscopy, mass spectrometry and nanoparticle tracking analysis (NTA). All complexes showed spontaneous formation of self-assemblies (108–109 particles mL−1), at low micromolar concentration, with high polydispersity. For perspective applications in medicine, there is thus a strong need for further characterization of the spontaneous self-assembly behavior in aqueous solutions for the class of neutral metallacarboranes, with the ultimate scope of finding the optimal conditions for exploiting this self-assembling behavior for improved biological performance.

scholarly journals Effect of rod–rod interaction on self-assembly behavior of ABC π-conjugated rod–coil–coil triblock copolymers

Soft Matter ◽  
2011 ◽  
Vol 7 (22) ◽  
pp. 10951 ◽  
Author(s):  
Chun-Jie Chang ◽  
Yi-Huan Lee ◽  
Hsin-Lung Chen ◽  
Chien-Hung Chiang ◽  
Hsiu-Fu Hsu ◽  
...  
Keyword(s):  
Self Assembly ◽  
Triblock Copolymers ◽  
Assembly Behavior

Azobenzene-Containing Liquid Crystal Triblock Copolymers: Synthesis, Characterization, and Self-Assembly Behavior

2008 ◽  
Vol 41 (7) ◽  
pp. 2459-2466 ◽  
Author(s):  
Wei Deng ◽  
Pierre-Antoine Albouy ◽  
Emmanuelle Lacaze ◽  
Patrick Keller ◽  
Xiaogong Wang ◽  
...  
Keyword(s):  
Liquid Crystal ◽  
Self Assembly ◽  
Triblock Copolymers ◽  
Assembly Behavior

Synthesis and self-assembly behavior of polyhedral oligomeric silsesquioxane-based triblock copolymers in selective solvents by dissipative particle dynamics simulation

2018 ◽  
Vol 20 (6) ◽  
pp. 4074-4082 ◽  
Author(s):  
Yun Jin ◽  
Danyi Guo ◽  
Bo Li ◽  
Shouping Xu ◽  
Jiang Cheng ◽  
...  
Keyword(s):  
Experimental Data ◽  
Self Assembly ◽  
Triblock Copolymers ◽  
Dissipative Particle Dynamics ◽  
Particle Dynamics ◽  
Dynamics Simulation ◽  
Selective Solvents ◽  
Assembly Behavior ◽  
Oligomeric Silsesquioxane ◽  
Dissipative Particle Dynamics Simulation

Self-assembly behaviors of POSS-based triblock copolymers were studied by DPD, and the results were in qualitative agreement with the experimental data.

scholarly journals SELF-ASSEMBLY OF TRIBLOCK COPOLYMERS IN AQUEOUS SOLUTION

2008 ◽  
Vol 53 (2) ◽  
Author(s):  
BRUNO URBANO ◽  
PATRICIO SILVA ◽  
ANDRÉS F OLEA ◽  
IRMA FUENTES ◽  
FRANCISCO MARTINEZ
Keyword(s):  
Aqueous Solution ◽  
Self Assembly ◽  
Triblock Copolymers
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