Force-induced mechanical response of molecule–metal interfaces: molecular nanomechanics of propanethiolate self-assembled monolayers on Au(111)

2013 ◽  
Vol 15 (38) ◽  
pp. 16001 ◽  
Author(s):  
Porntip Seema ◽  
Jörg Behler ◽  
Dominik Marx
Keyword(s):  
Mechanical Response ◽  
Self Assembled Monolayers ◽  
Assembled Monolayers ◽  
Metal Interfaces ◽  
Self Assembled

scholarly journals Conventional Nanoindentation in Self-Assembled Monolayers Deposited on Gold and Silver Substrates

2012 ◽  
Vol 2012 ◽  
pp. 1-5 ◽  
Author(s):  
Leila Costelle ◽  
Liina Lind ◽  
Pasi Jalkanen ◽  
Minna T. Räisänen ◽  
Roman Nowak ◽  
...  
Keyword(s):  
Mechanical Response ◽  
Self Assembled Monolayers ◽  
Energy Calculation ◽  
Complex Behaviour ◽  
Assembled Monolayers ◽  
Efficient Data ◽  
Self Assembled ◽  
Efficient Data Analysis ◽  
Insight Into

Self-assembled monolayers (SAMs) are promising materials for micromechanical applications. However, characterization of mechanical properties of monolayers is challenging for standard nanoindentation, and new efficient analysis techniques are needed. Hereby, a conventional nanoindentation method has been combined in a unique way with efficient data analysis based on consumed energy calculation and load-displacement data. The procedure has been applied on SAMs of 4,4′-biphenyldithiol (BPDT) on Au, 1-tetradecanethiol (TDT), and 1-hexadecanethiol (HDT) on Au and Ag substrates being the first study where SAMs of the same thiols on different substrates are analyzed by nanoindentation providing a new insight into the substrate effects. Unlike TDT and HDT SAMs, which are found to strongly enhance the homogeneity and stiffness of the underlying substrate, the BPDT covered Au substrate appears softer in mechanical response. In the case of TDT and HDT SAMs on Ag the structures are softer showing also faster relaxation than the corresponding structures on Au substrate. The proposed procedure enables a fast and efficient way of assessing the complex behaviour of SAM modified substrates. As a consequence, the results are relevant to practical issues dependent on layer activity and toughness.

Mechanical response of nanometer thick self-assembled monolayers on metallic substrates using classical nanoindentation

2011 ◽  
Vol 110 (11) ◽  
pp. 114301 ◽  
Author(s):  
Leila Costelle ◽  
Pasi Jalkanen ◽  
Minna T. Räisänen ◽  
Liina Lind ◽  
Roman Nowak ◽  
...  
Keyword(s):  
Mechanical Response ◽  
Self Assembled Monolayers ◽  
Metallic Substrates ◽  
Assembled Monolayers ◽  
Self Assembled

Electrochemical behavior of self-assembled monolayers based on functionalized oligothiophenes

1998 ◽  
Vol 95 (6) ◽  
pp. 1339-1342 ◽  
Author(s):  
R. Michalitsch ◽  
A. El Kassmi ◽  
P. Lang ◽  
A. Yassar ◽  
F. Garnier
Keyword(s):  
Electrochemical Behavior ◽  
Self Assembled Monolayers ◽  
Assembled Monolayers ◽  
Self Assembled

Imaging of patterned self-assembled monolayers by scanning photoelectron microscopy

2003 ◽  
Vol 104 ◽  
pp. 459-462 ◽  
Author(s):  
R. Klauser ◽  
M. Zharnikov ◽  
I.-H. Hong ◽  
S.-C. Wang ◽  
A. Gölzhäuser ◽  
...  
Keyword(s):  
Self Assembled Monolayers ◽  
Assembled Monolayers ◽  
Scanning Photoelectron Microscopy ◽  
Self Assembled

Self-assembled Monolayers Preparation and Characterization of BiFeO3 Thin Films

2009 ◽  
Vol 25 (1) ◽  
pp. 83-86 ◽  
Author(s):  
Guo-Qiang TAN ◽  
Hai-Yang BO ◽  
Hong-Yan MIAO ◽  
Ao XIA ◽  
Zhong-Liang HE
Keyword(s):  
Thin Films ◽  
Self Assembled Monolayers ◽  
Assembled Monolayers ◽  
Self Assembled
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