Kinetics and catalyst deactivation in the enantioselective hydrogenation of ethyl benzoylformate over Pt/Al2O3

2014 ◽  
Vol 4 (1) ◽  
pp. 170-178 ◽  
Author(s):  
Gerson Martin ◽  
Päivi Mäki-Arvela ◽  
Dmitry Yu. Murzin ◽  
Tapio Salmi
Keyword(s):  
Catalyst Deactivation ◽  
Enantioselective Hydrogenation ◽  
Ethyl Benzoylformate

Kinetic Modeling of Ethyl Benzoylformate Enantioselective Hydrogenation over Pt/Al2O3

2014 ◽  
Vol 53 (30) ◽  
pp. 11945-11953 ◽  
Author(s):  
Gerson Martin ◽  
Päivi Mäki-Arvela ◽  
Johan Wärnå ◽  
Karoliina Honkala ◽  
Dmitry Yu. Murzin ◽  
...  
Keyword(s):  
Kinetic Modeling ◽  
Enantioselective Hydrogenation ◽  
Ethyl Benzoylformate

Enantioselective Hydrogenation of Ethyl Benzoylformate, from Mechanism and Kinetics to Continuous Reactor Technology

2014 ◽  
Vol 57 (17-20) ◽  
pp. 1576-1581
Author(s):  
Gerson Martin ◽  
Päivi Mäki-Arvela ◽  
Johan Wärnå ◽  
Dmitry Yu. Murzin ◽  
Tapio Salmi
Keyword(s):  
Enantioselective Hydrogenation ◽  
Continuous Reactor ◽  
Reactor Technology ◽  
Mechanism And Kinetics ◽  
Ethyl Benzoylformate

Solvent Effects in the Enantioselective Hydrogenation of Ethyl Benzoylformate

2013 ◽  
Vol 143 (10) ◽  
pp. 1051-1060 ◽  
Author(s):  
Gerson Martin ◽  
Päivi Mäki-Arvela ◽  
Dmitry Yu. Murzin ◽  
Tapio Salmi
Keyword(s):  
Solvent Effects ◽  
Enantioselective Hydrogenation ◽  
Ethyl Benzoylformate

What catalysis needs from the electron microscopist

1988 ◽  
Vol 46 ◽  
pp. 694-695
Author(s):  
Alexis T. Bell
Keyword(s):  
Active Sites ◽  
Heterogeneous Catalysts ◽  
Catalyst Deactivation ◽  
Surface Composition ◽  
Internal Surface ◽  
Active Phase ◽  
Atomic Scale ◽  
Metal Catalyst ◽  
Internal Surface Area ◽  
Porous Support

Heterogeneous catalysts, used in industry for the production of fuels and chemicals, are microporous solids characterized by a high internal surface area. The catalyticly active sites may occur at the surface of the bulk solid or of small crystallites deposited on a porous support. An example of the former case would be a zeolite, and of the latter, a supported metal catalyst. Since the activity and selectivity of a catalyst are known to be a function of surface composition and structure, it is highly desirable to characterize catalyst surfaces with atomic scale resolution. Where the active phase is dispersed on a support, it is also important to know the dispersion of the deposited phase, as well as its structural and compositional uniformity, the latter characteristics being particularly important in the case of multicomponent catalysts. Knowledge of the pore size and shape is also important, since these can influence the transport of reactants and products through a catalyst and the dynamics of catalyst deactivation.

Analytical Electron Microscopy study of two vehicle-aged automotive exhaust catalysts having dissimilar activities

1989 ◽  
Vol 47 ◽  
pp. 272-273
Author(s):  
Sooho Kim ◽  
M. J. D’Aniello
Keyword(s):  
Electron Microscopy ◽  
Particle Size ◽  
Noble Metal ◽  
Catalyst Deactivation ◽  
Analytical Electron Microscopy ◽  
Microscopy Study ◽  
Metal Particles ◽  
Automotive Exhaust ◽  
Exhaust Catalysts ◽  
Analytical Electron

Automotive catalysts generally lose-agtivity during vehicle operation due to several well-known deactivation mechanisms. To gain a more fundamental understanding of catalyst deactivation, the microscopic details of fresh and vehicle-aged commercial pelleted automotive exhaust catalysts containing Pt, Pd and Rh were studied by employing Analytical Electron Microscopy (AEM). Two different vehicle-aged samples containing similar poison levels but having different catalytic activities (denoted better and poorer) were selected for this study.The general microstructure of the supports and the noble metal particles of the two catalysts looks similar; the noble metal particles were generally found to be spherical and often faceted. However, the average noble metal particle size on the poorer catalyst (21 nm) was larger than that on the better catalyst (16 nm). These sizes represent a significant increase over that found on the fresh catalyst (8 nm). The activity of these catalysts decreases as the observed particle size increases.

An analytical microscopic study of metals in fluidized catalytic cracking catalyst

1986 ◽  
Vol 44 ◽  
pp. 854-855
Author(s):  
Clifford S. Rainey
Keyword(s):  
Electron Microscopy ◽  
Spatial Distribution ◽  
Catalytic Cracking ◽  
Catalyst Deactivation ◽  
Coke Formation ◽  
Acid Sites ◽  
Y Zeolite ◽  
Fcc Catalyst ◽  
Fluidized Catalytic Cracking ◽  
High Regeneration

The spatial distribution of V and Ni deposited within fluidized catalytic cracking (FCC) catalyst is studied because these metals contribute to catalyst deactivation. Y zeolite in FCC microspheres are high SiO2 aluminosilicates with molecular-sized channels that contain a mixture of lanthanoids. They must withstand high regeneration temperatures and retain acid sites needed for cracking of hydrocarbons, a process essential for efficient gasoline production. Zeolite in combination with V to form vanadates, or less diffusion in the channels due to coke formation, may deactivate catalyst. Other factors such as metal "skins", microsphere sintering, and attrition may also be involved. SEM of FCC fracture surfaces, AEM of Y zeolite, and electron microscopy of this work are developed to better understand and minimize catalyst deactivation.

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