Molecular and electronic structure of nonradical homoleptic pyridyl-azo-oxime complexes of cobalt(iii) and the azo-oxime anion radical congener: an experimental and theoretical investigation

2014 ◽  
Vol 43 (14) ◽  
pp. 5317-5334 ◽  
Author(s):  
Shuvam Pramanik ◽  
Sima Roy ◽  
Tapas Ghorui ◽  
Sanjib Ganguly ◽  
Kausikisankar Pramanik
Keyword(s):  
Electronic Structure ◽  
Theoretical Investigation ◽  
Anion Radical ◽  
Molecular And Electronic Structure

Synthesis and optoelectronic study of Co(iii)–pyridyl-azo-oxime complexes and isolation of Co(iii)-bound azo-oxime anion radical.

Luminescent closed shell nickel(ii) pyridyl-azo-oximates and the open shell anion radical congener: molecular and electronic structure, ligand redox behaviour and biological activity

2017 ◽  
Vol 41 (10) ◽  
pp. 4157-4164 ◽  
Author(s):  
Shuvam Pramanik ◽  
Suhana Dutta ◽  
Sima Roy ◽  
Soumitra Dinda ◽  
Tapas Ghorui ◽  
...  
Keyword(s):  
Electronic Structure ◽  
Biological Activity ◽  
Anion Radical ◽  
Closed Shell ◽  
Open Shell ◽  
Redox Behaviour ◽  
Redox Active ◽  
Molecular And Electronic Structure ◽  
Anion Radicals

Luminescent nickel(ii) complexes have been synthesized using redox-active azo-oximes. The superior π-acidity of the organic backbone is a key to the isolation of Ni(ii) anion radicals.

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