A comparative study of the redox and excited state properties of (nBu4N)2[Mo6X14] and (nBu4N)2[Mo6X8(CF3COO)6] (X = Cl, Br, or I)

2013 ◽  
Vol 42 (19) ◽  
pp. 7224 ◽  
Author(s):  
Kaplan Kirakci ◽  
Pavel Kubát ◽  
Jan Langmaier ◽  
Tomáš Polívka ◽  
Marcel Fuciman ◽  
...  
Keyword(s):  
Excited State ◽  
Comparative Study

Excited State Tautomerization of 7-Azaindole in a 1:1 Complex with δ-Valerolactam: A Comparative Study with the Homodimer

2012 ◽  
Vol 116 (40) ◽  
pp. 9888-9896 ◽  
Author(s):  
Moitrayee Mukherjee ◽  
Shreetama Karmakar ◽  
Tapas Chakraborty
Keyword(s):  
Excited State ◽  
Comparative Study

scholarly journals Ground and excited-state electron-transfer reactions of a few (anthracen-9-yl)methanamines: a comparative study

ARKIVOC ◽  
2015 ◽  
Vol 2015 (7) ◽  
pp. 270-283
Author(s):  
Jomon P. Jacob ◽  
Ligi M. Lalu ◽  
Reshma Gopalakrishnan ◽  
Rekha R. Mallia ◽  
Perupparampil A. Unnikrishnan ◽  
...  
Keyword(s):  
Electron Transfer ◽  
Excited State ◽  
Comparative Study ◽  
Transfer Reactions ◽  
Electron Transfer Reactions ◽  
State Electron

scholarly journals Effect of Photolysis on Zirconium Amino Phenoxides for the Hydrophosphination of Alkenes: Improving Catalysis

2021 ◽  
Author(s):  
Bryan Novas ◽  
Jacob Morris ◽  
Matthew Liptak ◽  
Rory Waterman
Keyword(s):  
Excited State ◽  
Charge Transfer ◽  
Comparative Study ◽  
Enhanced Activity ◽  
Td Dft ◽  
Zirconium Catalysts

A comparative study of amino phenoxide zirconium catalysts in the hydrophosphination of alkenes with diphenylphosphine reveals enhanced activity upon irradiation. The origin of improved reactivity is hypothesized to result from substrate insertion upon an n to d charge transfer of a Zr–P bond in the excited state of putative phosphido (Zr–PR2) intermediates. TD-DFT analysis reveals the lowest lying excited state in the proposed active catalysts are dominated by a P 3p to Zr 4d MLCT, presumably leading to enhanced catalysis. This hypothesis follows from triamidoamine-supported zirconium catalysts but demonstrates the generality of photocatalytic hydrophosphination with d0 metals.

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