Half-sandwich bis(propiolamidinate) rare-earth metal complexes: synthesis, structure and dissociation of the cyclopentadienyl ligand via competition with an amidinate

2013 ◽  
Vol 42 (47) ◽  
pp. 16466 ◽  
Author(s):  
Ling Xu ◽  
Yu-Chen Wang ◽  
Wen-Xiong Zhang ◽  
Zhenfeng Xi
Keyword(s):  
Rare Earth ◽  
Metal Complexes ◽  
Rare Earth Metal ◽  
Earth Metal ◽  
Cyclopentadienyl Ligand ◽  
Rare Earth Metal Complexes ◽  
Half Sandwich

Half-sandwich rare-earth metal complexes bearing a C5Me4-C6H4-o-CH2NMe2 ligand: synthesis, characterization and catalytic properties for isoprene, 1-hexene and MMA polymerization

2019 ◽  
Vol 48 (48) ◽  
pp. 17840-17851
Author(s):  
Tingting Song ◽  
Ning Liu ◽  
Xiaobo Tong ◽  
Feng Li ◽  
Xiaoyue Mu ◽  
...  
Keyword(s):  
Rare Earth ◽  
Metal Complexes ◽  
Rare Earth Metal ◽  
Catalytic Properties ◽  
Earth Metal ◽  
Ligand Synthesis ◽  
Rare Earth Metal Complexes ◽  
Mma Polymerization ◽  
Half Sandwich

New rare-earth metal complexes bearing the ligand C5Me4-C6H4-o-CH2NMe2 were synthesized and studied as precatalysts for isoprene, 1-hexene and MMA polymerization.

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