The synthesis of multiphasic ionic liquid-coated Pt/Al2O3catalysts: the selective synchronous hydrogenation of CC and CO bonds and the modeling of the ionic liquid and solvent effects

2014 ◽  
Vol 4 (2) ◽  
pp. 447-455 ◽  
Author(s):  
Reza Vatan Meidanshahi ◽  
Mahboubeh Tasviri ◽  
Mohammad Khodadadi-Moghaddam ◽  
Mohammad Reza Gholami
Keyword(s):  
Ionic Liquid ◽  
Solvent Effects

Monitoring an ionic liquid synthesis with in-situ IR-spectroscopy – The intricacy of solvent effects

2019 ◽  
Vol 368 ◽  
pp. 649-658 ◽  
Author(s):  
Andreas Ohligschläger ◽  
Christoph Gertig ◽  
Dario Coenen ◽  
Sebastian Brosch ◽  
Dzmitry Firaha ◽  
...  
Keyword(s):  
Ionic Liquid ◽  
Ir Spectroscopy ◽  
Solvent Effects ◽  
In Situ Ir ◽  
In Situ Ir Spectroscopy

scholarly journals Investigating Solvent Effects of an Ionic Liquid on Pericyclic Reactions through Kinetic Analyses of Simple Rearrangements

ChemPlusChem ◽  
2017 ◽  
Vol 82 (3) ◽  
pp. 449-457 ◽  
Author(s):  
Sinead T. Keaveney ◽  
Ronald S. Haines ◽  
Jason B. Harper
Keyword(s):  
Ionic Liquid ◽  
Solvent Effects ◽  
Pericyclic Reactions

scholarly journals Solvent effects of 1-ethyl-3-methylimidazolium acetate: solvation and dynamic behavior of polar and apolar solutes

2015 ◽  
Vol 17 (13) ◽  
pp. 8480-8490 ◽  
Author(s):  
Volker Lesch ◽  
Andreas Heuer ◽  
Christian Holm ◽  
Jens Smiatek
Keyword(s):  
Molecular Dynamics ◽  
Ionic Liquid ◽  
Dynamic Behavior ◽  
Solvent Effects ◽  
Room Temperature ◽  
Md Simulations ◽  
Charged Model

We study the solvation properties of the ionic liquid 1-ethyl-3-methylimidazolium acetate ([eMIM]+[ACE]−) and the resulting dynamic behavior for differently charged model solutes at room temperature via atomistic molecular dynamics (MD) simulations of 500 ns length.

Cleavage of ethers in an ionic liquid. Enhancement, selectivity and potential application

2017 ◽  
Vol 15 (26) ◽  
pp. 5556-5563 ◽  
Author(s):  
William E. S. Hart ◽  
Leigh Aldous ◽  
Jason B. Harper
Keyword(s):  
Ionic Liquid ◽  
Solvent Effects ◽  
Potential Application ◽  
Side Reactions ◽  
Ether Cleavage

An ionic liquid is used to facilitate ether cleavage without the presence of side reactions; the microscopic origins of the solvent effects are examined. Controlled cleavage of this kind of ether is relevant in the fractionation of lignin.

scholarly journals Pressure, Isotope, and Water Co-solvent Effects in Liquid−Liquid Equilibria of (Ionic Liquid + Alcohol) Systems

2003 ◽  
Vol 107 (46) ◽  
pp. 12797-12807 ◽  
Author(s):  
Vesna Najdanovic-Visak ◽  
José M. S. S. Esperança ◽  
Luís P. N. Rebelo ◽  
Manuel Nunes da Ponte ◽  
Henrique J. R. Guedes ◽  
...  
Keyword(s):  
Ionic Liquid ◽  
Solvent Effects

Ionic liquid solvents: the importance of microscopic interactions in predicting organic reaction outcomes

2017 ◽  
Vol 89 (6) ◽  
pp. 745-757 ◽  
Author(s):  
Sinead T. Keaveney ◽  
Ronald S. Haines ◽  
Jason B. Harper
Keyword(s):  
Ionic Liquid ◽  
Ionic Liquids ◽  
Transition State ◽  
Physical Properties ◽  
Solvent Effects ◽  
Recent Progress ◽  
Comprehensive Understanding ◽  
Organic Reaction ◽  
Microscopic Interactions ◽  
Molecular Solvents

AbstractIonic liquids are attractive alternatives to molecular solvents as they have many favourable physical properties and can produce different organic reaction outcomes compared to molecular solvents. Thus far, interactions between the ionic liquid components and specific sites (such as charged centres, lone pairs and π systems) on the reagents and transition state have been identified as affecting reaction outcome; a comprehensive understanding of these interactions is necessary to allow prediction of ionic liquid solvent effects. This manuscript summarises our recent progress in the development of a framework for predicting the effect of an ionic liquid solvent on the outcome of organic processes. There will be a particular focus on the importance of the different interactions between the ionic liquid components and the species along the reaction coordinate that are responsible for the changes in reaction outcome observed in the cases described.

Nitrogen versus phosphorus nucleophiles – how changing the nucleophilic heteroatom affects ionic liquid solvent effects in bimolecular nucleophilic substitution processes

2016 ◽  
Vol 40 (9) ◽  
pp. 7437-7444 ◽  
Author(s):  
Karin S. Schaffarczyk McHale ◽  
Rebecca R. Hawker ◽  
Jason B. Harper
Keyword(s):  
Ionic Liquid ◽  
Nucleophilic Substitution ◽  
Solvent Effects ◽  
Reaction Coordinate

Changing the nucleophile gave different ionic liquid effects, showing the importance of interactions with all species along the reaction coordinate.

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