Solid state structural transformation of 1D to intermediate 2D and then to 3D porous coordination polymer by anion replacement; new precursors for preparation of PbCl2, Pb3O2Cl2 and PbO nanoparticles

CrystEngComm ◽  
2013 ◽  
Vol 15 (44) ◽  
pp. 8894 ◽  
Author(s):  
Lida Hashemi ◽  
Ali Morsali
Keyword(s):  
Solid State ◽  
Coordination Polymer ◽  
Structural Transformation ◽  
Porous Coordination Polymer ◽  
Pbo Nanoparticles

Solid state structural transformation of bromide coordination polymer to chloride by anion replacement; new precursors for preparation of PbBr2 and PbCl2 nanoparticles

RSC Advances ◽  
2014 ◽  
Vol 4 (33) ◽  
pp. 17265-17267 ◽  
Author(s):  
Lida Hashemi ◽  
Ali Morsali
Keyword(s):  
Solid State ◽  
Coordination Polymer ◽  
Anion Exchange ◽  
Structural Transformation ◽  
Coordination Polymers

Reversible anion-exchange of 2D lead(ii) coordination polymers from [Pb(4-bpdb)Br2]n (1) to [Pb(4-bpdb)Cl2]n (2) by solid state anion-replacement has been studied.

Supramolecular Hexagon and Chain Coordination Polymer Containing the MoO22+Core: Structural Transformation in the Solid State

2011 ◽  
Vol 11 (4) ◽  
pp. 1244-1252 ◽  
Author(s):  
Višnja Vrdoljak ◽  
Biserka Prugovečki ◽  
Dubravka Matković-Čalogović ◽  
Jana Pisk ◽  
Renata Dreos ◽  
...  
Keyword(s):  
Solid State ◽  
Coordination Polymer ◽  
Structural Transformation

scholarly journals Reversible Solid-State Structural Transformation of a 1D−2D Coordination Polymer by Thermal De/Rehydration Processes

2011 ◽  
Vol 50 (2) ◽  
pp. 597-603 ◽  
Author(s):  
Chih-Chieh Wang ◽  
Ching-Chun Yang ◽  
Chang-Tsung Yeh ◽  
Kum-Yi Cheng ◽  
Pei-Chen Chang ◽  
...  
Keyword(s):  
Solid State ◽  
Coordination Polymer ◽  
Structural Transformation

scholarly journals Synthesis of chiral porous coordination polymer that shows structural transformation induced by guest molecules

2015 ◽  
Vol 424 ◽  
pp. 221-225 ◽  
Author(s):  
Takashi Kitao ◽  
Yuta Tokunaga ◽  
Daiki Umeyama ◽  
Cho Rong Kim ◽  
Takashi Uemura ◽  
...  
Keyword(s):  
Coordination Polymer ◽  
Structural Transformation ◽  
Guest Molecules ◽  
Porous Coordination Polymer

Two Consecutive Magneto-Structural Gas-Solid Transformations with Single-Crystal Retention in Non-Porous Molecular Materials

2018 ◽  
Author(s):  
Julia Miguel-Donet ◽  
Javier López-Cabrelles ◽  
Nestor Calvo Galve ◽  
Eugenio Coronado ◽  
Guillermo Minguez Espallargas
Keyword(s):  
Solid State ◽  
Single Crystal ◽  
Structural Rearrangement ◽  
Magnetic Behaviour ◽  
Porous Solids ◽  
Potential Applications ◽  
Hcl Gas ◽  
Porous Coordination Polymer ◽  
Gas Molecules ◽  
Magnetostructural Transformation

<p>Modification of the magnetic properties in a solid-state material upon external stimulus has attracted much attention in the recent years for their potential applications as switches and sensors. Within the field of coordination polymers, gas sorption studies typically focus on porous solids, with the gas molecules accommodating in the channels. Here we present a 1D non-porous coordination polymer capable of incorporating HCl gas molecules, which not only causes a reordering of its atoms in the solid state but also provokes dramatic changes in the magnetic behaviour. Subsequently, a further solid-gas transformation can occur with the extrusion of HCl gas molecules causing a second structural rearrangement which is also accompanied by modification in the magnetic path between the metal centres. Unequivocal evidence of the two-step magnetostructural transformation is provided by X-ray single-crystal diffraction.</p>

A novel multichromic Zn (Ⅱ) cationic coordination polymer based on a new flexible viologen ligand exhibiting aniline detection in solid state

2021 ◽  
Author(s):  
Jiayun Zou ◽  
jie Ji ◽  
Meihong Fan ◽  
Jiayu Li ◽  
Haiyu Wang ◽  
...  
Keyword(s):  
Solid State ◽  
Coordination Polymer ◽  
Pyromellitic Acid

In this paper, a novel multichromic catioic coordination polymer, named [Zn4 (BTC)3(bcbpy)2] ·5H2O (1) based on a new flexible viologen ligand 1,1'-bis(3-cyanobenzyl)-[4,4'-bipyridine-1,1'-diium (H2bcbpy·2Cl), Zn(NO3)2·6H2O and pyromellitic acid (H4BTC), was synthesized....

scholarly journals Proton-conductive coordination polymer glass for solid-state anhydrous proton batteries

2021 ◽  
Vol 12 (16) ◽  
pp. 5818-5824
Author(s):  
Nattapol Ma ◽  
Soracha Kosasang ◽  
Atsushi Yoshida ◽  
Satoshi Horike
Keyword(s):  
Mechanical Properties ◽  
Solid State ◽  
Coordination Polymer ◽  
Proton Battery ◽  
Polymer Glass

Melt-quenched coordination polymer glass shows exclusive H+ conductivity (8.0 × 10−3 S cm−1 at 120 °C, anhydrous) and optimal mechanical properties (42.8 Pa s at 120 °C), enables the operation of an all-solid-state proton battery from RT to 110 °C.

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