Metathesis of renewable raw materials—influence of ligands in the indenylidene type catalysts on self-metathesis of methyl oleate and cross-metathesis of methyl oleate with (Z)-2-butene-1,4-diol diacetate

2014 ◽  
Vol 16 (3) ◽  
pp. 1579 ◽  
Author(s):  
Anna Kajetanowicz ◽  
Adrian Sytniczuk ◽  
Karol Grela
Keyword(s):  
Methyl Oleate ◽  
Raw Materials ◽  
Renewable Raw Materials ◽  
Cross Metathesis

Hydrogenolysis of glucose and fructose in glycol solutions over CuO-MgO-ZrO2 catalyst

2020 ◽  
pp. 48-55
Author(s):  
M.E. Sharanda ◽  
◽  
E.A. Bondarenko ◽  
Keyword(s):  
Ethylene Glycol ◽  
Propylene Glycol ◽  
Flow Reactor ◽  
General Trend ◽  
Raw Materials ◽  
Reaction Products ◽  
Renewable Raw Materials ◽  
High Partial Pressure ◽  
Zro2 Catalyst ◽  
Phase Process

Ethylene glycol and propylene glycol are important representatives of polyols. On an industrial scale, they are obtained from petrochemical raw materials. Within a decade, significant efforts were made for the producing of polyols from biologically renewable raw materials - carbohydrates. The general trend for carbohydrate hydrogenolysis includes application of liquid-phase process with the use of modified metal-oxide catalysts, at 120-120 ° C and pressure of 3MPa or above. So high pressure is used for the reason to increase hydrogen solubility, and also due to the high partial pressure of low boiling solvents. We supposed that usage of high boiling solvents could allow hydrogenolysis to be performed at the lower pressure. Ethylene glycol and propylene glycol are of particular interest as such kind of solvent since they are both the main products of glucose hydrogenolysis. In this work, the process of hydrogenolysis of glucose and fructose over Cu / MgO-ZrO2 catalyst have been studied at temperature range of 160-200 °C and a pressure of 0.1-0.3 MPa in a flow reactor. The solvents were simultaneously the target products of the reaction - ethylene glycol and / or propylene glycol. Gas chromatography and 13C NMR were used for the reaction products identification. It was found that the solubility of glucose in propylene glycol is 21 % by weight, and in ethylene glycol 62% by weight. It was pointed out that the process of hydrogenolysis can take place at a pressure close to atmospheric. Under these conditions, the conversion of hexoses reaches 96-100 %. The reaction products are preferably propylene glycol and ethylene glycol. The total selectivity for C3-2 polyols is 90-94 %, that is higher than in the hydrogenolysis of glucose in aqueous solution.

scholarly journals Organizational, technical and economic fundamentals of waste management and monitoring

2020 ◽  
Vol 164 ◽  
pp. 08031
Author(s):  
Evgeniy Velichko ◽  
Edward Tshovrebov ◽  
Ural Niyazgulov
Keyword(s):  
Legal Status ◽  
Raw Materials ◽  
Economic Regulation ◽  
Economic Activities ◽  
Renewable Raw Materials ◽  
Secondary Resources ◽  
Secondary Raw Materials ◽  
Production And Consumption ◽  
Level Of Use ◽  
Goals And Objectives

The article deals with issues of monitoring, planning, organizational and technical support, economic regulation and improving the efficiency of the infrastructure for processing, recycling and disposal of waste, resource conservation and management of secondary resources, their use as secondary raw materials for production, services, work and power generation. The Russian Federation has significant potential for economic growth due to the efficient use of secondary resources from billions of tons of generated production and consumption waste annually. These ecologically unsafe anthropogenic objects can be characterized as a source of valuable renewable raw materials, material and fuel and energy resources. However, the scale and level of use of various types of secondary resources are characterized by considerable unevenness and depend on the demand for secondary raw materials, the resource value of the waste, the environmental situation arising from treating them as environmental polluters, on the real economic conditions that determine the profitability of each specific type. economic activities that use secondary resources for the manufacture of products, works, services, energy production. The methods of monitoring the industry for the treatment, disposal and disposal of waste are: information-analytical, information-statistical, sociological, geo-information. The legal status of the monitoring system of the industry for the treatment, disposal and disposal of waste is determined by the limitations of its functionality within the framework of the goals and objectives facing it.

scholarly journals Palm Olein as Renewable Raw Materials for Industrial and Pharmaceutical Products Applications: Chemical Characterization and Physicochemical Properties Studies

2014 ◽  
Vol 2014 ◽  
pp. 1-5 ◽  
Author(s):  
Darfizzi Derawi ◽  
Bashar Mudhaffar Abdullah ◽  
Hasniza Zaman Huri ◽  
Rahimi M. Yusop ◽  
Jumat Salimon ◽  
...  
Keyword(s):  
Chemical Modification ◽  
Palm Olein ◽  
Raw Materials ◽  
Viscosity Index ◽  
Chemical Characterization ◽  
Pharmaceutical Products ◽  
Raw Material ◽  
Chemical Compositions ◽  
Renewable Raw Materials ◽  
Modification Process

Palm olein (POo) is widely produced as edible oil in tropical countries. POois considered as renewable raw material for the new industrial and pharmaceutical products synthesis based on its characterization. Palm olein was good on its viscosity index, oxidative stability, and flash and fire point. POocontained unsaturated triacylglycerols (TAGs): POO (33.3%); POP (29.6%) which plays an important role in chemical modification process to produce new industrial products. The double bond was detected on1H-NMR (5.3 ppm) and13C-NMR (130 ppm) spectra. The chemical compositions of POowere tested by using high performance liquid chromatography (HPLC) and gas chromatography (GC) techniques. This unsaturated oil is potentially to be used as renewable raw materials in chemical modification process to synthesise polyols, polyurethane, and biolubricant for industrial and pharmaceutical products application.

scholarly journals Equilibrium data for the cross-metathesis of methyl oleate with cinnamaldehyde

Data in Brief ◽  
2018 ◽  
Vol 20 ◽  
pp. 190-195
Author(s):  
Pablo D. Nieres ◽  
Andrés F. Trasarti ◽  
Carlos R. Apesteguía
Keyword(s):  
Methyl Oleate ◽  
Cross Metathesis ◽  
Equilibrium Data ◽  
The Cross

The role of catalysis in the synthesis of polyurethane foams based on renewable raw materials

2014 ◽  
Vol 223 ◽  
pp. 148-156 ◽  
Author(s):  
Sylwia Dworakowska ◽  
Dariusz Bogdał ◽  
Federica Zaccheria ◽  
Nicoletta Ravasio
Keyword(s):  
Raw Materials ◽  
Polyurethane Foams ◽  
Renewable Raw Materials

Surfactants Based on Renewable Raw Materials

2021 ◽  
pp. 1-12
Author(s):  
Divya Bajpai Tripathy ◽  
Anjali Gupta ◽  
Anuradha Mishra
Keyword(s):  
Raw Materials ◽  
Renewable Raw Materials
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