Structure and thermal properties of salicylate-based-protic ionic liquids as new heat storage media. COSMO-RS structure characterization and modeling of heat capacities

2014 ◽  
Vol 16 (8) ◽  
pp. 3549 ◽  
Author(s):  
Johan Jacquemin ◽  
Joanna Feder-Kubis ◽  
Michał Zorębski ◽  
Katarzyna Grzybowska ◽  
Mirosław Chorążewski ◽  
...  
Keyword(s):  
Ionic Liquids ◽  
Thermal Properties ◽  
Heat Storage ◽  
Heat Capacities ◽  
Structure Characterization ◽  
Protic Ionic Liquids ◽  
Storage Media

Thermal properties of protic ionic liquids derivatives triethanolamine-based salts of mineral and organic acids

2019 ◽  
Vol 138 (1) ◽  
pp. 703-712
Author(s):  
M. S. Gruzdev ◽  
A. M. Kolker ◽  
M. A. Кrestyaninov ◽  
L. P. Safonova
Keyword(s):  
Ionic Liquids ◽  
Thermal Properties ◽  
Organic Acids ◽  
Protic Ionic Liquids

Liquid densities, heat capacities, refractive index and excess quantities for {protic ionic liquids+water} binary system

2009 ◽  
Vol 41 (6) ◽  
pp. 799-808 ◽  
Author(s):  
Mérièm Anouti ◽  
Magaly Caillon-Caravanier ◽  
Yosra Dridi ◽  
Johan Jacquemin ◽  
Christopher Hardacre ◽  
...  
Keyword(s):  
Refractive Index ◽  
Ionic Liquids ◽  
Binary System ◽  
Heat Capacities ◽  
Protic Ionic Liquids ◽  
Excess Quantities

Studies on Thermal Properties of Selected Aprotic and Protic Ionic Liquids

2008 ◽  
Vol 43 (9-10) ◽  
pp. 2473-2488 ◽  
Author(s):  
Huimin Luo ◽  
Jing-Fang Huang ◽  
Sheng Dai
Keyword(s):  
Ionic Liquids ◽  
Thermal Properties ◽  
Protic Ionic Liquids

scholarly journals Solvate and protic ionic liquids from aza-crown ethers: synthesis, thermal properties, and LCST behavior

2018 ◽  
Vol 20 (5) ◽  
pp. 3118-3127 ◽  
Author(s):  
Yukiko Oba ◽  
Megumi Okuhata ◽  
Toshiyuki Osakai ◽  
Tomoyuki Mochida
Keyword(s):  
Ionic Liquids ◽  
Thermal Properties ◽  
Crown Ethers ◽  
Protic Ionic Liquids ◽  
Lcst Behavior ◽  
Aza Crown Ethers

Solvate and protic ILs containing alkyl aza-crown ethers were synthesized, some of which exhibited an LCST-type behavior in water.

DFT Study on the Chemical Absorption Mechanism of CO2 in Diamino Protic Ionic Liquids

2021 ◽  
Vol 125 (5) ◽  
pp. 1416-1428
Author(s):  
Jing Ma ◽  
Yutong Wang ◽  
Xueqing Yang ◽  
Mingxuan Zhu ◽  
Baohe Wang
Keyword(s):  
Ionic Liquids ◽  
Dft Study ◽  
Protic Ionic Liquids ◽  
Absorption Mechanism ◽  
Chemical Absorption

scholarly journals The Synthesis of Poly(Vinyl Alcohol) Grafted with Fluorinated Protic Ionic Liquids Containing Sulfo Functional Groups

Molecules ◽  
2021 ◽  
Vol 26 (14) ◽  
pp. 4158
Author(s):  
Patrycja Glińska ◽  
Andrzej Wolan ◽  
Wojciech Kujawski ◽  
Edyta Rynkowska ◽  
Joanna Kujawa
Keyword(s):  
Ionic Liquids ◽  
Vinyl Alcohol ◽  
Proton Exchange ◽  
Polymer Materials ◽  
Polymerization Reaction ◽  
Poly Vinyl Alcohol ◽  
Hydroxyl Groups ◽  
Protic Ionic Liquids ◽  
Synthesis Route ◽  
Sulfo Groups

There has been an ongoing need to develop polymer materials with increased performance as proton exchange membranes (PEMs) for middle- and high-temperature fuel cells. Poly(vinyl alcohol) (PVA) is a highly hydrophilic and chemically stable polymer bearing hydroxyl groups, which can be further altered. Protic ionic liquids (proticILs) have been found to be an effective modifying polymer agent used as a proton carrier providing PEMs’ desirable proton conductivity at high temperatures and under anhydrous conditions. In this study, the novel synthesis route of PVA grafted with fluorinated protic ionic liquids bearing sulfo groups (–SO3H) was elaborated. The polymer functionalization with fluorinated proticILs was achieved by the following approaches: (i) the PVA acylation and subsequent reaction with fluorinated sultones and (ii) free-radical polymerization reaction of vinyl acetate derivatives modified with 1-methylimidazole and sultones. These modifications resulted in the PVA being chemically modified with ionic liquids of protic character. The successfully grafted PVA has been characterized using 1H, 19F, and 13C-NMR and FTIR-ATR. The presented synthesis route is a novel approach to PVA functionalization with imidazole-based fluorinated ionic liquids with sulfo groups.

Development of a robust soft-SAFT model for protic ionic liquids using new high-pressure density data

2021 ◽  
pp. 113036
Author(s):  
Emanuel A. Crespo ◽  
Liliana P. Silva ◽  
Cristina I.P. Correia ◽  
Mónia A.R. Martins ◽  
Ramesh L. Gardas ◽  
...  
Keyword(s):  
High Pressure ◽  
Ionic Liquids ◽  
Protic Ionic Liquids ◽  
Density Data

Insights into the translational and rotational dynamics of cations and anions in protic ionic liquids by means of NMR fast-field-cycling relaxometry

2021 ◽  
Vol 23 (4) ◽  
pp. 2663-2675
Author(s):  
Viviane Overbeck ◽  
Henning Schröder ◽  
Anne-Marie Bonsa ◽  
Klaus Neymeyr ◽  
Ralf Ludwig
Keyword(s):  
Ionic Liquids ◽  
Rotational Dynamics ◽  
Protic Ionic Liquids ◽  
Field Cycling ◽  
Fast Field ◽  
Hydrogen Bonded

NMR Fast-Field-Cycling (FFC) relaxometry provides important information about translational and rotational dynamics of hydrogen bonded protic ionic liquids (PILs). 

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