scholarly journals Preparation of tetrabutylammonium salt of a mono-Ru(iii)-substituted α-Keggin-type silicotungstate with a 4,4′-bipyridine ligand and its electrochemical behaviour in organic solvents

2013 ◽  
Vol 42 (19) ◽  
pp. 7190 ◽  
Author(s):  
Shuhei Ogo ◽  
Sachie Moroi ◽  
Tadaharu Ueda ◽  
Kenji Komaguchi ◽  
Shinjiro Hayakawa ◽  
...  
Keyword(s):  
Organic Solvents ◽  
Electrochemical Behaviour ◽  
Keggin Type ◽  
Tetrabutylammonium Salt ◽  
Bipyridine Ligand

On the effect of ion pairing of Keggin type polyanions with quaternary ammonium cations on redox potentials in organic solvents

2016 ◽  
Vol 18 (32) ◽  
pp. 22487-22493 ◽  
Author(s):  
Bo Chen ◽  
Ronny Neumann
Keyword(s):  
Electrochemical Properties ◽  
Organic Solvents ◽  
Quaternary Ammonium ◽  
Ion Pairing ◽  
Redox Potentials ◽  
Quaternary Ammonium Cations ◽  
Keggin Type

The electrochemical properties of polyoxometalates in organic solvents show an interrelation between redox potentials, solvents and ion pairing.

The Mechanisms of Racemization of the 2,2'-Bipyridinebis-(1,10-phenanthroline) nickel(II) Ion and the 1,10-Phenanthrolinebis-(2,2'-bipyridine)-nickel(II) Ion

1963 ◽  
Vol 16 (1) ◽  
pp. 51 ◽  
Author(s):  
JA Broomhead ◽  
FP Dwyer
Keyword(s):  
Acid Solution ◽  
Organic Solvents ◽  
Intermolecular Mechanism ◽  
Basic Solutions ◽  
Bipyridine Ligand

The rates of racemization of the 1,10-phenanthrolinebis-(2,2'-bipyridine)nickel(II) ion and the 2,2'-bipyridinebis-(1,10-phenanthroline)nickel(II) ion have been measured in neutral, acid, and basic solutions as well as in organic solvents. Comparison of the rates in acid solution with the corresponding rates of dissociation has shown that racemization takes place by means of an intermolecular mechanism with the loss of one bipyridine ligand. Increased racemization rates in the presence of acids, bases, and specific ions such as NO2-;, Cl-, Br- have been accounted for by the same mechanism.

On electrochemical behaviour of zinc in organic solvents

1987 ◽  
Vol 32 (6) ◽  
pp. 891-894 ◽  
Author(s):  
S. Bia&ł;&ł;ozór ◽  
E.T. Bandura
Keyword(s):  
Organic Solvents ◽  
Electrochemical Behaviour

Effect of crown ethers on synthesis of polyaniline and its electrochemical behaviour in organic solvents

1993 ◽  
Vol 60 (1) ◽  
pp. 81-83 ◽  
Author(s):  
V.D. Pokhodenko ◽  
V.A. Krylov ◽  
Ja.I. Kurys ◽  
V.G. Golovaty ◽  
V.P. Shabelnikov
Keyword(s):  
Organic Solvents ◽  
Crown Ethers ◽  
Electrochemical Behaviour
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