Dielectric relaxations and conduction mechanisms in polyether–clay composite polymer electrolytes under high carbon dioxide pressure

2013 ◽  
Vol 15 (39) ◽  
pp. 16626 ◽  
Author(s):  
Shunsuke Kitajima ◽  
Federico Bertasi ◽  
Keti Vezzù ◽  
Enrico Negro ◽  
Yoichi Tominaga ◽  
...  
Keyword(s):  
Carbon Dioxide ◽  
Polymer Electrolytes ◽  
Composite Polymer ◽  
High Carbon ◽  
Composite Polymer Electrolytes ◽  
Dielectric Relaxations ◽  
Conduction Mechanisms ◽  
Carbon Dioxide Pressure ◽  
High Carbon Dioxide

Dielectric Relaxations in Lithium Composite Polymer Electrolytes Based on PEO and Diethylaluminum Carboxylate

2000 ◽  
pp. 627-632
Author(s):  
B. Misztal-Faraj ◽  
F. Krok ◽  
J. R. Dygas ◽  
Z. Florjañczyk ◽  
E. Zygad O-Monikowska ◽  
...  
Keyword(s):  
Polymer Electrolytes ◽  
Composite Polymer ◽  
Composite Polymer Electrolytes ◽  
Dielectric Relaxations

scholarly journals Excellent Performances of Composite Polymer Electrolytes with Porous Vinyl-Functionalized SiO2 Nanoparticles for Lithium Metal Batteries

Polymers ◽  
2021 ◽  
Vol 13 (15) ◽  
pp. 2468
Author(s):  
Hui Zhan ◽  
Mengjun Wu ◽  
Rui Wang ◽  
Shuohao Wu ◽  
Hao Li ◽  
...  
Keyword(s):  
Polymer Electrolytes ◽  
Specific Capacity ◽  
Sio2 Nanoparticles ◽  
Inorganic Materials ◽  
Solid Polymer Electrolytes ◽  
Lithium Metal ◽  
Composite Polymer ◽  
Composite Electrolyte ◽  
Composite Polymer Electrolytes ◽  
Lithium Metal Batteries

Composite polymer electrolytes (CPEs) incorporate the advantages of solid polymer electrolytes (SPEs) and inorganic solid electrolytes (ISEs), which have shown huge potential in the application of safe lithium-metal batteries (LMBs). Effectively avoiding the agglomeration of inorganic fillers in the polymer matrix during the organic–inorganic mixing process is very important for the properties of the composite electrolyte. Herein, a partial cross-linked PEO-based CPE was prepared by porous vinyl-functionalized silicon (p-V-SiO2) nanoparticles as fillers and poly (ethylene glycol diacrylate) (PEGDA) as cross-linkers. By combining the mechanical rigidity of ceramic fillers and the flexibility of PEO, the as-made electrolyte membranes had excellent mechanical properties. The big special surface area and pore volume of nanoparticles inhibited PEO recrystallization and promoted the dissolution of lithium salt. Chemical bonding improved the interfacial compatibility between organic and inorganic materials and facilitated the homogenization of lithium-ion flow. As a result, the symmetric Li|CPE|Li cells could operate stably over 450 h without a short circuit. All solid Li|LiFePO4 batteries were constructed with this composite electrolyte and showed excellent rate and cycling performances. The first discharge-specific capacity of the assembled battery was 155.1 mA h g−1, and the capacity retention was 91% after operating for 300 cycles at 0.5 C. These results demonstrated that the chemical grafting of porous inorganic materials and cross-linking polymerization can greatly improve the properties of CPEs.

Effect of prolonged exposure of rats to high carbon dioxide concentrations

1978 ◽  
Vol 86 (3) ◽  
pp. 1149-1151
Author(s):  
P. M. Gramenitskii ◽  
V. A. Galichii ◽  
N. V. Petrova ◽  
N. Yu. Leont'eva
Keyword(s):  
Carbon Dioxide ◽  
Prolonged Exposure ◽  
High Carbon ◽  
Carbon Dioxide Concentrations ◽  
High Carbon Dioxide
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