Reaction kinetics of CO2 absorption in to phosphonium based anion-functionalized ionic liquids

2013 ◽  
Vol 15 (20) ◽  
pp. 7796 ◽  
Author(s):  
Burcu E. Gurkan ◽  
Thomas R. Gohndrone ◽  
Mark J. McCready ◽  
Joan F. Brennecke
2021 ◽  
Vol 329 ◽  
pp. 115569
Author(s):  
Rouzbeh Ramezani ◽  
Ida M. Bernhardsen ◽  
Renzo Di Felice ◽  
Hanna K. Knuutila

2012 ◽  
Vol 81 ◽  
pp. 251-259 ◽  
Author(s):  
Teerawat Sema ◽  
Abdulaziz Naami ◽  
Zhiwu Liang ◽  
Raphael Idem ◽  
Paitoon Tontiwachwuthikul ◽  
...  

2019 ◽  
Vol 26 (1) ◽  
pp. 26-32
Author(s):  
Sanaa Rabie Saleh ◽  
Ahmed Daham Wiheeb

Binding organic liquids are a strong base of amidine have been used for CO2 capture. Up to now, there is no known datum on the reaction kinetics of CO2 with 1,5-Diazabicyclo[4.3.0]non-5-ene (DBN). In this paper, Kinetics of reaction between CO2 and DBN/MDEA in 1-Pentanol were performed utilizing the stirred cell reactor with DBN concentration (2 – 2.9 M) and at room temperature. The reaction path was qualified using zwitterion and the termolecular mechanism. From the kinetic datum with DBN concentrations (2 – 2.9 M), it was found that the capturing process happen in a fast reaction system with a second-order reaction kinetics of DBN/MDEA and first order with CO2. In addition, CO2 absorption was achieved using gas – liquid contact system. CO2 absorption rate was (2×10^(-5)-2.8 × 10^(-5) kmol⁄m^2 .sec) at DBN concentration (2 – 2.9 M). Finally, it is known that DBN/MDEA/1-Pentanol/CO2 system is easily switchable and can be used both CO2 capture and for other applications that require rapid change of medium from nonionic to ionic liquid.


RSC Advances ◽  
2014 ◽  
Vol 4 (33) ◽  
pp. 17097-17104 ◽  
Author(s):  
Nora Harwardt ◽  
Natascha Stripling ◽  
Simon Roth ◽  
Haifeng Liu ◽  
Ulrich Schwaneberg ◽  
...  

Conductivity and viscosity explain part of the effect of ionic liquids on the laccase–mediator system kinetics, but not all.


2017 ◽  
Vol 114 ◽  
pp. 860-865 ◽  
Author(s):  
Joshuah K. Stolaroff ◽  
Congwang Ye ◽  
Du T. Nguyen ◽  
James Oakdale ◽  
Jennifer M. Knipe ◽  
...  

2014 ◽  
Vol 46 (12) ◽  
pp. 730-745 ◽  
Author(s):  
Ahmed Sodiq ◽  
Aravind V. Rayer ◽  
Akinola A. Olanrewaju ◽  
Mohammad R. M. Abu Zahra

2015 ◽  
Vol 54 (50) ◽  
pp. 12525-12533 ◽  
Author(s):  
Helei Liu ◽  
Min Xiao ◽  
Zhiwu Liang ◽  
Wichitpan Rongwong ◽  
Jie Li ◽  
...  

2016 ◽  
Vol 13 (1) ◽  
pp. 53
Author(s):  
Siti Nabihah Jamaludin ◽  
Ruzitah Mohd Salleh

Anthropogenic CO2 emissions has led to global climate change and widely contributed to global warming since its concentration has been increasing over time. It has attracted vast attention worldwide. Currently, the different CO2 capture technologies available include absorption, solid adsorption and membrane separation. Chemical absorption technology is regarded as the most mature technology and is commercially used in the industry. However, the key challenge is to find the most efficient solvent in capturing CO2. This paper reviews several types of CO2 capture technologies and the various factors influencing the CO2 absorption process, resulting in the development of a novel solvent for CO2 capture.


2020 ◽  
Author(s):  
Camilo A. Mesa ◽  
Ludmilla Steier ◽  
Benjamin Moss ◽  
Laia Francàs ◽  
James E. Thorne ◽  
...  

<p><i>Operando</i> spectroelectrochemical analysis is used to determine the water oxidation reaction kinetics for hematite photoanodes prepared using four different synthetic procedures. Whilst these photoanodes exhibit very different current / voltage performance, their underlying water oxidation kinetics are found to be almost invariant. Lower photoanode performance was found to correlate with the observation of optical signals indicative of charge accumulation in mid-gap oxygen vacancy states, indicating these states do not contribute directly to water oxidation.</p>


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