Water balance model for polymer electrolyte fuel cells with ultrathin catalyst layers

2014 ◽  
Vol 16 (5) ◽  
pp. 2106-2117 ◽  
Author(s):  
Karen Chan ◽  
Michael Eikerling
Keyword(s):  
Fuel Cells ◽  
Water Balance ◽  
Polymer Electrolyte ◽  
Polymer Electrolyte Fuel Cells ◽  
Water Balance Model ◽  
Balance Model ◽  
Catalyst Layers

scholarly journals Tipping water balance and the Pt loading effect in polymer electrolyte fuel cells: a model-based analysis

2018 ◽  
Vol 2 (6) ◽  
pp. 1189-1196 ◽  
Author(s):  
Tasleem Muzaffar ◽  
Thomas Kadyk ◽  
Michael Eikerling
Keyword(s):  
Fuel Cells ◽  
Water Balance ◽  
Polymer Electrolyte ◽  
Polymer Electrolyte Fuel Cells ◽  
Loading Effect ◽  
Model Based ◽  
Pt Loading Effect ◽  
Low Pt Loading ◽  
Model Based Analysis

Tipping water balance drastically affecting the performance of electrode layers in polymer electrolyte fuel cells with low Pt loading.

Effectiveness factor of Pt utilization in cathode catalyst layer of polymer electrolyte fuel cells

2008 ◽  
Vol 86 (7) ◽  
pp. 657-667 ◽  
Author(s):  
Zetao Xia ◽  
Qianpu Wang ◽  
Michael Eikerling ◽  
Zhongsheng Liu
Keyword(s):  
Fuel Cells ◽  
Polymer Electrolyte ◽  
Catalyst Layer ◽  
Polymer Electrolyte Fuel Cells ◽  
Effectiveness Factor ◽  
Cathode Catalyst ◽  
Catalyst Layers ◽  
Effectiveness Factors ◽  
Cathode Catalyst Layer ◽  
Pt Utilization

In this work, we analyze effectiveness factors of Pt utilization in perfluorosulfonate ionomer (PFSI) bonded thin film cathode catalyst layers of polymer electrolyte fuel cells. We define the effectiveness factor of Pt utilization as the apparent rate of current conversion exhibited by a specific catalyst layer design divided by the ideal rate obtained if all Pt atoms were used equally in electrochemical reactions at the specified electrode overpotential and externally provided reactant concentrations. This definition includes statistical factors at all relevant scales as well as non-uniformities of reaction rate distributions under operation. Our model is based on the random composite agglomerated morphology of the catalyst layer. It accounts for the interplay of transport phenomena and electrochemical kinetics. At the mesoscopic scale, limited effectiveness of Pt utilization in agglomerates is mainly an electrostatic effect. We determined spatial distributions of effectiveness factors of agglomerates in the through-plane direction, and thereafter calculated overall effectiveness factors of the cathode catalyst layer. Our results show that small agglomerate radius, low operating current density, high operating temperature, and high oxygen partial pressure result in high effectiveness factors of Pt utilization. Finally, we compared PFSI-bonded thin film cathode catalyst layers with ultrathin two-phase cathode catalyst layers in terms of effectiveness factors. Including the surface to volume atom ratio of Pt nanoparticles, the two different types of structures exhibit similar effectiveness factors of Pt utilization, which are found to be distinctly below 10%.Key words: polymer electrolyte fuel cells, fuel cell modeling, cathode catalyst layer, Pt utilization, effectiveness factor.

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