Band engineering of Cu2+ doped In2xZn3(1−x)S3 solid solution with high photocatalytic activity for H2 production under visible light

2013 ◽  
Vol 3 (8) ◽  
pp. 1993 ◽  
Author(s):  
Fan Li ◽  
Guoping Chen ◽  
Jianheng Luo ◽  
Qingli Huang ◽  
Yanhong Luo ◽  
...  
2015 ◽  
Vol 3 (47) ◽  
pp. 23732-23742 ◽  
Author(s):  
Li Zhang ◽  
Xianliang Fu ◽  
Sugang Meng ◽  
Xiaoliang Jiang ◽  
Jinghui Wang ◽  
...  

A simple and convenient one-pot solvothermal method was developed for the preparation of platinized CdS nanorods. It is more efficient than the conventional post-deposition methods to enhance the HER activity of CdS. The use of a noble metal co-catalyst can be significantly reduced by the route without unduly sacrificing the activity.


2021 ◽  
Vol 11 (22) ◽  
pp. 10854
Author(s):  
Jingyun Mao ◽  
Huiling Zhong ◽  
Xinpin Liu ◽  
Qingrong Qian ◽  
Yongjin Luo ◽  
...  

The development of a facile method for the synthesis of GaN:ZnO solid solution, an attractive material with a wurtzite-type structure, is vital to enhance its photocatalytic activity toward H2 evolution. Herein, GaN:ZnO solid solution nanorods with diameters of around 180 nm were fabricated by combining the electro-spun method with a sequentially calcinating process. Photocatalytic water-splitting activities of the as-obtained samples loaded with Rh2−yCryO3 co-catalyst were estimated by H2 evolution under visible-light irradiation. The as-prepared GaN:ZnO nanorods at a nitridation temperature of 850 °C showed the optimal performance. Careful characterization of the GaN:ZnO solid solution nanorods indicated that the nitridation temperature is an important parameter affecting the photocatalytic performance, which is related to the specific surface area and the absorbable visible-light wavelength range. Finally, the mechanism of the GaN:ZnO solid solution nanorods was also investigated. The proposed synthesis strategy paves a new way to realize excellent activity and recyclability of GaN:ZnO solid solution nanorod photocatalysts for hydrogen generation.


2009 ◽  
Vol 631-632 ◽  
pp. 339-344
Author(s):  
Tsugumi Hayashi ◽  
Yohei Baba ◽  
Toshiharu Taga ◽  
Shun Yokoyama ◽  
Hiroaki Suzuki ◽  
...  

Objective of study was the development of core-shell type ZnS-CdS photocatalyst with the stratified morphology. To form the stratified morphology, condition of the precursor is extremely important. For this purpose, three types of precursors, thus core-shell type, egg-shell type and uniform type, was tried to synthesize by utilizing the results of the calculation. The size of the synthesized precursor particles was about 40-100 nm. Main phase of the particle was gradually changed from ZnO (pH8.0) to Cd(OH)2 (pH9.5). Detailed analysis of the synthesized precursor was clearly demonstrated that these have the crystalline structure and each metal element was co-existed in one particle. Therefore, it could be concluded that core-shell type or uniform type precursor was successfully synthesized. Core-shell type ZnS-CdS stratified photocatalyst could be successfully synthesized by sulfurization for 1h, and it shows the high photocatalytic activity under visible light irradiation.


NANO ◽  
2016 ◽  
Vol 11 (05) ◽  
pp. 1650054 ◽  
Author(s):  
Bin Zeng ◽  
Yang Yin

CuS hexagonal nanosheet/graphene was fabricated by a facile one-pot microwave-thermal method. The samples possess excellent photocatalytic activity for degradation of organic pollutant under visible light. The high photocatalytic activity was attributed to the deposition of CuS hexagonal nanosheet onto graphene. CuS nanosheet serves as a transporter which efficiently inhibits the recombination of the photo-induced charge carriers in the nanocomposites. The developed method demonstrates a facile approach towards the synthesis of two-dimensional semiconductor-graphene nanocomposites with excellent photocatalytic performance under visible light.


2018 ◽  
Vol 54 (4B) ◽  
pp. 42
Author(s):  
Trinh Duy Nguyen

Flower-like Bi2WO6 were successfully synthesized using the solvothermal method at different temperatures and characterized by XRD, FE-SEM, and DRS. We also investigated the photocatalytic activity of Bi2WO6 for the decomposition of rhodamine B under visible light irradiation. From XRD and SEM results, the reaction temperature has significant effects on the morphologies of the samples. From DRS results, Bi2WO6 samples displayed the absorption spectrum up to the visible region and then they showed the high photocatalytic activity under visible light irradiation, as a comparison with TiO2-P25.


RSC Advances ◽  
2018 ◽  
Vol 8 (30) ◽  
pp. 16513-16520 ◽  
Author(s):  
Chenghe Hua ◽  
Xiaoli Dong ◽  
Yu Wang ◽  
Nan Zheng ◽  
Hongchao Ma ◽  
...  

BiOCl1−xBrx nanosheets are covered by a thin layer of AgBr that forms BiOCl1−xBrx@AgBr heterostucture with high photocatalytic activity.


2021 ◽  
Author(s):  
Ye Liu ◽  
Jing Xu ◽  
Zhenlu Liu ◽  
Xinyu Liu ◽  
Shengming Xu ◽  
...  

Ni-based nanomaterials have attracted extensive concern as photocatalysts thanks to their high photocatalytic activity and non-toxicity. In this study, a novel visible light induced photocatalyst CuMn-LDO/NiS (CMS) was successfully synthesized...


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