Selective oxidation of thiourea with H2O2 catalyzed by [RuIII(edta)(H2O)]−: kinetic and mechanistic studies

2013 ◽  
Vol 42 (13) ◽  
pp. 4725 ◽  
Author(s):  
Debabrata Chatterjee ◽  
Sabine Rothbart ◽  
Rudi van Eldik
Keyword(s):  
Selective Oxidation ◽  
Mechanistic Studies

Organocatalytic oxidation of substituted anilines to azoxybenzenes and nitro compounds: mechanistic studies excluding the involvement of a dioxirane intermediate

2017 ◽  
Vol 19 (5) ◽  
pp. 1291-1298 ◽  
Author(s):  
Errika Voutyritsa ◽  
Alexis Theodorou ◽  
Maroula G. Kokotou ◽  
Christoforos G. Kokotos
Keyword(s):  
Selective Oxidation ◽  
Environmentally Friendly ◽  
Nitro Compounds ◽  
Mechanistic Studies ◽  
Substituted Anilines

Organocatalytic and environmentally friendly approaches for the selective oxidation of substituted anilines either to azoxybenzenes or to nitro compounds were developed.

Selective oxidation of organic sulfides to sulfoxides using sugar derived cis-dioxo molybdenum(vi) complexes: kinetic and mechanistic studies

RSC Advances ◽  
2016 ◽  
Vol 6 (33) ◽  
pp. 28015-28022 ◽  
Author(s):  
Noorullah Baig ◽  
Vimal Kumar Madduluri ◽  
Ajay K. Sah
Keyword(s):  
Selective Oxidation ◽  
Mechanistic Studies ◽  
Selective Transformation ◽  
Organic Sulfides

Six cis-dioxo molybdenum(vi) complexes of d-glucose derived ligands have been applied as catalysts for the selective transformation of organic sulfides to sulfoxides, and kinetics as well as mechanistic aspects of this reaction have been explored.

Selective oxidation of aniline into azoxybenzene catalyzed by Nb-peroxo@iron oxides at room temperature

2020 ◽  
Vol 44 (21) ◽  
pp. 8710-8717
Author(s):  
André L. D. Lima ◽  
Humberto V. Fajardo ◽  
André E. Nogueira ◽  
Márcio C. Pereira ◽  
Luiz C. A. Oliveira ◽  
...  
Keyword(s):  
Iron Oxides ◽  
Selective Oxidation ◽  
Room Temperature ◽  
High Selectivity

Nb-peroxo@iron oxides show high selectivity and activity in aniline conversion to azoxybenzene.

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