scholarly journals Light intensity dependence of the kinetics of the photocatalytic oxidation of nitrogen(ii) oxide at the surface of TiO2

2013 ◽  
Vol 15 (48) ◽  
pp. 20876 ◽  
Author(s):  
Ralf Dillert ◽  
Astrid Engel ◽  
Julia Große ◽  
Patrick Lindner ◽  
Detlef W. Bahnemann
Keyword(s):  
Light Intensity ◽  
Photocatalytic Oxidation ◽  
Intensity Dependence ◽  
Kinetics Of

Light-Intensity Dependence In The Kinetics Of N-Gap Photoelectrode Stabilization

2010 ◽  
Vol 89 (3) ◽  
pp. 181-186 ◽  
Author(s):  
F. van Overmeire ◽  
F. Vanden Kerchove ◽  
W. P. Gomes ◽  
F. Cardon
Keyword(s):  
Light Intensity ◽  
Intensity Dependence ◽  
Kinetics Of

scholarly journals Characteristics and Kinetics of Rosin Pentaerythritol Ester via Oxidation Process under Ultraviolet Irradiation

Molecules ◽  
2018 ◽  
Vol 23 (11) ◽  
pp. 2816 ◽  
Author(s):  
Yuanlin Li ◽  
Xiongmin Liu ◽  
Qiang Zhang ◽  
Bo Wang ◽  
Chang Yu ◽  
...  
Keyword(s):  
Light Intensity ◽  
Oxidation Kinetics ◽  
Pseudo First Order Reaction ◽  
Initial Oxidation ◽  
Photo Oxidation ◽  
Average Value ◽  
Pentaerythritol Ester ◽  
Fundamental Information ◽  
The Stability ◽  
Kinetics Of

A self-designed reaction device was used as a promising equipment to investigate the oxidation characteristics and kinetics of rosin pentaerythritol ester (RPE) under UV irradiation. Photo-oxidation kinetics and the initial quantum yield (Φ) of RPE were calculated. The initial oxidation product of the photo-oxidation reaction—peroxide was analyzed by iodimetry. The peroxide concentration is related to the light intensity (I) and the temperature (T), and the increasing T and I would destabilize the RPE by accelerating peroxide forming. Photo-oxidation of RPE follows the pseudo first-order reaction kinetics. The relationship between activation energy and logarithm of light intensity (ln I) is linear, and it is expressed as Ea = −4.937ln I + 45.565. Φ was calculated by the photo-oxidation kinetics, and the average value of Φ was 7.19% in the light intensity range of 200–800 μW cm−2. This research can provide fundamental information for application of RPE, and help obtain a better understanding of the stability of rosin esters.

scholarly journals Kinetics of bulk photo-initiated copper(i)-catalyzed azide–alkyne cycloaddition (CuAAC) polymerizations

2016 ◽  
Vol 7 (3) ◽  
pp. 603-612 ◽  
Author(s):  
Han Byul Song ◽  
Austin Baranek ◽  
Christopher N. Bowman
Keyword(s):  
Light Intensity ◽  
Exposure Time ◽  
Copper Salt ◽  
Solvent Content ◽  
Kinetics Of

Kinetics of bulk photo-initiated copper(i)-catalyzed azide–alkyne cycloaddition (CuAAC) polymerizations is governed by several factors including the physicochemical nature of the monomers; the copper salt and photoinitiator types and concentrations; light intensity; exposure time and solvent content.

Use of Experimental Designs to Establish a Kinetic Law for a Gas Phase Photocatalytic Process

2014 ◽  
Vol 12 (1) ◽  
pp. 113-122 ◽  
Author(s):  
Cécile Raillard ◽  
Audrey Maudhuit ◽  
Valérie Héquet ◽  
Laurence Le Coq ◽  
Jean Sablayrolles ◽  
...  
Keyword(s):  
Light Intensity ◽  
Photocatalytic Degradation ◽  
Gas Phase ◽  
Photocatalytic Oxidation ◽  
Experimental Designs ◽  
Photocatalytic Process ◽  
Air Velocity ◽  
Kinetic Rate ◽  
Initial Concentration ◽  
Designs Of Experiments

Abstract The photocatalytic degradation of three common indoor VOCs – acetone, toluene and heptane – is investigated in a dynamic photocatalytic oxidation loop using Box–Behnken designs of experiments. Thanks to the experimental results and the establishment of a kinetic rate law based on a simplified mechanism, a predictive model for the VOC degradation involving independent factors is developed. The parameters under investigation are initial concentration, light intensity and air velocity through the photocatalytic medium. The obtained model fits properly the experimental curves in the range of concentration, light intensity and air flow studied.

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