scholarly journals Terpyridine–tetrathiafulvalene hybrid ligands and their electroactive metal complexes

2013 ◽  
Vol 37 (5) ◽  
pp. 1427 ◽  
Author(s):  
Esmah Belhadj ◽  
Abdelkrim El-Ghayoury ◽  
Emilie Ripaud ◽  
Leokadiya Zorina ◽  
Magali Allain ◽  
...  
Keyword(s):  
Metal Complexes ◽  
Hybrid Ligands

Metal complexes of tridentate hybrid ligands. I. Cobalt and nickel conlplexes of ligands containing the donor sequence As-N-O

1969 ◽  
Vol 22 (11) ◽  
pp. 2315 ◽  
Author(s):  
B Chiswell ◽  
KW Lee
Keyword(s):  
Metal Complexes ◽  
Electronic Spectra ◽  
Weak Field ◽  
Magnetic Data ◽  
Conductivity Measurements ◽  
Hybrid Ligands ◽  
Cobalt And Nickel

The interaction of the new tridentate ?hybrid? ligand, N-o- dimethylarsino-phenylsalicylaldimine (As-N-O), with cobalt(II) salts leads to the formation of cationic octahedral cobalt(III) complexes of the type [Co(As-N-O)2]+. No cobalt(II) complex entities containing the ligand could be isolated. With nickel(II) salts three types of octahedral complexes were obtained: (a) [Ni(As-N-O)2],H2O, (b) Ni(As-N- O)X,-xH2O (X = Cl, Br, or NCS), (c) [Ni2(As-N-O)3ClO4]. Electronic spectra, conductivity measurements, and magnetic data have been used to determine the structure of the complexes isolated. The ?hybrid? ligand appears to operate overall as a relatively weak field ligand.

scholarly journals 3H-1,3-Azaphospholo[4,5-b]pyridines – novel heterocyclic P,N-bridging or hybrid ligands: synthesis and first d8-transition metal complexes

2016 ◽  
Vol 45 (5) ◽  
pp. 2261-2272 ◽  
Author(s):  
Mohamed Shaker S. Adam ◽  
Markus K. Kindermann ◽  
Peter G. Jones ◽  
Joachim W. Heinicke
Keyword(s):  
Transition Metal ◽  
Metal Complexes ◽  
Transition Metal Complexes ◽  
Heterocyclic Ligands ◽  
Hybrid Ligands

Novel bicyclic P,N-heterocyclic ligands and the first P- and P,N-coordinated LM(0)(CO)5, LRh(COD)Cl, (LPd(All)Cl)2PdCl2 and (LPdCl2)2 transition metal complexes thereof are presented.

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