Metal–organic frameworks built from achiral 3-(5-(pyridin-4-yl)-4H-1,2,4-triazol-3-yl)benzoic acid: syntheses and structures of metal(ii) complexes

2014 ◽  
Vol 43 (1) ◽  
pp. 145-151 ◽  
Author(s):  
Yun Gong ◽  
Miao Miao Zhang ◽  
Wei Hua ◽  
Jun Liang Sun ◽  
Hui Fang Shi ◽  
...  
Keyword(s):  
Benzoic Acid ◽  
Metal Organic Frameworks ◽  
Metal Organic

Two pyrene-based metal−organic frameworks constructed from 1,3,6,8-tetrakis(p-benzoic acid)pyrene: Syntheses, structures and photoelectron performances

2020 ◽  
Vol 285 ◽  
pp. 121252 ◽  
Author(s):  
Ya-Dan Huang ◽  
Jian-Hua Qin ◽  
Xiao-Gang Yang ◽  
Hua-Rui Wang ◽  
Fei-Fei Li ◽  
...  
Keyword(s):  
Benzoic Acid ◽  
Metal Organic Frameworks ◽  
Metal Organic

Acentric and chiral four-connected metal–organic frameworks based on the racemic binaphthol-like chiral ligand of 4-(1-H(or methyl)-imidaozol-1-yl)benzoic acid

CrystEngComm ◽  
2011 ◽  
Vol 13 (10) ◽  
pp. 3432 ◽  
Author(s):  
Ke-Hui Cui ◽  
Shi-Yan Yao ◽  
Hai-Qin Li ◽  
Yan-Tao Li ◽  
Hai-Ping Zhao ◽  
...  
Keyword(s):  
Benzoic Acid ◽  
Metal Organic Frameworks ◽  
Chiral Ligand ◽  
Metal Organic

Syntheses, structures, luminescence and magnetic properties of seven isomorphous metal–organic frameworks based on 2,7-bis(4-benzoic acid)-N-(4-benzoic acid)carbazole

2018 ◽  
Vol 42 (4) ◽  
pp. 2830-2837 ◽  
Author(s):  
Dong-Hui Chen ◽  
Ling Lin ◽  
Tian-Lu Sheng ◽  
Yue-Hong Wen ◽  
Xiao-Quan Zhu ◽  
...  
Keyword(s):  
Magnetic Properties ◽  
Benzoic Acid ◽  
Metal Organic Frameworks ◽  
Metal Organic ◽  
Lanthanide Metal

Seven isomorphous lanthanide metal–organic frameworks with special luminescence and magnetic properties are synthesized and characterized.

scholarly journals A Family of Luminescent Metal Organic Frameworks: Synthesis, Structural, and Sensing Studies

2021 ◽  
Author(s):  
P. Hariprasad ◽  
Nageswara Rao Tentu ◽  
Faheem Ahmed ◽  
Yarasani Prashanthi
Keyword(s):  
Benzoic Acid ◽  
Metal Organic Frameworks ◽  
Metal Organic

Herein we report, three novel luminescent Metal-Organic frame works (MOFs) viz.[Co(bpeb)(hfipbb)0.5]n (LCo-1), [Zn(bpeb)2(hfipbb)]n (LZn) and [Co(bpeb)2 (oba)]n (LCo-2),(where bpeb, hfipbb and oba represents (1,4-bis[2-(4-pyridyl)ethenyl] benzene),4,4′-(Hexafluoroisopropylidene)bis(benzoic acid) and 4,41-Oxybis(benzoic acid) respectively);...

scholarly journals Triazolium-Containing Metal–Organic Frameworks: Control of Catenation in 2D Copper(II) Paddlewheel Structures

2013 ◽  
Vol 66 (4) ◽  
pp. 409 ◽  
Author(s):  
Alexandre Burgun ◽  
Christian J. Doonan ◽  
Christopher J. Sumby
Keyword(s):  
Benzoic Acid ◽  
Heterogeneous Catalyst ◽  
Click Reaction ◽  
Metal Organic Frameworks ◽  
Ester Hydrolysis ◽  
Charge Balance ◽  
Reaction Conditions ◽  
Metal Organic ◽  
Methyl Triflate

One approach to exploit metal–organic frameworks (MOFs) as heterogeneous catalyst platforms requires the development of materials containing groups that can be utilised to anchor a catalytic moiety into the links within the structure. Here we report the synthesis of the first integrated triazolium-containing MOF linker and the first MOFs containing linkers of this type. 1,4-Bis(4-benzoic acid)-1-methyl-1H-1,2,3-triazolium chloride, H2L1Me, was synthesised in three steps by a ‘click’ reaction of methyl 4-ethynylbenzoate with methyl 4-azidobenzoate, methylation using methyl triflate, followed by ester hydrolysis in overall 74 % yield. The equivalent neutral triazole precursor, 1,4-bis(4-benzoic acid)-1H-1,2,3-triazole hydrochloride, H2L1(HCl), was also prepared and a comparison of the chemistry with Zn(NO3)2·6H2O and Cu(NO3)2·3H2O is presented. The results support the use of reaction conditions to control interpenetration and provide additional evidence that the charge on structurally similar ligands can drastically alter the types of structures that are accessible due to the requirements for charge balance in the final product.

Self-assembly of a series of metal–organic frameworks with semi-rigid multicarboxylate 3,4-bis(carboxymethoxy)benzoic acid ligands

Polyhedron ◽  
2017 ◽  
Vol 135 ◽  
pp. 60-71 ◽  
Author(s):  
Xiao-Zong Li ◽  
Can Zhao ◽  
You Zhang ◽  
Ting Luo ◽  
Yi-Hang Wen ◽  
...  
Keyword(s):  
Benzoic Acid ◽  
Self Assembly ◽  
Metal Organic Frameworks ◽  
Metal Organic

Three novel topologically different metal–organic frameworks built from 3-nitro-4-(pyridin-4-yl)benzoic acid

2019 ◽  
Vol 75 (2) ◽  
pp. 150-160 ◽  
Author(s):  
Tao Qin ◽  
Shunlin Zhang ◽  
Yixiong Wang ◽  
Tianjiao Hou ◽  
Dunru Zhu ◽  
...  
Keyword(s):  
Benzoic Acid ◽  
Gas Adsorption ◽  
Metal Organic Frameworks ◽  
Three Dimensional ◽  
Crystal Structure Analysis ◽  
Coordination Geometry ◽  
Design And Synthesis ◽  
Connected Node ◽  
Metal Organic ◽  
3D Framework

The design and synthesis of metal–organic frameworks (MOFs) have attracted much interest due to the intriguing diversity of their architectures and topologies. However, building MOFs with different topological structures from the same ligand is still a challenge. Using 3-nitro-4-(pyridin-4-yl)benzoic acid (HL) as a new ligand, three novel MOFs, namely poly[[(N,N-dimethylformamide-κO)bis[μ2-3-nitro-4-(pyridin-4-yl)benzoato-κ3 O,O′:N]cadmium(II)] N,N-dimethylformamide monosolvate methanol monosolvate], {[Cd(C12H7N2O4)2(C3H7NO)]·C3H7NO·CH3OH} n , (1), poly[[(μ2-acetato-κ2 O:O′)[μ3-3-nitro-4-(pyridin-4-yl)benzoato-κ3 O:O′:N]bis[μ3-3-nitro-4-(pyridin-4-yl)benzoato-κ4 O,O′:O′:N]dicadmium(II)] N,N-dimethylacetamide disolvate monohydrate], {[Cd2(C12H7N2O4)3(CH3CO2)]·2C4H9NO·H2O} n , (2), and catena-poly[[[diaquanickel(II)]-bis[μ2-3-nitro-4-(pyridin-4-yl)benzoato-κ2 O:N]] N,N-dimethylacetamide disolvate], {[Ni(C12H7N2O4)2(H2O)2]·2C4H9NO} n , (3), have been prepared. Single-crystal structure analysis shows that the CdII atom in MOF (1) has a distorted pentagonal bipyramidal [CdN2O5] coordination geometry. The [CdN2O5] units as 4-connected nodes are interconnected by L − ligands to form a fourfold interpenetrating three-dimensional (3D) framework with a dia topology. In MOF (2), there are two crystallographically different CdII ions showing a distorted pentagonal bipyramidal [CdNO6] and a distorted octahedral [CdN2O4] coordination geometry, respectively. Two CdII ions are connected by three carboxylate groups to form a binuclear [Cd2(COO)3] cluster. Each binuclear cluster as a 6-connected node is further linked by acetate groups and L − ligands to produce a non-interpenetrating 3D framework with a pcu topology. MOF (3) contains two crystallographically distinct NiII ions on special positions. Each NiII ion adopts an elongated octahedral [NiN2O4] geometry. Each NiII ion as a 4-connected node is linked by L − ligands to generate a two-dimensional network with an sql topology, which is further stabilized by two types of intermolecular OW—HW...O hydrogen bonds to form a 3D supramolecular framework. MOFs (1)–(3) were also characterized by powder X-ray diffraction, IR spectroscopy and thermogravimetic analysis. Furthermore, the solid-state photoluminescence of HL and MOFs (1) and (2) have been investigated. The photoluminescence of MOFs (1) and (2) are enhanced and red-shifted with respect to free HL. The gas adsorption investigation of MOF (2) indicates a good separation selectivity (71) of CO2/N2 at 273 K (i.e. the amount of CO2 adsorption is 71 times higher than N2 at the same pressure).

Defect creation by benzoic acid in Cu-Based Metal−Organic frameworks for enhancing sulfur capture

2020 ◽  
Vol 298 ◽  
pp. 110070 ◽  
Author(s):  
Hong-Yan Zhang ◽  
Rui-Hua Shi ◽  
Hui-Ling Fan ◽  
Chao Yang ◽  
Chao-Nan Zhang ◽  
...  
Keyword(s):  
Benzoic Acid ◽  
Metal Organic Frameworks ◽  
Defect Creation ◽  
Metal Organic ◽  
Sulfur Capture
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